Citation: YUAN Zhuang-Dong, ZHOU Fang-Xia, ZHANG Hui-Ping, YUE Cheng-Yang. Syntheses, Crystal Structures and Luminescent Properties of Two Au(Ⅰ) Complexes Containing 2-Mecaptopyridine-1-oxygen[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1283-1288. doi: 10.3969/j.issn.1001-4861.2013.00.224 shu

Syntheses, Crystal Structures and Luminescent Properties of Two Au(Ⅰ) Complexes Containing 2-Mecaptopyridine-1-oxygen

1.
Key Laboratory of Inorganic Chemistry in Universities of Shandong, Department of Chemistry and Chemical Engineering, Jining University, Qufu, Shandong 273155, China

Received Date: 1 December 2012
Available Online: 28 February 2013
Fund Project: 国家自然科学基金(No.21101075,21201081) (No.21101075,21201081)山东省优秀中青年科学家科研奖励基金(No.BS2011CL009,BS2012CL008) (No.BS2011CL009,BS2012CL008)山东省高等学校科技计划(No.J11LB52) (No.J11LB52)济宁学院青年科研基金(No.2011QNKJ07) (No.2011QNKJ07)济宁学院“国家级基金计划预研课题(No.2011YYJJ06和2011YYJJ07)”资助项目。 (No.2011YYJJ06和2011YYJJ07)

Two new Au(Ⅰ) complexes, namely, (ph₃P)Au(mpo) (1) and [Au(mpo)₂][Na(H₂O)₄]·H₂O (2) have been synthesized via the reaction of (ph₃P)AuCl with 2-mercaptopyridine-1-oxide sodium (Nampo) in dichloromethane (CH₂Cl₂) solution. Their crystal structures have been determined by elemental analysis and single-crystal X-ray diffraction studies. Complex 1 crystallizes in the monoclinic system, space group P2₁/c, and features isolated (ph₃P)Au(mpo) molecules. Complex 2 crystallizes in the orthorhombic system, space group Pnma. The structure of complex 2 features three-dimensional (3D) network composed of Au(mpo)₂ units, 1D Na(H₂O)₄ belt as well as isolated H₂O molecules interlinked via weak hydrogen bonds. Complex 2 exhibits blue emission with λ_max=423.5 nm by irradiation of UV light (λ=300 nm). CCDC: 932336, 1; 932337, 2.
- 2-mecaptopyridine-1-oxyge;Au(Ⅰ) complex;luminescence
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沈阳化工大学材料科学与工程学院沈阳 110142