Citation: TAI Xi-Shi, ZHAO Wen-Hua, LI Fa-Hui. Synthesis, Structural Characterization and Antitumor Activity of a Ca(Ⅱ)-Schiff Base Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1328-1332. doi: 10.3969/j.issn.1001-4861.2013.00.202 shu

Synthesis, Structural Characterization and Antitumor Activity of a Ca(Ⅱ)-Schiff Base Complex

1.
1. College of Chemistry and Chemical Engineering, Weifang University, Weifang, Shandong 261061, China;

Received Date: 17 June 2012
Available Online: 1 February 2013
Fund Project: 山东省优秀中青年科学家奖励基金(No.2010BSA07004) (No.2010BSA07004)

A 3D network Ca(Ⅱ) complex has been synthesized in CH₃CH₂OH solvent, and characterized by elemental analysis, IR spectra, molar conductivity, thermal analysis and X-ray crystal structure determination. The results of crystal structure show that that each Ca(Ⅱ) ion is coordinated with six oxygen atoms from Schiff base ligands (Schiff base derived from 2-carboxybenzaldehyde and diethylenetriamine), forming a distorted octahedral coordination geometry. The compound formed 3D network structure through hydrogen bonds and π-π interaction of benzene rings. The antitumor activity of the Ca(Ⅱ) complex also was investigated. CCDC: 709605.
- 2-carboxybenzaldehyde-diethylenetriamine;Ca(Ⅱ) complex;synthesis;structure characterization;antitumor activity
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沈阳化工大学材料科学与工程学院沈阳 110142