Citation: LIN Zi-Xia, WANG Gang, ZHENG Ming-Bo, ZHAO Bin, LI Nian-Wu, PU Lin, SHI Yi. Ultra-Long-Term Cyclability of Li₄Ti₅O₁₂/Graphene Nanocomposite Anode Material with Three-Dimensional Continuous Structure for Lithium-Ion Batteries[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1465-1470. doi: 10.3969/j.issn.1001-4861.2013.00.232 shu

Ultra-Long-Term Cyclability of Li₄Ti₅O₁₂/Graphene Nanocomposite Anode Material with Three-Dimensional Continuous Structure for Lithium-Ion Batteries

1.
Nanjing National Laboratory of Microstructures, School of Electronic Science and Engineering, Nanjing University, Nanjing 210093, China

Received Date: 28 January 2013
Available Online: 10 April 2013
Fund Project: 国家重点基础研究发展计划(No.2013CB932900,2011CB922100) (No.2013CB932900,2011CB922100)国家自然科学基金(No.51202106,60990314,61106089) (No.51202106,60990314,61106089)江苏省自然科学基金(No.KB2011011)资助项目。 (No.KB2011011)

Li₄Ti₅O₁₂/graphene nanocomposite was synthesized using thermally exfoliated graphene with a three-dimensional continuous nanoporous structure as the matrix. The precursors were introduced into the interior nanopores of thermally exfoliated graphene by the ethanol evaporation method. After heat treatment, Li₄Ti₅O₁₂ nanoparticles were formed in situ in the nanopores of thermally exfoliated graphene. As an anode material for lithium-ion batteries, the three-dimensional continuous structure of thermally exfoliated graphene ensures sufficient contact between Li₄Ti₅O₁₂ and graphene during the long cycling. Consequently, the nanocomposite shows superior cyclic stability. The capacity retention is still as high as 94% after 5 000 cycles at 5C.
- Li₄Ti₅O₁₂;graphene;nanocomposite;anode;lithium-ion battery
1. [1]
  [1] Armand M, Tarascon J M. Nature, 2008,451:652-657
2. [2]
  [2] Amine K, Belharouak I, Chen Z, et al. Adv. Mater., 2010, 22:3052-3057
3. [3]
  [3] Kang E, Jung Y S, Kim G H, et al. Adv. Funct. Mater., 2011,21:4349-4357
4. [4]
  [4] Feckl J M, Fominykh K, Dölinger M, et al. Angew. Chem. Int. Ed., 2012,51:7459-7463
5. [5]
  [5] Wang Y G, Liu H M, Wang K X, et al. J. Mater. Chem., 2009,19:6789-6795
6. [6]
  [6] JIANG Zhi-Jun(蒋志军), LIU Kai-Yu(刘开宇), CHEN Yun-Yang(陈云扬), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27(2):239-244
7. [7]
  [7] Yi T F, Xie Y, Zhu Y R, et al. J. Power Sources, 2013,222: 448-454
8. [8]
  [8] Wang H, Cui L F, Yang Y, et al. J. Am. Chem. Soc., 2010, 132:13978-13980
9. [9]
  [9] Yang S, Feng X, Ivanovici S, et al. Angew. Chem. Int. Ed., 2010,49:8408-8411
10. [10]
  [10] CUI Yong-Li(崔永丽), XU Kun(徐坤), YUAN Zheng(袁铮), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2013, 29(1):50-56
11. [11]
  [11] NIU Yu-Lian(牛玉莲), JIN Xin(金鑫), ZHENG Jia(郑佳), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012, 28(9):1878-1884
12. [12]
  [12] JIN Li(金莉), SUN Dong(孙东), ZHANG Jian-Rong(张剑荣). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28(6): 1084-1090
13. [13]
  [13] Kim H K, Bak S M, Kim K B. Electrochem. Commun., 2010,12:1768-1771
14. [14]
  [14] Shen L, Yuan C, Luo H, et al. Nanoscale, 2011,3:572-574
15. [15]
  [15] Jian Z, Zhao L, Wang R, et al. RSC Adv., 2012,2:1751-1754
16. [16]
  [16] Han S Y, Kim I Y, Jo K Y, et al. J. Phys. Chem. C, 2012, 116:7269-7279
17. [17]
  [17] Tang Y, Huang F, Zhao W, et al. J. Mater. Chem., 2012,22: 11257
18. [18]
  [18] Shi Y, Wen L, Li F, et al. J. Power Sources, 2011,196:8610-8617
19. [19]
  [19] Xiang H, Tian B, Liao P, et al. J. Alloys Compd., 2011,509: 7205-7209
20. [20]
  [20] Zhu N, Liu W, Xue M, et al. Electrochim. Acta, 2010,55: 5813-7209
21. [21]
  [21] Du Q L, Zheng M B, Zhang L F, et al. Electrochim. Acta, 2010,55:3897-3903
22. [22]
  [22] Qiu D F, Xu Z J, Zheng M B, et al. J. Solid State Electrochem., 2012,16:1889-1892
23. [23]
  [23] Zheng M B, Qiu D F, Zhao B, et al. RSC Adv., 2013,3:699-703
24. [24]
  [24] Yi T F, Jiang L J, Shu J, et al. J. Phys. Chem. Solids, 2010, 71:1236-1242
25. [25]
  [25] Zhu G N, Wang Y G, Xia Y Y. Energy Environ. Sci., 2012, 5:6652-6667
26. [26]
  [26] Cao Q, Zhang H P, Wang G J, et al. Electrochem. Comm., 2007,9:1228-1232
27. [27]
  [27] Yi T F, Liu H P, Zhu Y R, et al. J. Power Sources, 2012, 215:258-265
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沈阳化工大学材料科学与工程学院沈阳 110142

Ultra-Long-Term Cyclability of Li4Ti5O12/Graphene Nanocomposite Anode Material with Three-Dimensional Continuous Structure for Lithium-Ion Batteries

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通讯作者: 陈斌, bchen63@163.com

Ultra-Long-Term Cyclability of Li₄Ti₅O₁₂/Graphene Nanocomposite Anode Material with Three-Dimensional Continuous Structure for Lithium-Ion Batteries