Citation: LIU Guang-Xiang. Synthesis, Crystal Structure and Magnetic Property of a Copper(Ⅱ) Coordination Polymer Constructed from Nicotinic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1914-1920. doi: 10.3969/j.issn.1001-4861.2013.00.290 shu

Synthesis, Crystal Structure and Magnetic Property of a Copper(Ⅱ) Coordination Polymer Constructed from Nicotinic Acid

LIU Guang-Xiang

1.
School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University, Nanjing 211171, China

Received Date: 26 January 2013
Available Online: 30 March 2013
Fund Project: 国家自然科学基金(No.20971004, 21271106) (No.20971004, 21271106)教育部科学技术重点项目(No.210102)资助项目。 (No.210102)

A new three-dimensional (3D) coordination polymer of[Cu₂(nic)4(H₂O)]_n (1) (Hnic=nicotinic acid) has been prepared and characterized by elemental analysis, IR spectroscopy, and single-crystal X-ray diffraction. The crystal is of monoclinic, space group P2₁/c with a=1.071 56(3) nm, b=1.958 79(6) nm, c=1.379 50(3) nm, β=104.498 (2)°, V=2.803 31(13) nm³, D_c=1.501 g·cm^-3, Z=4, F(000)=1 280, Goof=1.014, R₁=0.041 7, wR₂=0.113 2. Complex 1 shows a 3D uninodal 5-connected framework with (4⁴·6⁶) topology. Moreover, Magnetic susceptibility measurements demonstrate that complex 1 exhibits antiferromagnetic interaction within the binuclear units. CCDC: 921590.
- Cu(Ⅱ) complex;nicotinic acid;crystal structure;magnetism
1. [1]
  [1] Robin A Y, Fromm K M. Coord. Chem. Rev., 2006,250: 2127-2157
2. [2]
  [2] Hou J Z, Li M, Li Z, et al. Angew. Chem. Int. Ed., 2008,47: 1711-1714
3. [3]
  [3] Blatov V A, Carlucci L, Ciani G, et al. CrystEngComm, 2004, 6:378-395
4. [4]
  [4] Zou R Q, Zhong R Q, Du M, et al. Cryst. Growth Des., 2008, 8:452-459
5. [5]
  [5] Li J R, Yu Q, Saöudo E C, et al. Chem. Mater., 2008,20: 1218-1220
6. [6]
  [6] Gomez-Lor B, Gutiörrez-Puebla E, Iglesias M, et al. Inorg. Chem., 2002,41:2429-2432
7. [7]
  [7] Luo J, Xu H, Liu Y, et al. J. Am. Chem. Soc., 2008,130: 9626-9627
8. [8]
  [8] Coronado E, Day P. Chem. Rev., 2004,104:5419-5448
9. [9]
  [9] Cariati E, Macchi R, Roberto D, et al. J. Am. Chem. Soc., 2007,129:9410-9420
10. [10]
  [10] Mi L, Hou H, Song Z, et al. Chem.-Eur. J., 2008,14:1814-1821
11. [11]
  [11] Bujak M, Angel R J. J. Solid State Chem., 2005,178:2237-2246
12. [12]
  [12] Chen W, Yuan H M, Wang J Y, et al. J. Am. Chem. Soc., 2003,125:9266-9267
13. [13]
  [13] Kahn O, Martinez C J. Science, 1998,279:44-48
14. [14]
  [14] Hagrman P J, Hagrman D, Zubieta J. Angew. Chem. Int. Ed., 1999,38:2639-2684
15. [15]
  [15] Liu F C, Zhao J P, Hu B W, et al. Dalton Trans., 2010,39: 1185-1187
16. [16]
  [16] Cheng J W, Zheng S T, Yang G Y. Inorg. Chem., 2008,47: 4930-4935
17. [17]
  [17] Zhang J, Kang Y, Zhang J, et al. Eur. J. Inorg. Chem., 2006:2253-2258
18. [18]
  [18] Yeh C W, Suen M C, Hu H L, et al. Polyhedron, 2004,23: 1947-1952
19. [19]
  [19] Liu F C, Zeng Y F, Zhao J P, et al. Inorg. Chem., 2007,46: 7698-7700
20. [20]
  [20] Kahn O. Molecular Magnetism. New York: VCH Publishers, Inc., 1993.
21. [21]
  [21] CrysAlisPro, Oxford Diffraction Ltd., Oxfordshire, U. K., 2010.
22. [22]
  [22] Sheldrick G M. SHELXS-97, Program for Crystal Structure Solution, University of Göttingen, Germany, 1997.
23. [23]
  [23] Sheldrick G M. SHELXL-97, Program for the Refinement of Crystal Structure, University of Gttingen, Germany, 1997.
24. [24]
  [24] Köppers H, Lieba F, Spek A L. J. Appl. Crystallogr., 2006,39:338-346
25. [25]
  [25] Gurunatha K L, Maji T K. Eur. J. Inorg. Chem., 2009:1592-1599
26. [26]
  [26] Liu Y H, Tsai H L, Lu Y L, et al. Inorg. Chem., 2001,40: 6426-6431
27. [27]
  [27] Jiang X R, Yuan H Y, Feng Y L. J. Solid State Chem., 2012,191:181-190
28. [28]
  [28] Chen S S, Zhao Y. Fan J, et al. CrystEngComm, 2012,14: 3564-3576
29. [29]
  [29] Gong Y, Li J, Qin J B, et al. Cryst. Growth Des., 2011,11: 1662-1674
30. [30]
  [30] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordinated Compounds. 5th Ed. New York:Wiley & Sons, 1997.
31. [31]
  [31] Colacio E, Ghazi M, Kivekas R, et al. Inorg. Chem., 2000, 39:2882-2890
32. [32]
  [32] Kasumov V T, Köksal F, Sezer A. Polyhedron, 2005,24: 1203-1211
33. [33]
  [33] Psomas G, Raptopoulou C P, Iordanidis L, et al. Inorg. Chem., 2000,39,3042-3048
34. [34]
  [34] Segla P, Palicova M, Miklos D, et al. Z. Anorg. Allg. Chem., 2004,630:470-478
1. [1]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
2. [2]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
3. [3]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
4. [4]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
5. [5]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
8. [8]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
9. [9]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
10. [10]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
11. [11]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
12. [12]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
13. [13]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
14. [14]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
15. [15]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
16. [16]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
17. [17]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
18. [18]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
19. [19]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
20. [20]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(458)
HTML views(84)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142