Citation: MA Xiao-Li, SUN Shuai, YANG Ying. Synthesis, Crystal Structure and Properties of Silicon(Ⅳ) Complexes with N-aryl Substituted α-Diimine Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1295-1301. doi: 10.3969/j.issn.1001-4861.2013.00.199 shu

Synthesis, Crystal Structure and Properties of Silicon(Ⅳ) Complexes with N-aryl Substituted α-Diimine Ligands

1.
1. School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China;

Received Date: 31 August 2012
Available Online: 2 February 2013
Fund Project: 国家自然科学基金(No.21001016, 20902112)资助项目。 (No.21001016, 20902112)

Two silicon(Ⅳ) compounds with α-diimine ligands, L(SiMe₃)₂(2) (L=[(2, 6-ⁱPr₂C₆H₃)NC(Me)]₂), L'(SiMe₃)₂ (4) (L'=[(2, 6-ⁱPr₂C₆H₃)NCH]₂) were synthesized by the reaction of corresponding sodium salts or lithium salts with chloro(trimethyl)silane. The crystal of compound 2 belongs to the monoclinic system, space group P2₁/n with a=0.958 5(3) nm, b=1.811 8(5) nm, c=0.982 4(3) nm, β=102.173(3), V=1.667 7(8) nm³, Z=2. The crystal of compound 4 belongs to the triclinic system, space group P1 with a=0.883 7(2) nm, b=0.967 5(2) nm, c=1.142 9(4) nm, β=88.94(2), V=0.835 8(4) nm³, Z=1. A zig-zag arrangement of the atoms N(1), C(13), C(13ⁱ), and N(1ⁱ) is the core of both of the two molecular structures. Both of the two complexes were characterized by single crystal X-ray structural analysis, ¹H NMR, elemental analysis, and FTIR spectra, analyzed by UV-Vis spectrum and fluorescent spectra properties. The compounds exhibit strong fluorescence under ultraviolet light. CCDC: 896958, 2; 896957, 4.
- α-diimine;crystal structure;silicon(Ⅳ) complex;photoluminescence
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沈阳化工大学材料科学与工程学院沈阳 110142