Citation: LI Shu-Cun, ZHAO Min-Shou, JIAO Ti-Feng. Effect of Addition of Boron on Structure and Electrochemical Characteristic of Ti_0.26Zr_0.07V_0.24Mn_0.1Ni_0.33 Alloy[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(10): 2119-2125. doi: 10.3969/j.issn.1001-4861.2013.00.279 shu

Effect of Addition of Boron on Structure and Electrochemical Characteristic of Ti_0.26Zr_0.07V_0.24Mn_0.1Ni_0.33 Alloy

1.
1 College of Environment and Chemical Engineering, Yanshan University, Qinhuangdao, Hebei 066004, China;

Received Date: 19 January 2013
Available Online: 3 May 2013
Fund Project: 河北省自然科学基金(No.B2010001132)资助项目 (No.B2010001132)

The results show that all alloys are composed of V-based solid solution with body-centered-cube (BCC) structure and C14 Laves phase with hexagonal structure. The addition of Bincreases the discharge capacity of Ti_0.26Zr_0.07V_0.24Mn_0.1Ni_0.33 alloy electrode and Ti_0.26Zr_0.07V_0.24Mn_0.1Ni_0.33B0.1 alloy delivers the discharge capacity of 476.7 mAh·g^-1at discharge current of 60 mA·g^-1. The addition of Bdecreases the high-rate discharge ability of the alloy electrode in some extent. EISindicates that addition of Bdecreases the dynamic performance, which makes the charge transfer resistance (R_ct) increases and the exchange current density (I₀) decreases markedly. Considerable improvement in the high-temperature dischargeability is observed by addition of B, and the discharge capacity is up to 525.6 mAh·g^-1 at 343 Kfor Ti_0.26Zr_0.07V_0.24Mn_0.1Ni_0.33B_0.025 alloy electrode.
- hydrogen storage alloy; electrochemical characteristics; boron
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Effect of Addition of Boron on Structure and Electrochemical Characteristic of Ti0.26Zr0.07V0.24Mn0.1Ni0.33 Alloy

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通讯作者: 陈斌, bchen63@163.com

Effect of Addition of Boron on Structure and Electrochemical Characteristic of Ti_0.26Zr_0.07V_0.24Mn_0.1Ni_0.33 Alloy