Citation: WU Bao-Ming, YE Nai-Qing, MA Zhen, HAN Jian-Feng, XU Dong. Low Temperature Combustion Synthesis and Electrochemical Performance of xLi₂MnO_3^-(1-x)LiNi_0.7Co_0.3O₂[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1835-1841. doi: 10.3969/j.issn.1001-4861.2013.00.275 shu

Low Temperature Combustion Synthesis and Electrochemical Performance of xLi₂MnO_3^-(1-x)LiNi_0.7Co_0.3O₂

WU Bao-Ming ¹ ,
YE Nai-Qing ^1,2 ,
MA Zhen ¹ ,
HAN Jian-Feng ¹ ,
XU Dong ¹

1.
1 College of Material Science and Engineering, Guilin University of Technology, Guilin, Guangxi 541004, China;

Received Date: 9 March 2013
Available Online: 19 April 2013
Fund Project: 广西自然科学基金(No.0832256) (No.0832256)广西研究生教育创新计划(No.2011105960805M16)资助项目。 (No.2011105960805M16)

The cathode materials for lithium ion batteries xLi₂MnO_3^-(1-x)LiNi_0.7Co_0.3O₂ were prepared via low temperature combustion process. The structure, morphology and electrochemical performance of the synthesized materials were studied systematically. The optimal preparing conditions and the optimal ratio of Li₂MnO₃ for the cathode materials were studied by single factor experiment. The experimental results show that the synthesized products have α-NaFeO₂ layered structure, sphere-like morphology and excellent electrochemical performance; the optimal conditions to prepare these materials are to reheat the combustion products at 850℃ for 20 h, the optimal ratio of Li₂MnO₃ is x=0.7. The cathode material 0.7Li₂MnO₃-0.3LiNi_0.7Co_0.3O₂ synthesized under such conditions has the highest discharge capacity of 263.1 mAh·g^-1, excellent cycle and rate performance.
- Lithium-ion batteries;cathode material;xLi₂MnO_3^-(1-x)LiNi_0.7Co_0.3O₂;low temperature combustion synthesis
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通讯作者: 陈斌, bchen63@163.com

Low Temperature Combustion Synthesis and Electrochemical Performance of xLi₂MnO_3^-(1-x)LiNi_0.7Co_0.3O₂