Citation: CHEN Xiao-Hua, WU Qiong-Jie, LU Wei, YANG Ming-Xing, CHEN Li-Juan. Syntheses and Crystal Structures of Two Vanadium Complexes with Salicyloylhydrazone Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1521-1526. doi: 10.3969/j.issn.1001-4861.2013.00.235 shu

Syntheses and Crystal Structures of Two Vanadium Complexes with Salicyloylhydrazone Ligands

1.
1 College of Materials Science and Engineering, Fujian Normal University, Fuzhou 350007, China;

Received Date: 4 September 2012
Available Online: 24 February 2013
Fund Project: 福建省教育厅课题(No.JB10007)资助项目。 (No.JB10007)

Two new V(V) complexes, [VOL¹(C₂H₅O)]₂(1) (H₂L¹=2-hydroxyacetophenone salicyloylhydrazone) and [VOL²(i-C₃H₇O)](2) (H₂L²=salicylaldehyde salicyloylhydrazone) have been synthesized and characterized by elemental analysis, IR, UV and X-Ray diffraction. Complex 1 reveals a centrosymmetric dimer, in which the two vanadium centers are bridged by phenolic oxygen atoms. Each vanadium(V) in 1 exhibits a slightly distorted octahedral geometry. While complex 2 is a mononuclear structure, in which vanadium(V) has a distorted square-pyramidal geometry. Complex 2 forms an infinite 1D chain-like supramolecular structure by intermolecular hydrogen bonds. The electrochemical property for complex 2 was studied with an electrochemical analyzer. CCDC: 889674, 1; 889675, 2.
- hydrazone;vanadium(V) complex;crystal structure
1. [1]
  [1] Murphy T B, Rose N J, Schomaker V, et al. Inorg. Chim. Acta, 1985,108:183-194
2. [2]
  [2] Seena E B, Mathew N, Kuriakose M, et al. Polyhedron, 2008,27:1455-1462
3. [3]
  [3] Ghosh T, Mondal B, Ghosh T, et al. Inorg. Chim. Acta, 2007, 360:1753-1761
4. [4]
  [4] Kuriakose M, Kurup M R P, Suresh E. Polyhedron, 2007,26: 2713-2718
5. [5]
  [5] LI Lian-Zhi(李连之), XU Tao(许涛), WANG Da-Qi(王大奇), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2004,20:236-240
6. [6]
  [6] Liu S X, Gao S. Polyhedron, 1998,17,81-84
7. [7]
  [7] DENG Zhao-Peng(邓兆鹏), GAO Shan(高山), ZHAO Hui (赵辉), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2007,23:173-176
8. [8]
  [8] Huang S M, Jiang F F, Chen X H, et al. Acta Cryst., 2010, E66:m456
9. [9]
  [9] LIU Jiu-Hui(刘九辉), WU Xiao-Yuan(吴小园), ZHANG Quan-Zheng(张全争), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2006,22:1028-1032
10. [10]
  [10] Sheldrick G M. SHELXS-97, Program for X-ray Crystal Structure Solution, University of Göttingen, Germany, 1997.
11. [11]
  [11] Sheldrick G M. SHELXL-97, Program for X-ray Crystal Structure Refinement, University of Göttingen, Germany, 1997.
12. [12]
  [12] Palacios M S, Rocio M J, Domnguez S, et al. Polyhedron, 1997,16:1143-1147
13. [13]
  [13] Monfared H H, Kheirabadi S, Lalami N A, et al. Polyhedron, 2011,16:1375-1384
14. [14]
  [14] Chen X H, Wu Q J, Liang Z Y, et al. Acta Cryst., 2009, C65:m190-m194
15. [15]
  [15] WU Qiong-Jie(吴琼洁), CHEN Xiao-Hua(陈小华), CAI Bi-Qiong(蔡碧琼), et al. Chinese J. Inorg. Chem. (Wuji Huaxue Xuebao), 2012,28:201-206
16. [16]
  [16] Addison A W, Rao T N, Reedijk J, et al. J. Chem. Soc., Dalton Trans., 1984:1349-1356
17. [17]
  [17] Monfared H H, Kheirabadi S, Lalami, et al. Polyhedron, 2011,30:1375-1384
18. [18]
  [18] Sutradhar M, Mukherjee G, Drew M G B, et al. Inorg. Chem., 2006,45:5150-5161
19. [19]
  [19] Gao S, Weng Z Q, Liu S X. Polyhedron, 1998,17,3595-3606
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沈阳化工大学材料科学与工程学院沈阳 110142