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Citation: WANG Na, MA Zhi-Hong, HAN Zhan-Gang, LIN Jin, ZHENG Xue-Zhong. Synthesis, Crystal Structures and Thermal Stability of Monsubstituted Cyclopentadienyl Dimolybdenum Carbonyl Complexes[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2225-2230. doi: 10.3969/j.issn.1001-4861.2013.00.329 shu

Synthesis, Crystal Structures and Thermal Stability of Monsubstituted Cyclopentadienyl Dimolybdenum Carbonyl Complexes

1.
1 College of Chemistry & Material Science, Hebei Normal University, Shijiazhuang 050024, China;

Received Date: 19 October 2012
Available Online: 17 May 2013
Fund Project: 河北省自然科学基金(No.B2008000150) (No.B2008000150)河北师范大学重点基金(No.L2009Z06)资助项目 (No.L2009Z06)

Monsubstituted cyclopentadienes (C₅H₅R) (R=n-Butyl (1), Benzyl (2), n-Propyl (3), Allyl (4)) reacted with Mo(CO)₆ to give four new dinuclear cyclopentadienyl molybdenum carbonyl complexes (C₅H₄R)₂Mo₂(CO)₆ (R=n-Butyl (5), Benzyl (6), n-Propyl (7), Allyl (8)), respectively. The complexes 5～8 were characterized by elemental analysis, IR, ¹H NMRspectrum, and TG. The crystal structures of 5 and 6 were determined by X-ray single crystal diffraction. The structures show that complex 5 crystallizes in monoclinic system with space group P2_l/c and complex 6 is triclinic crystal system with space group Pl.The TGanalysis shows that the complexes 5 and 6 are stable below 107 and 162 ℃, respectively. CCDC: 883603, 5; 881472, 6.
- molybdenum carbonyl; monsubstituted cyclopentadienyl; crystal structure; X-ray diffraction
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