Citation: XIE Feng-Xia, ZHANG Xin-Xin, ZHANG Dan, HUA Min, ZHANG Feng-Xing. Synthesis, Structure and Properties of Sm(Ⅲ) and Dy(Ⅲ) Complexes with Pyridine-2,5-dicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1497-1503. doi: 10.3969/j.issn.1001-4861.2013.00.214 shu

Synthesis, Structure and Properties of Sm(Ⅲ) and Dy(Ⅲ) Complexes with Pyridine-2,5-dicarboxylic Acid

1.
1 College of Environment and Chemical Engineer, Xi'an Polytechnic Univercity, Xi'an 710048, China;

Received Date: 22 May 2012
Available Online: 6 March 2013
Fund Project: 西安工程大学校科研启动基金(No.BS0902)资助项目。 (No.BS0902)

Two new Lanthanide complexes [Ln(pydc)₂(H₂O)₅]·4H₂O (Ln=Sm (1), Dy (2)) were obtained by the hydrothennal reactions of Ln(NO₃)₃·6H₂O, pyridine-2,5-dicarboxylic acid (H₂pydc) with 1:1 mole ratio. Single-crystal X-ray diffraction analysis reveals that both the crystals belong to monoclinic,space group C2/c. The structure and property of complexes have been characterized by elemental analysis, thermal analyses, IR spectra and Fluorescence. The single crystal structures show that the two complexes are isomorphic and have zero-dimensional structures and hydrogen bonds result in three-dimensional supramolecular structures. the coordination number of central ion Ln(Ⅲ) is nine. The complex 1 and 2 exhibit intense luminescence in the liquid state at room temperature. CCDC: 869044, 1; 874032, 2.
- lanthanide;coordination complex;carboxylic acid;thermalsynthesis;fluorescence
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