Citation: WEI Zan-Bin, XIE Qing-Fan, CHEN Yan-Min. Synthesis, Crystal Structure and Thermal Stability of Complex Na₃[Na₅(dhns)₂]·(phen)₄·2H₂O with Bihydroxynaphthalenedisulfonate[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1414-1418. doi: 10.3969/j.issn.1001-4861.2013.00.212 shu

Synthesis, Crystal Structure and Thermal Stability of Complex Na₃[Na₅(dhns)₂]·(phen)₄·2H₂O with Bihydroxynaphthalenedisulfonate

1.
1 College of Chemistry & Chemical Engineering, Xiamen University, Xiamen, Fujian 361005, China;

Received Date: 9 September 2012
Available Online: 3 February 2013
Fund Project: 福建省教育厅科技基金(No.JA08212) (No.JA08212)福建省科技厅科技项目(No.2008F5053)资助项目。 (No.2008F5053)

A new complex, Na₃[Na₅(dhns)₂]·(phen)₄·2H₂O, was obtained from the self-assembly of disodium 2,7-dihydroxy-naphthalene-3,6-disulfonate (Na₂H₂dhns) and 1,10-phenanthroline (Phen) in a water-ethanol solution. The compound was characterized by elemental analysis, IR, TGA, and X-ray diffraction single crystal structure analyses. The compound crystallizes in the orthorhombic system, space group Pna2₁, a=2.829 85(12) nm, b=1.038 99(14) nm, c=2.259 23(13) nm, V=6.642 6(10) nm³, Z=4, D_c=1.573 g·cm^-3, R₁=0.050 6, wR₂=0.124 0, S=1.05. CCDC: 881794.
- supramolecule;crystal strucrure;self-assembly;naphthalenedisulfonic acid
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沈阳化工大学材料科学与工程学院沈阳 110142

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Synthesis, Crystal Structure and Thermal Stability of Complex Na₃[Na₅(dhns)₂]·(phen)₄·2H₂O with Bihydroxynaphthalenedisulfonate