Citation: LIU Chun-Bo, ZHAO Han, WANG Shan-Shan, ZHA Xiao-Lin, LI Xiu-Ying, CHE Guang-Bo. Syntheses and Crystal Structures of Co(Ⅱ) and Mn(Ⅱ) Complexes with 2,4’-Biphenyldicarboxylic Acid and Imidazo[4,5-f][1,10]phenanthroline Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1533-1538. doi: 10.3969/j.issn.1001-4861.2013.00.207 shu

Syntheses and Crystal Structures of Co(Ⅱ) and Mn(Ⅱ) Complexes with 2,4’-Biphenyldicarboxylic Acid and Imidazo[4,5-f][1,10]phenanthroline Ligands

1.
1 College of Environmental Science and Engineering, Jilin Normal University, Siping, Jilin 136000, China;

Received Date: 26 June 2012
Available Online: 2 February 2013
Fund Project: 国家自然科学基金(No.60978059) (No.60978059)教育部新世纪优秀人才(No.NCET-10-0176)资助项目。 (No.NCET-10-0176)

Two complexes constructed with 2,4'-biphenyldicarboxylic acid (2,4'-H₂bpdc), 1,10-phenanthroline derivative ligands and metallic salts, namely, {[Co(2,4'-bpdc)(L)(H₂O)]·H₂O}_n (1), [Mn(2,4'-bpdc)(L)(H₂O)]_n (2) (L=imidazo[4,5-f][1,10]phenanthroline) were synthesized under hydrothermal reaction. The complexes are characterized by elemental analysis, single crystal X-ray diffraction and thermogravimetric analysis. Complex 1 has a 1D chain structure. Complex 2 forms a one-dimensional double-chain structure. They both further linked into a three-dimensional net structure via the intermolecular hydrogen bonds and aromatic π-π interactions. CCDC: 934719, 1; 934720,2.
- cobalt(Ⅱ) complex;manganese(Ⅱ) complex;2,4’-biphenyldicarboxylic acid;imidazo[4,5-f][1,10]phenanthroline;crystal structure
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沈阳化工大学材料科学与工程学院沈阳 110142