Citation: WANG Hui-Sheng, PAN Zhi-Quan. Synthesis, Crystal Structure, and Magnetic Properties of a Mn-Ce Mixed-Metal Complex Containing Benzoic Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1459-1464. doi: 10.3969/j.issn.1001-4861.2013.00.255 shu

Synthesis, Crystal Structure, and Magnetic Properties of a Mn-Ce Mixed-Metal Complex Containing Benzoic Ligands

1.
Key Laboratory for Green Chemical Process of Ministry of Education, School of Chemical Engineering & Pharmacy, Wuhan Institute of Technology, Wuhan 430073, China

Received Date: 1 December 2012
Available Online: 9 May 2013
Fund Project: 国家自然科学基金(No.21201136) (No.21201136)武汉工程大学科学研究基金(No.10122012)资助项目。 (No.10122012)

In this paper, a novel Mn-Ce mixed-metal complex [Mn₃Ce₂(O)₅(O₂CPh)₉(CH₃OH)₃]·2CH₃CN (1·2CH₃CN, HO₂CPh is benzoic acid) has been synthesized using the synthetic method of oxidation Mn²⁺ ions by (NH₄)₂Ce(NO₃)₆. The obtained complex were fully characterized by X-ray single crystal structural diffraction, IR, elemental analysis, and magnetic investigation. The structure analysis indicates that the complex crystallizes in triclinic system, P1 space group. In the complex, two Mn⁴⁺ ions, two Ce⁴⁺ ions and four bridging μ₃-O atoms comprise an irregular cubane which is further linked to the other Mn³⁺ ion by another μ₃-O atom. There are no hydrogen bonds but slightly strong π-π stacking interactions between clusters in the crystal cell. Magnetic investigation shows that weak ferromagnetic interactions between Mn ions are present within the cluster, and the values of the spin ground state S and magnetic anisotropy are 5 and-0.31 cm^-1, respectively. The complex do not possess frequency-dependent on alternating-current magnetic susceptibilities. CCDC: 912993.
- Mn-Ce mixed-metal complex;crystal structure;magnetic property;benzoic acid
1. [1]
  [1] Aromí G, Brechin E K. Struct. Bonding(Berlin), 2006,122:1-67
2. [2]
  [2] Gatteschi D, Sessoli R. Angew. Chem. Int. Ed., 2003,42:268-297
3. [3]
  [3] Wernsdorfer W, Soler M, Christou G, et al. J. Appl. Phys., 2002,91:7164-7166
4. [4]
  [4] WANG Tian-Wei(王天维), LIN Xiao-Ju(林小驹), WEI Ji-Zong(韦吉宗), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2002,18(11):1071-1080
5. [5]
  [5] Wemple M W, Tsai H L, Claude J P, et al. Inorg. Chem., 1996,35:6437-6449
6. [6]
  [6] Tasiopoulos A J, Wernsdorfer W, Abboud K A, et al. Angew. Chem. Int. Ed., 2004,43:6338-6342
7. [7]
  [7] Liu C M, Zhang D Q, Zhu D B. Inorg. Chem., 2009,48:792-794
8. [8]
  [8] Ma Y S, Song Y, Li Y Z, et al. Inorg. Chem., 2007,46:5459-5461
9. [9]
  [9] Ramalakshmi D, Rajasekharan M V. Acta Cryst., 1999,B55: 186-191
10. [10]
  [10] Tasiopoulos A J, Jr P L M, Abboud K A, et al. Inorg. Chem., 2007,46:9678-9691
11. [11]
  [11] Tasiopoulos A J, O'Brein T A, Abboud K A, et al. Angew. Chem. Int. Ed., 2004,43:345-349
12. [12]
  [12] Milios C J, Wood P A, Parsons S, et al. Inorg. Chim. Acta, 2007,360:3932-3940
13. [13]
  [13] Mishra A, Tasiopoulos A J, Wernsdorfer W, et al. Inorg. Chem., 2008,47:4832-4843
14. [14]
  [14] Mishra A, Tasiopoulos A J, Wernsdorfer W, et al. Inorg. Chem., 2007,46:3105-3115
15. [15]
  [15] Wang H S, Ma C B, Wang M, et al. J. Mol. Struct., 2008, 875:288-294
16. [16]
  [16] Wemple M W, Tsai H L, Wang S, et al. Inorg. Chem., 1996, 35:6437-6449
17. [17]
  [17] Canty A J, Minchin N J, Patrick J M, et al. Dalton Trans., 1983:1253-1259
18. [18]
  [18] SAINT-Plus, Version 6.02; Bruker Analytical X-ray System: Madison, WI, 1999.
19. [19]
  [19] Sheldrick G M. SADABS: An Empirical Absorption Correction Program; Bruker Analytica X-ray Systems, Madison, WI, 1996.
20. [20]
  [20] Sheldrick G M. SHELXTL-97; Universität of Göttingen, Göttingen, Germany, 1997.
21. [21]
  [21] Liu W, Thorp H H. Inorg. Chem., 1993,32:4102-4105
22. [22]
  [22] Brown I D, Shannon R D. Acta Crystallogr., 1973,A29:266-282
23. [23]
  [23] Roulhac P L, Palenik G J. Inorg. Chem., 2003,42:118-121
24. [24]
  [24] Benelli C, Gatteschi D. Chem. Rev., 2002,102:2369-2387
25. [25]
  [25] Borras-Almenar J J, Clemente-Juan J M, Coronado E, et al. Inorg. Chem., 1999,38:6081-6088
26. [26]
  [26] Shores M P, Sokol J J, Long J R. J. Am. Chem. Soc., 2002, 124:2279-2292
1. [1]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
2. [2]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
3. [3]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
4. [4]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
5. [5]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
6. [6]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
7. [7]
  Ling Liu , Haibin Wang , Genrong Qiang . Curriculum Ideological and Political Design for the Comprehensive Preparation Experiment of Ethyl Benzoate Synthesized from Benzyl Alcohol. University Chemistry, 2024, 39(2): 94-98. doi: 10.3866/PKU.DXHX202304080
8. [8]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
9. [9]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
10. [10]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
11. [11]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
12. [12]
  Xin XIONG , Qian CHEN , Quan XIE . First principles study of the photoelectric properties and magnetism of La and Yb doped AlN. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1519-1527. doi: 10.11862/CJIC.20240064
13. [13]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
14. [14]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
15. [15]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
16. [16]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
17. [17]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
18. [18]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
19. [19]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
20. [20]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(433)
HTML views(41)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142