Citation: HU Tuo-Ping, LIU Jian-Feng, LÜ Xu-Yan, XIAO Li-Qun, SONG Jiang-Feng. Syntheses, Crystal Structures and Fluorescent Properties of Two Complexes (Zn(Ⅱ) and Co(Ⅱ)) Based on 2H-Imidazole-4, 5-dicarbonitrile[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(9): 1928-1934. doi: 10.3969/j.issn.1001-4861.2013.00.270 shu

Syntheses, Crystal Structures and Fluorescent Properties of Two Complexes (Zn(Ⅱ) and Co(Ⅱ)) Based on 2H-Imidazole-4, 5-dicarbonitrile

1.
Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China

Received Date: 9 October 2013
Available Online: 1 May 2013
Fund Project: 国家国际科技合作(No.2011DFA51980) (No.2011DFA51980)省自然科学基金(No.2011081022)资助项目。 (No.2011081022)

Two novel metal-organic complexes {[Zn₂(IMDN)₄(H₂O)₃]·(H₂O)₃}_n (1) and[Co(IMDN)₂(H₂O)₂]_n (2) (HIMDN=2H-imidazole-4,5-dicarbonitrile) based on HIMDN have been synthesized by the method of normal temperature diffusion, and characterized by elemental analysis, FTIR, thermal gravimetric analysis and X-ray diffraction single-crystal structural analysis. The coordination environment of two Zn (Ⅱ) ions is different in 1. One Zn (Ⅱ) ion is four-coordinated and the other is six-coordinated. The central Co (Ⅱ) ion is six-coordinated in 2. Both complexes show one dimensional (1D) chain structure and connected by hydrogen bonds to form three-dimensional structure. Moreover, the fluorescent property of complex 1 had been investigated in the solid state. CCDC: 889348, 1; 889349, 2.
- 2H-imidazole-4,5-dicarbonitrile;1D chain;crystal structure;fluorescence
1. [1]
  [1] Moulton B, Zaworotko M J. Chem. Rev., 2001,101:1629-1658
2. [2]
  [2] Kitagawa S, Kitaura R, Noro S I. Angew., Chem. Int. Ed., 2004,43:2334-2375
3. [3]
  [3] Evans O R, Lin W. Acc. Chem. Res., 2002,35:511-522
4. [4]
  [4] Zhang J P, Chen X M. J Am. Chem. Soc., 2008,130:6010-6017
5. [5]
  [5] Michael O K. Chem. Soc. Rev., 2009,38:1215-1217
6. [6]
  [6] Sarah E J, Bowman, Kara L B. Inorg. Chem., 2010,49(17): 7890-7897
7. [7]
  [7] Telfer S G, Kuroda R. Coord. Chem. Rev., 2003,242:33-46
8. [8]
  [8] Maji T K, Matsuda R, Kitagawa S A. Nature Mater., 2007,6: 142-148
9. [9]
  [9] Sano T, Negishi N, Koike K, et al. J. Mater. Chem., 2004, 14:380-384
10. [10]
  [10] Hu T P, Bi W H, Hu X Q, et al. Cryst. Growth Des., 2010, 10:3324-3326
11. [11]
  [11] Hu T P, Bi W H, Sun D F, et al. RSC Adv., 2011,1:1682-1686
12. [12]
  [12] HU Xiao-Qin(胡晓琴). Thesis for the Master of North University of China(中北大学硕士论文). 2011.
13. [13]
  [13] Akihiro T, Takuya K, Hiroshi F. Inorg. Chem., 2009,48(6): 2614-2625
14. [14]
  [14] Yang H, Chen J M, Sun J J, et al. Dalton Trans., 2009: 2540-2551
15. [15]
  [15] Akordi M H, Liu Y L, Larsen R W, et al. J. Am. Chem. Soc., 2008,130:12639-12641
16. [16]
  [16] Lu W G, Su C Y, Lu T B, et al. J. Am. Chem. Soc., 2006, 128:34-35
17. [17]
  [17] REN Chun-Xia(任春霞). Thesis for the Doctorate of Zhongshan University(中山大学硕士论文). 2004.
18. [18]
  [18] Prasad B L V, Sato H, Enoki T, et al. Chem. Soc., Dalton Trans., 1999:25-30
19. [19]
  [19] Sheldrick G M. SADABS 2.05, University of Göttingen, Germany.
20. [20]
  [20] Sheldrick G M. SHELXL97, Program for the Refinement of Crystal Structure, University of Gottingen, Germany, 1997.
21. [21]
  [21] Sheldrick G M. SHELXL97, Program for the Refinement of Crystal Structure, University of Gottingen, Germany, 1997.
22. [22]
  [22] SONG Jin-Hao(宋金浩), GU Ya-Kun(顾雅琨), LI Xia(李夏). Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2010,26(8): 1457-1462
23. [23]
  [23] ZHANG Deng-Qing(张灯青), ZHANG Wen-Hua(张文华), CHEN Jin-Xiang(陈金香). Acta Chimica Sinica (Huaxue Xuebao), 2005.63(22):2089-2092
24. [24]
  [24] Zhang B S, Zheng M, Wu C S, et al. Chinese J. Struct. Chem., 2012,4:577-581
25. [25]
  [25] Fu Z Y, Wu X T, Dai J C, et al. Eur. J. Inorg. Chem., 2002: 2730-2735
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沈阳化工大学材料科学与工程学院沈阳 110142