Citation: WANG Yin-Ge, LIU Qian-Qian, ZHAI Li-Xin, QIAN Hui-Fen, HUANG Wei. Structural and Spectral Studies of Cis Cadmium(Ⅱ), Manganese(Ⅱ) and Nickel(Ⅱ) Complexes Having 2-Thiophenimidazo[4,5-f][1,10]phenanthroline and 2-(5-Bromothiophen)imidazo[4,5-f][1,10]phenanthroline Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(8): 1687-1695. doi: 10.3969/j.issn.1001-4861.2013.00.294 shu

Structural and Spectral Studies of Cis Cadmium(Ⅱ), Manganese(Ⅱ) and Nickel(Ⅱ) Complexes Having 2-Thiophenimidazo[4,5-f][1,10]phenanthroline and 2-(5-Bromothiophen)imidazo[4,5-f][1,10]phenanthroline Ligands

1.
1College of Sciences, Nanjing University of Technology, Nanjing 210009, China;

Received Date: 16 February 2013
Available Online: 28 May 2013
Fund Project: 国家自然科学基金(No.21171088) (No.21171088)

Three mononuclear cadmium(Ⅱ), manganese(Ⅱ) and nickel(Ⅱ) complexes having 2-thiophenimidazo[4,5-f][1,10]phenanthroline (TIP) and 2-(5-bromothiophen)imidazo[4,5-f][1,10]phenanthroline (5-Br-TIP) ligands formulated as [cis-Cd(NO3)(TIP)₂] (1), [cis-MnCl₂(5-Br-TIP)₂] (2) and [cis-NiCl₂(TIP)₂] (3), have been synthesized and structurally compared. They are characterized by elemental analysis, FT-IR, UV-Vis spectra, luminescence spectra and X-ray single-crystal structural analysis. All of them are 1:2 mononuclear complexes with the same cis configuration, among which complex 1 is eight-coordinated and the others are six-coordinated. Ligands TIP and 5-Br-TIP in complex 1~3 are essentially planar with the dihedral angles between imidazole and thiophene rings in the range of 3.9(1)°~9.2(1)°. CCDC: 922633, 1; 922634, 2; 922635, 3.
- cadmium(Ⅱ) complex;manganese(Ⅱ) complex;nickel(Ⅱ) complex;2-thiophenimidazo[4,5-f][1,10]phenanthroline;2-(5-bromothiophen) imidazo[4,5-f][1,10]phenanthroline;crystal structure
1. [1]
  [1] Prat O, Lopez E, Mathis G. Anal. Biochem., 1991,195:283-289
2. [2]
  [2] Hsiao W L W, Mo Z Y, Fang M, et al. Mutat Res-Genet Toxicol E. M., 2000,471:45-55
3. [3]
  [3] Hong Y N, Lam J W Y, Tang B Z. Chem. Commun., 2009, 29:4332-4553
4. [4]
  [4] Beauvais L G, Shores M P, Long J R. J. Am. Chem. Soc., 2000,122:2763-2772
5. [5]
  [5] Turnbull G A, Andrew P, Barnes W L. Appl. Phys. Lett., 2003,82:313-315
6. [6]
  [6] Chou H H, Hsu C Y, Lin Y S, et al. Tetrahedron, 2012,68: 767-773
7. [7]
  [7] Gratzel M. Inorg. Chem., 2005,44:6841-6851
8. [8]
  [8] Chang Y J, Chow T J. J. Mater. Chem., 2011,21:9523-9532
9. [9]
  [9] Mushrush M, Facchetti A, Lefenfeld M. J. Am. Chem. Soc., 2003,125:9414-9423
10. [10]
  [10] Ponomarenko S A, Kirchmeyer S, Elschner A. Adv. Funct. Mater., 2003,13:591-596
11. [11]
  [11] Chen C Y, Lu H C, Wu C G, et al. Adv. Funct. Mater., 2007,17:29-36
12. [12]
  [12] Huang W, Tanaka H, Ogawa T, et al. Adv. Mater., 2010,22: 2753-2758
13. [13]
  [13] Ammann M, Rang A, Schalley A, et al. Eur. J. Org. Chem., 2006:1940-1948
14. [14]
  [14] Wu C G, Lu H C, Chen L N, et al. J. Polym. Sci., Part A: Polym. Chem., 2008,46:1586-1597
15. [15]
  [15] Araki K, Endo H, Masuda G, et al. Chem. Eur. J., 2004,10: 3331-3340
16. [16]
  [16] Vos J G, Kelly J M. Dalton Trans., 2006:4869-4883
17. [17]
  [17] Batista R M F, Costa S P G, Belsley M, et al. Dye Pigment., 2009,80:329-336
18. [18]
  [18] Goze C, Sabatini C, Barbieri A, et al. Eur. J. Inorg. Chem., 2008:1293-1299
19. [19]
  [19] Tzalis D, Tor Y. Tetrahedron Lett., 1995,36:6017-6020
20. [20]
  [20] Schafer B, Gorls H, Meyer S, et al. Eur. J. Inorg. Chem., 2007:4056-4063
21. [21]
  [21] Rau S, Fischer R, Jager M, et al. Eur. J. Inorg. Chem., 2004:2001-2003
22. [22]
  [22] Frey J, Kraus T, Heitz V, et al. Chem. Commun., 2005:5310-5312
23. [23]
  [23] Tzalis D, Tor Y. Angew. Chem. Int. Ed., 1997,36:2666-2668
24. [24]
