Citation: CUI Hong-Xia. Synthesis and Magnetic Property of a Novel Tetracyanonickelate(Ⅱ) Complex with Discrete Water Cluster (H₂O)₄[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1485-1489. doi: 10.3969/j.issn.1001-4861.2013.00.217 shu

Synthesis and Magnetic Property of a Novel Tetracyanonickelate(Ⅱ) Complex with Discrete Water Cluster (H₂O)₄

CUI Hong-Xia

1.
Department of Chemistry and Chemical Engineering, Shengli College China University of Petroleum, Dongying, Shandong 257097, China

Received Date: 23 April 2012
Available Online: 4 March 2013

A tetracyanonickelate-nickel complex {[Ni(i-Pr₃TACN)][Ni(CN)₄]}₂·2H₂O (1) has been synthesized by self-assembly using K₂[Ni(CN)₄] and [NiPr₃TACN]Cl₂, (i-Pr₃TACN=1,4, 7-Triisopropyl-1,4,7-Triazacyclononane). The X-ray character shows there is a discrete tetramer water clusters in 1. Within the cluster, the four water molecules are fully coplanar and each water monomer acts as both single hydrogen bond donor and acceptor. The magnetic susceptibility shows an antiferromagnetic interaction between the Ni(Ⅱ) ions and the J values is -1.09 cm^-1. CCDC: 727702.
- tetracyanonickelate;crystal structure;water cluster;magnetic property
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Synthesis and Magnetic Property of a Novel Tetracyanonickelate(Ⅱ) Complex with Discrete Water Cluster (H₂O)₄