Citation: WANG Li-Zhen, ZHANG Wen-Jing, LIU Yu-Jun, GU Shu-Hua, SUN Xin-Ke. Influence of NaBF₄ on the Graphite Anode for Li-Ion Battery[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(7): 1407-1413. doi: 10.3969/j.issn.1001-4861.2013.00.196 shu

Influence of NaBF₄ on the Graphite Anode for Li-Ion Battery

1.
1 Zhengzhou University of Light Industry, Zhengzhou 450001, China;

Received Date: 28 December 2012
Available Online: 11 February 2013

The influence of NaBF₄ on graphite anode for Li-ion battery was studied by adding it into the process of slurry preparation with the methods of galvanostatic charge-discharge, CV, EIS, SEM and EDS. The results showed that: when the amount of NaBF₄ was 2%, not only the reversible capacity at the initial cycle was improved, but also the efficiency. The performances of self-discharge and the cycle stability were all both improved. And its self-discharge rate calculated by capacity was 0.87%·d^-1, reduced15% than it without NaBF₄. The results of CV, EDS and SEM tests both suggested that, NaBF₄ involved in the process of SEI formation, changing its components and morphology.
- Li-ion battery;graphite anode;SEI film;self-discharge;cycle stability
1. [1]
  [1] Besenhar J O, Winter M, Yang J. J. Power Sources, 1995,54: 228-231
2. [2]
  [2] Fukuta K, Kikuya K, Isono K, et al. J. Power Sources, 1997, 69:165-169
3. [3]
  [3] Sumiya K, Suzuki J, Takasu R, et al. J. Electroanal. Chem., 1999,462:150-153
4. [4]
  [4] Abe T, Fukuda H, Iriyama Y, et al. J. Electrochem. Soc., 2004,151:1120-1124
5. [5]
  [5] Kaplan B, Groult H, Barhoun A, et al. J. Electrochem. Soc. 2002,149(5):D72-D78
6. [6]
  [6] Itagaki M, Yotsuda S, Kobari N, et al. Electrochim Acta, 2006,51:1629-1635
7. [7]
  [7] Zhang S S, Xu K, Jow T R. J. Power Sources, 2005,143:197-202
8. [8]
  [8] Abe K, Yoshitake H, Kitakura T, et al. Electrochim Acta, 2004,49:4613-4622
9. [9]
  [9] Inaba M, Kawatate Y, Funabiki A, et al. Electrochim Acta, 1999,45:99-105
10. [10]
  [10] WU Shan(武山), ZHUANG Quan-Chao(庄全超). Battery Bimonthly(Dianchi), 2005,35(3):242-243
11. [11]
  [11] Ratnakumar B V, Smart M C, Surampudi S. J Power Sources, 2001,97-98:137-139
12. [12]
  [12] Aurbach D, Ein-Eli Y, Markovsky B, et al. J. Electrochem. Soc, 1995,142:2882-2890
13. [13]
  [13] Besenhard J O, Wagner M W, Winter M, et al. J. Power Sources, 1993,44(1/2/3):413-420
14. [14]
  [14] Aubarch D, Ein-Eli Y, Chusid O. J. Electrochem. Soc., 1994, 141:603-611
15. [15]
  [15] Ein-Eli Y, Thomas S R, Koch V R, et al. J. Electrochem. Soc., 1997,144:1159-1165
16. [16]
  [16] Komaba S, Itabashi T, Kaplan B, et al. Electrochem. Commun., 2003,5:962-966
17. [17]
  [17] ZHENG Hong-He(郑洪河), ZHANG Li-Na(张丽娜). Chin. J. Power Source (Dianyuan Jishu), 2011,35(1):36-38
18. [18]
  [18] ZHENG Hong-He(郑洪河). Electrolytes for Lithium Ion Batteries. Beijing: Chemical Industry Press, 2006:73
19. [19]
  [19] ZHUANG Quan-Chao(庄全超), XU Shou-Dong(徐守东), QIU Xiang-Yun(邱祥云), et al. Prog. Chem.(Huaxue Jinzhan), 2010,22(6):1044-1057
20. [20]
  [20] LÜ Dong-Sheng(吕东生), LI Wei-Shan(李伟善), LIU Xu (刘煦), et al. Battery Bimonthly (Dianchi), 2003,33(5): 326-327
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沈阳化工大学材料科学与工程学院沈阳 110142

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通讯作者: 陈斌, bchen63@163.com

Influence of NaBF₄ on the Graphite Anode for Li-Ion Battery