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Citation: YANG Hao, CHEN Jian-Guo, FENG Yu-Quan, BAO Xiao-Yu, SUN Ru-Zhong. Synthesis, Crystal Structure and Properties of 1D Ribbon-Like Complex [Co(DMPhTPY)V2O6]n with Substituted Terpyridine and Polyoxovanadate Ligand[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1454-1458. doi: 10.3969/j.issn.1001-4861.2013.00.203 shu

Synthesis, Crystal Structure and Properties of 1D Ribbon-Like Complex [Co(DMPhTPY)V2O6]n with Substituted Terpyridine and Polyoxovanadate Ligand

  • 1.

    College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, Henan 473061, China

  • Received Date: 13 November 2012
    Available Online: 16 February 2013

    Fund Project: 河南省科技厅自然科学基金(No.112300410189)资助项目。 (No.112300410189)

  • A 1D ribbon-like structure coordination polymer of [Co(DMPhTPY)V2O6]n (DMPhTPY=6,6"-dimethyl-4'-phenyl-2,2':6',2"-terpyridine)was synthesized under the hydrothermal condition. The structure was characterized by elemental analysis, IR and X-ray single crystal diffraction. The crystal structure of the complex belongs to triclinic system, space group P1. Thermal stability, photoluminescence property and magnetic susceptibility of the complex have been investigated. The results show that the title complex has high thermal stability and antiferromagnetic exchange interaction between the Co(Ⅱ) ions. CCDC: 880007.
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