Citation: GUO Hai-Fu, PAN Yong, MA De-Yun, YAN Peng. Effect of Electron-Withdrawing Groups of Schiff Base and Its Palladium Complex on Antimicrobial and Catalytic Activities[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1447-1453. doi: 10.3969/j.issn.1001-4861.2013.00.240 shu

Effect of Electron-Withdrawing Groups of Schiff Base and Its Palladium Complex on Antimicrobial and Catalytic Activities

GUO Hai-Fu ¹ ,
PAN Yong ^1,2 ,
MA De-Yun ¹ ,
YAN Peng ¹

1.
1 College of Chemistry and Chemical Engineering, Zhaoqing University, Zhaoqing, Guangdong 5260621, China;

Received Date: 25 October 2012
Available Online: 6 February 2013
Fund Project: 肇庆市科技创新计划项目(No.2009G013)资助项目。 (No.2009G013)

Two Schiff Bases (L1 and L2) and their palladium complexes (1 and 2) were prepared by the condensation of 2,6-diisopropylaniline with benzaldehyde and 2,4-dichlorobenzaldehyde, respectively, and characterized by elemental analysis, IR-spectroscopy and single crystal X-ray diffraction. Compared with known structures of Schiff base (L1) and its palladium complex (1), we discovered that the introduction of electro-withdrawing groups of L2 and complex 2 have effects on antimicrobial and catalytic activities. The antimicrobial activities results indicated that the ligands and their complexes perform good activities, and the complexes have better effect than the ligands, and the electro-withdrawing groups will effectively improve the activities. The Heck reactions of bromobenzene with acrylic acid catalyzed by complex 1 and 2 have also been studied. We have investigated the effect of different factors (bases, temperature and solvent) on reaction and finally determined the optimum reaction condition. The catalytic activities results shown that the electro-withdrawing groups of ligands will increase the steric effect of 1 and 2, and reducing their activities. CCDC: 882286,L1; 882287, 2; 222403, 1; 882289, 2.
- Schiff bases;palladium complexes;crystal structures;antimicrobial activity;catalytic activity
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