Citation: ZHOU Qin-Qin, FU Da-Wei. A Novel Supramolecular Compound with 4-Iodobenzenaminium Based on 18-Crown-6：Synthesis, Structure and Dielectric Properties[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1696-1702. doi: 10.3969/j.issn.1001-4861.2013.00.299 shu

A Novel Supramolecular Compound with 4-Iodobenzenaminium Based on 18-Crown-6：Synthesis, Structure and Dielectric Properties

ZHOU Qin-Qin ,
FU Da-Wei

1.
Ordered Matter Science Research Center, Southeast University, Nanjing 210096, China

Received Date: 17 January 2013
Available Online: 30 May 2013
Fund Project:

One novel organic-inorganic hybrid supramolecular compound, ([(4-IA-NH₃)·(18-crown-6)]₂·(Cu₂Cl₆) (1), has been synthesized and characterized by IR spectroscopy, XRPD, thermogravimetric analysis and single crystal X-ray diffraction (where 4-IA-NH₃⁺=4-iodobenzenaminium; 18-crown-6=1,4,7,10,13,16-hexaoxacyclooctadecane). The organic [(4-IA-NH₃)·(18-crown-6)]⁺ cation assemblies and inorganic Cu₂Cl₆^2- anions arrange alternately to build the macrocycle-based rotator-stator supramolecular inclusion. Temperature-dependent dielectric constants of compound 1 show no distinct dielectric anomalies, suggesting no phase transition within the measured temperature range (130~450 K). A high dielectric constant above 350 K at a low frequency of 500 Hz suggests that the increase in the disorder molecular thermal motion and/or H-bonding dipole interactions. CCDC: 919514.
- inclusion compound;crown ether;macrocycle;crystal structure;permittivity
1. [1]
  [1] Vanderah T A. Science, 2002,298:1182-1184
2. [2]
  [2] Lee H N, Christen H M, Christen M F, et al. Nature, 2005, 433:395-399
3. [3]
  [3] Mohamed M B, Wang H, Fuess H, J. Phys. D: Appl. Phys., 2010,43:455409(7 pages)
4. [4]
  [4] Ye H Y, Fu D W, Zhang Y, et al. J. Am. Chem. Soc., 2009, 131:42-43
5. [5]
  [5] Fu D W, Song Y M, Wang G X, et al. J. Am. Chem. Soc., 2007,129:5346-5347
6. [6]
  [6] Hou J G, Qu Y F, Vaish R H, et al. J. Am. Ceram. Soc., 2010,93:1414-1421
7. [7]
  [7] Homes C C, Vogt T, Shapiro S M, et al. Science, 2001,293: 673-676
8. [8]
  [8] Hughes H, Allix M M B, Bridges C A, et al. J. Am. Chem. Soc., 2005,27:13790-13791
9. [9]
  [9] Shukla A K, Agrawal V K, Das I M L, et al. Phase Transit., 2006,79:875-887
10. [10]
  [10] Subramanian M A, Li D, Duan N, et al. Solid State Chem., 2000,151:323-325
11. [11]
  [11] Kobrsi I, Knox J E, Heeg M J, et al. Inorg. Chem., 2005,44: 4894-4896
12. [12]
  [12] Zou X Q, Zhu G S, Zhang F, et al. CrystEngComm, 2010, 12:352-354
13. [13]
  [13] Hu S, Meng Z S, Tong M L. Cryst. Growth Des., 2010,10: 1742-1748
14. [14]
  [14] Iqbal M J, Khan R A. J. Alloy. Compd., 2009,478:847-852
15. [15]
  [15] Li R X, Cheng J R, Meng Z Y, et al. J. Mater. Sci: Mater. Electron, 2006,17:587-591
16. [16]
  [16] Horiuchi S, Kumai R, Tokura Y. Angew. Chem. Int. Ed., 2007,46:3497-3501
17. [17]
  [17] Akutagawa T, Koshinaka H, Sato D, et al. Nat. Mater., 2009,8:342-347
18. [18]
  [18] Akutagawa T, Endo D, Kudo F, et al. Cryst. Growth Des., 2008,8:812-816
19. [19]
  [19] Fu D W, Zhao M M, Ge J Z. J. Mol. Struct., 2011,1006:227-233
20. [20]
  [20] Fu D W, Zhang W, Cai H L, et al. J. Am. Chem. Soc., 2011,133:2780-12786
21. [21]
  [21] Fu D W, Ge J Z, Dai J, et al. Inorg. Chem. Commun., 2009,12:994-997
22. [22]
  [22] Fu D W, Zhang W, Xiong R G. Cryst. Growth Des., 2008,8: 3461-3464
23. [23]
  [23] Fu D W, Dai J, Ge J Z, et al. Inorg. Chem. Commun., 2010, 13:282-285
24. [24]
  [24] Fu D W, Ge J Z, Zhang Y, et al. Z. Anorg. Allg. Chem., 2009,635:2631-2635
25. [25]
  [25] Fu D W, Dai J, Ge J Z, et al. Inorg. Chim. Acta, 2010,363: 2584-2589
26. [26]
  [26] Fu D W, Ye H Y, Ye Q, et al. Dalton Trans., 2008:874-877
27. [27]
  [27] Fu D W, Zhang W, Xiong R G. Dalton Trans., 2008:3946-3948
28. [28]
  [28] Rigaku. CrystalClear, Version1.4.0. Rigaku Corporation, Tokyo, Japan, 2005.
29. [29]
  [29] Sheldrick G M. SHELXS-97, Programm for Crystal Structure Solution, University of Göttingen, Göttingen, Gremany, 1997.
30. [30]
  [30] Sheldrick G M. SHELXS-97, Program for Crystal Structure Refinement, University of Göttingen, Göttingen, Gremany, 1997.
31. [31]
  [31] Nakamoto K. Infrared and Rraman Spectra of Inorganic and Coordination Compounds. 3rd Ed. New York: Wiley, 1978.
32. [32]
  [32] Newnham R E. Structure Property Relations. New York: Springer, 1975.
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沈阳化工大学材料科学与工程学院沈阳 110142