Citation: ZOU Xiao-Yan, YAN Peng-Fei, ZHANG Feng-Ming, LI Guang-Ming. Synthesis and Crystal Structure of N,N’-Bis(2-hydroxy-3-methoxybenzylidene)-1,3-propanediamine La(Ⅲ) Complexes Modulated by Counterion PF₆^-[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1680-1686. doi: 10.3969/j.issn.1001-4861.2013.00.314 shu

Synthesis and Crystal Structure of N,N’-Bis(2-hydroxy-3-methoxybenzylidene)-1,3-propanediamine La(Ⅲ) Complexes Modulated by Counterion PF₆^-

1.
Key Laboratory of Functional Inorganic Material Chemistry (MOE); School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, China

Received Date: 8 May 2013
Available Online: 14 June 2013
Fund Project: 国家自然科学基金(No.21072049,21072050)资助项目。 (No.21072049,21072050)

Complex [La₂(NO₃)₆(H₂L)₂]·CH₂Cl₂ (1) has been synthesized by reactions of N,N'-bis(2-hydroxy-3-meth-oxybenzylidene)-1,3-propanediamine (H₂L) with La(NO₃)₃·6H₂O. X-ray diffraction analysis reveals that complex 1 exhibits a dinuclear structure bridged by two H₂L ligands. Complex [La₂(NO₃)₂(H₂L)₄](PF₆)₄·4H₂O·2CH₂Cl₂ (2) can be transformed from 1 with the introduction of (NH₄)(PF₆), which exhibits a dinuclear structure linked by two NO₃^- anions. The PF₆^- counterion plays an essential role on steering the structural transformation. CCDC: 937367, 1; 937368, 2.
- N,N’-bis(2-hydroxy-3-methoxybenzylidene)-1,3-propanediamine;salen lanthanide complexes;crystal structure
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis and Crystal Structure of N,N’-Bis(2-hydroxy-3-methoxybenzylidene)-1,3-propanediamine La(Ⅲ) Complexes Modulated by Counterion PF6-

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Crystal Structure of N,N’-Bis(2-hydroxy-3-methoxybenzylidene)-1,3-propanediamine La(Ⅲ) Complexes Modulated by Counterion PF₆^-