Citation: QU Ling-Zhi, CHENG Zhi-Qiang, DENG Da-Wei, CAO Jie, JIN Jing, GU Yue-Qing. Oil-Soluble CuInS₂/ZnS Quantum Dots and Water Transfer Using Temperature-Sensitive Poly(N-isopropylacrylamide-co-Acrylamide-co-Octadecyl acrylate) Micelle[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1361-1368. doi: 10.3969/j.issn.1001-4861.2013.00.204 shu

Oil-Soluble CuInS₂/ZnS Quantum Dots and Water Transfer Using Temperature-Sensitive Poly(N-isopropylacrylamide-co-Acrylamide-co-Octadecyl acrylate) Micelle

1.
1 School of Life Science and Technology, China Pharmaceutical University, Nanjing 210009, China;

Received Date: 6 November 2012
Available Online: 21 March 2013
Fund Project: 国家自然科学基金(No.30800257 and No.81071194) (No.30800257 and No.81071194)江苏省自然科学基金(No.BK2011634) (No.BK2011634)中央高校基本科研业务费专项资金(No.JKP2011017) (No.JKP2011017)教育部新世纪优秀人才支持计划(No.NCET-12-0974)资助项目。 (No.NCET-12-0974)

High-quality oil-soluble CuInS₂/ZnS core/shell quantum dots (QDs) have been synthesized successfully using a non-hot-injection method. The as-prepared QDs exhibits tunable photoluminescence (PL) emission (PL peak, 550~800 nm) with a maximum PL quantum yield (QY) up to 80%. Furthermore, in this study, we explored further the water transfer of oil-soluble CuInS₂/ZnS QDs by using temperature-sensitive poly(N-isopropylacryla-mide-co-Acrylamide-co-Octadecylacrylate) (P(NIPA-co-AAm-co-ODA)) micelle. The QDs-loaded micelle not only shows favorable PL properties, but also maintains the initial sensitive thermal responsibility. These results confirm the promising potential of cadmium-free CuInS₂/ZnS QDs as a fluorescent probe for the biological imaging of micelle.
- CuInS₂/ZnS core/shell QDs;micelle;water transfer
1. [1]
  [1] Lewinski N, Colvin V, Drezek R. Small, 2008,4(1):26-49
2. [2]
  [2] Deng D W, Xia J F, Gu Y Q, et al. J. Colloid Interface Sci., 2012,367:234-240
3. [3]
  [3] CHENG Fang(程芳), LIU Zheng(刘贞), HU Yu-Zhu(胡育筑), et al. Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2012,33(3):475-480
4. [4]
  [4] CAO Mei-Rong(曹美荣), HOU Jie(侯洁), ZHANG Qi(张奇), et al. Chem. J. Chinese Universities(Gaodeng Xuexiao Huaxue Xuebao), 2012,33(3):437-441
5. [5]
  [5] WU Jie(吴杰), CHI Yan-Hua(迟燕华), ZHUANG Jia(庄稼). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(7): 1199-1206
6. [6]
  [6] Xie R G, Rutherford M, Peng X G. J. Am. Chem. Soc., 2009, 131:5691-5697
7. [7]
  [7] Alle P M, Liu W, Bawendi M G, et al. J. Am. Chem. Soc., 2010,132:470-471
8. [8]
  [8] Park J, Dvoracek C, Lee K H, et al. Small, 2011,7(22):3148-3152
9. [9]
  [9] Deng D W, Chen Y Q, Gu Y Q, et al. Chem. Mater., 2012, 24:3029-3037
10. [10]
  [10] Zhang J, Xie R G, Yang W S, et al. Chem. Mater., 2011,23: 3357-3361
11. [11]
  [11] Li L, Daou T J, Reiss P, et al. Chem. Mater., 2009,21:2422-2429
12. [12]
  [12] Pons T, Pic E,Cassette E, et al. ACS Nano, 2010,4(5):2531-2538
13. [13]
  [13] Zhang W J, Zhong X H. Inorg. Chem., 2011,50:4065-4072
14. [14]
  [14] Xue B, Deng D W, Gu Y Q, et al. Dalton Trans., 2012,41: 4935-4947
15. [15]
  [15] Cao J, Deng D W, Gu Y Q, et al. J. Biomed. Mater. Res. Part A, 2012:958-968
16. [16]
  [16] Kakizawa Y, Kataoka K. Adv. Drug Deliv. Rev., 2002,54(2): 203-222
17. [17]
