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Citation: GU Jin-Zhong, SHAO Yong-Liang, ZHU Kong-Yang. Synthesis, Crystal Structure and Magnetic Properties of a Nd(Ⅲ) Coordination Polymer Constructed by 3-Carboxyphenoxyacetate and 1,10-Phenanthroline[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1480-1484. doi: 10.3969/j.issn.1001-4861.2013.00.223 shu

Synthesis, Crystal Structure and Magnetic Properties of a Nd(Ⅲ) Coordination Polymer Constructed by 3-Carboxyphenoxyacetate and 1,10-Phenanthroline

  • 1.

    Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Provinc, College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China

  • Received Date: 16 February 2012
    Available Online: 31 January 2013

    Fund Project: 国家自然科学基金(No.21071068)资助项目。 (No.21071068)

  • Under hydrothermal conditions, NdCl3·6H2O reacts with 3-H2CPOA (3-H2CPOA=3-carboxyphenoxyace-tatic acid) and phen (phen=1,10-phenanthroline), producing a novel coordination polymer [Nd(3-CPOA)1.5(phen)]n (1). Complex 1 crystallizes in monoclinic space group P21/c, with a=0.982 7(8),b=1.140 6(10), c=2.115 8(19) nm, β=90.574(9)°, V=2.371(4) nm3, and Z=4. X-ray diffraction studies show that complex 1 possesses a three-dimensional framework structure based on a binuclear unit. Magnetic studies for complex 1 indicate the presence of stronger antiferromagnetic coupling between the adjacent Nd(Ⅲ) ions. CCDC: 888765.
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