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Citation: CHU Zhao-Hua, CHEN Yan-Min, XIE Qing-Fan. Syntheses, Crystal Structures and Magnetic Properties of Two 3d-4f Heterometallic Complexes [Fe(phen)3]2[FeLn(H2O)(tiron)3]·6H2O (Ln=HoⅢ, YbⅢ)[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1385-1390. doi: 10.3969/j.issn.1001-4861.2013.00.213 shu

Syntheses, Crystal Structures and Magnetic Properties of Two 3d-4f Heterometallic Complexes [Fe(phen)3]2[FeLn(H2O)(tiron)3]·6H2O (Ln=HoⅢ, YbⅢ)

  • 1.

    1 Department of Chemistry, HanShan Normal University, Chaozhou, Guangdong 521041, China;

  • Received Date: 1 July 2012
    Available Online: 2 February 2013

    Fund Project: 广东省科技厅科技项目(No.2011B090400521) (No.2011B090400521)福建省科技厅科技项目(No.2008F5053)资助项目。 (No.2008F5053)

  • Two isostructural heteronuclear complexes [Fe(phen)3]2[FeLn(H2O)(tiron)3]·6H2O (Ln=Ho (1) and Yb (2)), Na2H2tiron=disodium 4,5-dihydro-xybenzene-1,3-disulfonate) were self-assembly synthesized via hydrothermal reaction. The complexes crystallized in the cubic system, space group P213. In [FeLn(H2O)(tiron)3]6-unit was revealed that the Fe3+ ion is in a FeO6 distorted trigonal anti-prism coordination polyhedron completed by six phenolate O atoms from three tiron4-ligands, and Ln3+ in a LnO7 distorted monocapped trigonal anti-prism coordination polyhedron completed by three phenolate μ2-O atoms and three O atoms from sulfonate groups of three ligands and one O atom from coordinated water. The [Fe(phen)3]3+ cations and [FeCe(tiron)3]6-anions via π-π interaction between phen ligands and electric attraction between cations and anions was assembled into multi-dimensional supramolecule. The magnetic properties of the complexes were been determined in the temperature range 2~300 K, indicating that the antiferromagnetic interaction between the central Ln(Ⅲ)-Fe(Ⅲ) ions. CCDC: 866880, 1; 867589, 2.
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    1. [1]

      [1] Kahn O. Molecular Magnetism. New York: VCH, 1993.

    2. [2]

      [2] Miller J S, Drillon M, Ed. Magnetism: Molecules to Materials: Vol.Ⅰ-Ⅳ. Weinheim: Wiley-VCH, 2003.

    3. [3]

      [3] Sessoli R, Powell A K. Coord. Chem. Rev., 2009,253:2328-2341

    4. [4]

      [4] WANG Cai-Feng(王彩凤), LIU Wei(刘玮), LI Yi-Zhi(李一 志), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24:1017-1022

    5. [5]

      [5] Koo B H, Lim K S, Ryu D W, et al. Chem. Commun., 2012, 48:2519-2523

    6. [6]

      [6] LIN Shuang-Yan(林双燕), GUO Yun-Nan(郭云南), XU Gong-Feng(许公峰), et al. Chinese J. Applied Chemistry(Yingyong Huaxue), 2010,27(12):1365-1371

    7. [7]

      [7] Andruh M, Costes J P, Diaz C, et al. Inorg. Chem., 2009,48 (8):3342-3359

    8. [8]

      [8] JIANG Xiao-Yu(蒋晓瑜), CHEN Wen-Zhe(陈文哲). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24:1650-1656

    9. [9]

      [9] Gurunatha K L, Mostafa G, Ghoshal D, et al. Cryst. Growth Des., 2010(6):2483-2489

    10. [10]

      [10] Zhang W, Zhao F, Liu T, et al. Sci. China Ser. B: Chem., 2007,50(3):308-317

    11. [11]

      [11] Xu J, Zheng S T, Yang G Y. Sci. China Chem., 2011,54(9): 1407-1417

    12. [12]

      [12] Pasatoiu T D, Sutter J P, Madalan A M, et al. Inorg. Chem., 2011,50(13):5890-5898

    13. [13]

      [13] Jana A, Majumder S, Carrella L, et al. Inorg. Chem., 2010, 49(19):9012-9025

    14. [14]

      [14] Zhao X, Ye X P, Chang L M, et al. Inorg. Chem. Commun., 2012,16:95-99

    15. [15]

      [15] ZHANG Xu-Hong(张旭红), WANG Shu-Ping(王淑萍). Progress in Chemistry(Huaxue Jinzhan), 2010,22(9):1709-1719

    16. [16]

      [16] Haddad S F, Raymond K N. Inorg. Chim. Acta, 1986,122: 111-118

    17. [17]

      [17] Sheriff T S, Carr P, Piggott B. Inorg. Chim. Acta, 2003,348: 115-122

    18. [18]

      [18] Côté A P, Shimizu G K H. Chem. Commun., 2001:251-252

    19. [19]

      [19] Sun H Y, Huang C H, Xu G X. Polyhedron, 1995,14(7):947-951

    20. [20]

      [20] XIE Qing-Fan(解庆范), CHEN Yan-Min(陈延民), HUANG Miao-Ling(黄妙龄). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26:263-268

    21. [21]

      [21] Sheldrick G M. SHELXTL, Program for X-ray Crystal Structure Solution and Refinement, University of Gottingen, Germany, 1997.

    22. [22]

      [22] Liu J F, Liu J L, Zhao G L. Acta Cryst. Sect. E, 2009,65: m1385-m1386

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