  [17] Torchilin V P. J. Control Release, 2001,73(2-3):137-172
18. [18]
  [18] Nishiyama N, Kataoka K. Pharmacol. Ther., 2006,3(112): 630-648
19. [19]
  [19] Cheng C, Wei H, Shi B X, et al. Biomaterials, 2008,4(29): 497-505
20. [20]
  [20] Neradovic D, Van Nostrum C F, Hennink W E. Macromole-cules, 2001,22(34):7589-7591
21. [21]
  [21] Wei H, Cheng S, Zhang X, et al. Prog. Polym. Sci., 2009,34 (9):893-910
22. [22]
  [22] DENG Da-Wei(邓大伟), YU Jun-Sheng(于俊生). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2008,24(5):701-707
23. [23]
  [23] QI Cui-Cha(齐翠茶), HE Zi-Jian(何子剑), XIE Hai-Yan(谢海燕). Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2010,26(6):951-956
24. [24]
  [24] Stuart M A C, Huck W T S, Genzer J, et al. Nature Mater., 2010,9:101-113
25. [25]
  [25] Liu X M, Wang L S, He C B, et al. Biomaterials, 2004,25 (25):5659-5666
1. [1]
  Endong YANG , Haoze TIAN , Ke ZHANG , Yongbing LOU . Efficient oxygen evolution reaction of CuCo₂O₄/NiFe-layered bimetallic hydroxide core-shell nanoflower sphere arrays. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 930-940. doi: 10.11862/CJIC.20230369
2. [2]
  Fan Wu , Wenchang Tian , Jin Liu , Qiuting Zhang , YanHui Zhong , Zian Lin . Core-Shell Structured Covalent Organic Framework-Coated Silica Microspheres as Mixed-Mode Stationary Phase for High Performance Liquid Chromatography. University Chemistry, 2024, 39(11): 319-326. doi: 10.12461/PKU.DXHX202403031
3. [3]
  Miaomiao He , Zhiqing Ge , Qiang Zhou , Jiaqing He , Hong Gong , Lingling Li , Pingping Zhu , Wei Shao . Exploring the Fascinating Realm of Quantum Dots. University Chemistry, 2024, 39(6): 231-237. doi: 10.3866/PKU.DXHX202310040
4. [4]
  Zunxiang Zeng , Yuling Hu , Yufei Hu , Hua Xiao . Analysis of Plant Essential Oils by Supercritical CO₂Extraction with Gas Chromatography-Mass Spectrometry: An Instrumental Analysis Comprehensive Experiment Teaching Reform. University Chemistry, 2024, 39(3): 274-282. doi: 10.3866/PKU.DXHX202309069
5. [5]
  Yuena Yang , Xufang Hu , Yushan Liu , Yaya Kuang , Jian Ling , Qiue Cao , Chuanhua Zhou . The Realm of Smart Hydrogels. University Chemistry, 2024, 39(5): 172-183. doi: 10.3866/PKU.DXHX202310125
6. [6]
  Siming Bian , Sijie Luo , Junjie Ou . Application of van Deemter Equation in Instrumental Analysis Teaching: A New Type of Core-Shell Stationary Phase. University Chemistry, 2025, 40(3): 381-386. doi: 10.12461/PKU.DXHX202406087
7. [7]
  Chuanming GUO , Kaiyang ZHANG , Yun WU , Rui YAO , Qiang ZHAO , Jinping LI , Guang LIU . Performance of MnO₂-0.39IrO_x composite oxides for water oxidation reaction in acidic media. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1135-1142. doi: 10.11862/CJIC.20230459
8. [8]
  Gaoyan Chen , Chaoyue Wang , Juanjuan Gao , Junke Wang , Yingxiao Zong , Kin Shing Chan . Heart to Heart: Exploring Cardiac CT. University Chemistry, 2024, 39(9): 146-150. doi: 10.12461/PKU.DXHX202402011
9. [9]
  Yi Yang , Xin Zhou , Miaoli Gu , Bei Cheng , Zhen Wu , Jianjun Zhang . S型ZnO/CdIn₂S₄光催化剂制备H₂O₂偶联苄胺氧化的超快电子转移飞秒吸收光谱研究. Acta Physico-Chimica Sinica, 2025, 41(6): 100064-. doi: 10.1016/j.actphy.2025.100064
10. [10]
