Citation: ZHANG Fu-Xing, WANG Jian-Qiu, KUANG Dai-Zhi, FENG Yong-Lan, CHEN Zhi-Ming, XU Zhi-Feng, YU Jiang-Xi. Synthesis, Crystal Structure and Photoluminescence Properties of Dibenzyl Tin Complex with Salicylidene-2-aminophenol[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1442-1446. doi: 10.3969/j.issn.1001-4861.2013.00.206 shu

Synthesis, Crystal Structure and Photoluminescence Properties of Dibenzyl Tin Complex with Salicylidene-2-aminophenol

1.
Department of Chemistry and Material Science, Hengyang Normal University; Key Laboratory of Functional Organometallic Materials of Hengyang Normal University, College of Hunan Province; Hengyang, Hunan 421008, China

Received Date: 24 August 2012
Available Online: 3 February 2013
Fund Project: 湖南省高校创新平台开放基金项目(No.12K124) (No.12K124)湖南省自然科学基金项目(No.11JJ3021) (No.11JJ3021)湖南省重点学科基金和湖南省高校重点实验室开放基金(No.11K01)资助项目。 (No.11K01)

Dibenzyl tin complex with salicylidene-2-aminophenol was synthesised by the reaction of dibenzyl tin dichloride with salicylidene-2-aminophenol Schiff Bases. The crystal structures have been determined by X-ray diffraction. It belongs to monoclinic system, space group P2₁/n with a=1.110 03(3) nm, b=1.719 87(5) nm, c=1.176 09(3) nm, β=100.564 0(10)°, V=2.207 23(10) nm³, Z=4, D_c=1.541 g·cm^-3, μ(Mo Kα)=11.81 cm^-1,F(000)= 1 023, R₁=0.026 8, wR₂=0.061 9. The tin atom is rendered five-coordination in a distorted tigonal bipyram idal-structure. The study on the title complex has been performed with quantum chemistry calculation. The stabilities, the orbital energies and composition characteristics of some frontier molecular orbitals of the complex have been investigated. The photoluminescent property of complexes was investigated. CCDC: 934721.
- organotin;crystal structure;quantum chemistry;fluorescence properties
1. [1]
  [1] Chandrasekhar V, Thirumoorthi R, Metre R K, et al. J. Organomet. Chem., 2011,696:600-606
2. [2]
  [2] Effendy, Marchetti F, Marinelli A, et al. J. Inorg. Chem. Acta, 2011,366,388-393
3. [3]
  [3] Hanif M, Hussain M, Ali S, et al. Polyhedron, 2010,29,613-619
4. [4]
  [4] ZHANG Xiao-Yan(张晓燕), YANG Guang(杨光), ZHANG Jun(张俊), et al. Chem. J. Chinsese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2010,31(6):1162-1166
5. [5]
  [5] Siddiqi Z A, Shahid M, Kumar S, et al. J. Organomet. Chem., 2009,694:3768-3774
6. [6]
  [6] Ruan B F, Tian Y U, Zhou H P, et al. Inorg. Chim. Acta, 2011,365:302-308
7. [7]
  [7] YIN Han-Dong(尹汉东), WANG Chuan-Hua(王传华), WANG Yong (王勇), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2002,18(2):201-204
8. [8]
  [8] YAN Wen-Hua(闫文华), KANG Wan-Li(康万利), LI Jin-Huan(李金环). Chinese J. Appl. Chem.(Yingyong Huaxue), 2007,24(6):660-664
9. [9]
  [9] Shujha S, Shah A, Rehman Z U, et al. Eur. J. Med. Chem., 2010,45:2902-2911
10. [10]
  [10] ZHANG Fu-Xing(张复兴), KUANG Dai-Zhi(邝代治), WANG Jian-Qiu(王剑秋), et al. Chinese J. Org. Chem.(Youji Huaxue), 2008,28(8):1457-1461
11. [11]
  [11] Hodnett M E, Mooney P D. J. Med. Chem., 1970,13(4):786
12. [12]
  [12] Hodnett M E, Dunn W J. J. Med. Chem., 1972,15(2):339
13. [13]
  [13] LI Zhong-Fang(李忠芳), WANG Su-Wenb(王素文), WANG Jieb(王捷), et al. Chinese J. Struct. Chem.(Jiegou Huaxue), 2003,22(6):750-754
14. [14]
  [14] LIU Hong-Wen(刘宏文), LU Wen-Guan(卢文贯), TAO Jia-Xun(陶家洵), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2003,19(12):1351-1355
15. [15]
  [15] LIU Bao-Dian(刘宝殿), XU Yong-Xiang(徐永祥), BAO Ming (包明), et al. Chem. J. Chinsese Universities(Gaodeng Xuexiao Huaxue Xuebao), 1994,15(9):1322-1326
16. [16]
  [16] LI Wu-Ju(李五聚), SHI Zan(史攒), LI Shi-Yin(李时银), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2000, 16(3):510-514
1. [1]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
2. [2]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
3. [3]
  Zhaoyang WANG , Chun YANG , Yaoyao Song , Na HAN , Xiaomeng LIU , Qinglun WANG . Lanthanide(Ⅲ) complexes derived from 4′-(2-pyridyl)-2, 2′∶6′, 2″-terpyridine: Crystal structures, fluorescent and magnetic properties. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1442-1451. doi: 10.11862/CJIC.20240114
4. [4]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
5. [5]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Jia Zhou . Constructing Potential Energy Surface of Water Molecule by Quantum Chemistry and Machine Learning: Introduction to a Comprehensive Computational Chemistry Experiment. University Chemistry, 2024, 39(3): 351-358. doi: 10.3866/PKU.DXHX202309060
8. [8]
  Dongju Zhang , Rongxiu Zhu . Construction of Ideological and Political Education in Quantum Chemistry Course: Several Teaching Cases to Reveal the Universal Connection of Things. University Chemistry, 2024, 39(7): 272-277. doi: 10.3866/PKU.DXHX202311032
9. [9]
  Guoxian Zhu , Jing Chen , Rongkai Pan . Enhancing the Teaching Quality of Atomic Structure: Insights and Strategies. University Chemistry, 2024, 39(3): 376-383. doi: 10.3866/PKU.DXHX202305027
10. [10]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
11. [11]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
12. [12]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
13. [13]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
14. [14]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
15. [15]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
16. [16]
  Yongzhi LI , Han ZHANG , Gangding WANG , Yanwei SUI , Lei HOU , Yaoyu WANG . A two-dimensional metal-organic framework for the determination of nitrofurantoin and nitrofurazone in aqueous solution. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 245-253. doi: 10.11862/CJIC.20240307
17. [17]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
18. [18]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
19. [19]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
20. [20]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(463)
HTML views(58)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142