  [24] (a)Hu B, Fu S J, Xu F, et al. J. Org. Chem., 2011,76:4444-4456 (b)Huang W, Masuda G, Maeda S, et al. Chem. Eur. J., 2006,12:607-619 (c)Huang W, Tanaka H, Ogawa T. J. Phys. Chem. C, 2008, 112:11513-11526 (d)Huang W, Masuda G, Maeda S, et al. Inorg. Chem., 2008,47:468-480 (e)Wang L, You W, Huang W, et al. Inorg. Chem., 2009,48: 4295-4305 (f)Huang W, Wang L, Tanaka H, et al. Eur. J. Inorg. Chem., 2009:1321-1320 (g)Zhang B, Cao K S, Xu Z A, et al. Eur. J. Inorg. Chem., 2012:3844-3851 (h)Xu F, Peng Y X, Hu B, et al. CrystEngComm, 2012,14: 8023-8032 (i)HU Bin(胡斌), YAN Liu-Shui(颜流水), ZHANG Ai-Qin (张爱琴). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:2540-2547 (j)Liu Q Q, Geng J, Wang X X, et al. Polyhedron, 2013,59: 52-57 (k)Hu B, Liu Q Q, Tao, T, Zhang K, et al. Inorg. Chim. Acta, 2013,394:576-582 (l)Tao T, Peng Y X, Huang W, et al. J. Org. Chem., 2013, 78:2472-2481
25. [25]
  [25] Wang X L, Chen Y Q, Zhang J X, et al. Z. Anorg. Allg. Chem., 2010,636:830-834
26. [26]
  [26] (a)Zheng C G, Ma C L, Yu X W, et al. Chem. Biodiversity, 2011,8:1486-1496 (b)Karnahl M, Krieck S, Gorls H, et al. Eur. J. Inorg. Chem., 2009:4962-4971 (c)Batista R M F, Costa S P G, Belsley M, et al. Tetrahedron, 2008,64:9230-9238
27. [27]
  [27] Siemens. SAINT v4 Software Reference Manual. Madison, Wisconsin, USA: Siemens Analytical X-Ray Systems, Inc.; 2000.
28. [28]
  [28] Sheldrick G M. SADABS, Program for Empirical Absorption Correction of Area Dectector Data. Germany: Univ. of Gottingen, 2000.
29. [29]
  [29] Siemens. SHELXTL, Version 6.10 Reference Manual. Madison, Wisconsin, USA: Siemens Analytical X-Ray Systems, Inc.; 2000.
1. [1]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
2. [2]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
5. [5]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
6. [6]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
7. [7]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
8. [8]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
9. [9]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
10. [10]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
11. [11]
  Liyang ZHANG , Dongdong YANG , Ning LI , Yuanyu YANG , Qi MA . Crystal structures, luminescent properties and Hirshfeld surface analyses of three cadmium(Ⅱ) complexes based on 2-(3-(pyridin-2-yl)-1H-pyrazol-1-yl)benzoate. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1943-1952. doi: 10.11862/CJIC.20240079
12. [12]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
13. [13]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
14. [14]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
15. [15]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
16. [16]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
17. [17]
  Keweiyang Zhang , Zihan Fan , Liyuan Xiao , Haitao Long , Jing Jing . Unveiling Crystal Field Theory: Preparation, Characterization, and Performance Assessment of Nickel Macrocyclic Complexes. University Chemistry, 2024, 39(5): 163-171. doi: 10.3866/PKU.DXHX202310084
18. [18]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
19. [19]
  Ji Qi , Jianan Zhu , Yanxu Zhang , Jiahao Yang , Chunting Zhang . Visible Color Change of Copper (II) Complexes in Reversible SCSC Transformation: The Effect of Structure on Color. University Chemistry, 2024, 39(3): 43-57. doi: 10.3866/PKU.DXHX202307050
20. [20]
  Tianyun Chen , Ruilin Xiao , Xinsheng Gu , Yunyi Shao , Qiujun Lu . Synthesis, Crystal Structure, and Mechanoluminescence Properties of Lanthanide-Based Organometallic Complexes. University Chemistry, 2024, 39(5): 363-370. doi: 10.3866/PKU.DXHX202312017

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(456)
HTML views(70)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142