  You Wu , Chang Cheng , Kezhen Qi , Bei Cheng , Jianjun Zhang , Jiaguo Yu , Liuyang Zhang . ZnO/D-A共轭聚合物S型异质结高效光催化产H₂O₂及其电荷转移动力学研究. Acta Physico-Chimica Sinica, 2024, 40(11): 2406027-. doi: 10.3866/PKU.WHXB202406027
11. [11]
  Peng Li , Yuanying Cui , Zhongliao Wang , Graham Dawson , Chunfeng Shao , Kai Dai . CeO₂/Bi₁₉Br₃S₂₇ S型异质结的高效界面电荷转移用于增强光催化CO₂还原. Acta Physico-Chimica Sinica, 2025, 41(6): 100065-. doi: 10.1016/j.actphy.2025.100065
12. [12]
  Kun Rong , Cuilian Wen , Jiansen Wen , Xiong Li , Qiugang Liao , Siqing Yan , Chao Xu , Xiaoliang Zhang , Baisheng Sa , Zhimei Sun . 层状MoS₂/Ti₃C₂T_x异质结光热转换材料用于太阳能驱动水蒸发. Acta Physico-Chimica Sinica, 2025, 41(6): 100053-. doi: 10.1016/j.actphy.2025.100053
13. [13]
  Jianjun Liu , Xue Yang , Chi Zhang , Xueyu Zhao , Zhiwei Zhang , Yongmei Chen , Qinghong Xu , Shao Jin . Preparation and Fluorescence Characterization of CdTe Semiconductor Quantum Dots. University Chemistry, 2024, 39(7): 307-315. doi: 10.3866/PKU.DXHX202311031
14. [14]
  Yu SU , Xinlian FAN , Yao YIN , Lin WANG . From synthesis to application: Development and prospects of InP quantum dots. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2105-2123. doi: 10.11862/CJIC.20240126
15. [15]
  Xiaowu Zhang , Pai Liu , Qishen Huang , Shufeng Pang , Zhiming Gao , Yunhong Zhang . Acid-Base Dissociation Equilibrium in Multiphase System: Effect of Gas. University Chemistry, 2024, 39(4): 387-394. doi: 10.3866/PKU.DXHX202310021
16. [16]
  Zeyu XU , Anlei DANG , Bihua DENG , Xiaoxin ZUO , Yu LU , Ping YANG , Wenzhu YIN . Evaluation of the efficacy of graphene oxide quantum dots as an ovalbumin delivery platform and adjuvant for immune enhancement. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1065-1078. doi: 10.11862/CJIC.20240099
17. [17]
  Li'na ZHONG , Jingling CHEN , Qinghua ZHAO . Synthesis of multi-responsive carbon quantum dots from green carbon sources for detection of iron ions and L-ascorbic acid. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 709-718. doi: 10.11862/CJIC.20240280
18. [18]
  Yanhui Zhong , Ran Wang , Zian Lin . Analysis of Halogenated Quinone Compounds in Environmental Water by Dispersive Solid-Phase Extraction with Liquid Chromatography-Triple Quadrupole Mass Spectrometry. University Chemistry, 2024, 39(11): 296-303. doi: 10.12461/PKU.DXHX202402017
19. [19]
  Jiao CHEN , Yi LI , Yi XIE , Dandan DIAO , Qiang XIAO . Vapor-phase transport of MFI nanosheets for the fabrication of ultrathin b-axis oriented zeolite membranes. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 507-514. doi: 10.11862/CJIC.20230403
20. [20]
  Zhiwen HU , Weixia DONG , Qifu BAO , Ping LI . Low-temperature synthesis of tetragonal BaTiO₃ for piezocatalysis. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 857-866. doi: 10.11862/CJIC.20230462

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(466)
HTML views(41)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Oil-Soluble CuInS2/ZnS Quantum Dots and Water Transfer Using Temperature-Sensitive Poly(N-isopropylacrylamide-co-Acrylamide-co-Octadecyl acrylate) Micelle

Metrics

通讯作者: 陈斌, bchen63@163.com

Oil-Soluble CuInS₂/ZnS Quantum Dots and Water Transfer Using Temperature-Sensitive Poly(N-isopropylacrylamide-co-Acrylamide-co-Octadecyl acrylate) Micelle