Citation: XUE Meng-Wei, LIU Guang-Xiang, WANG Xiao-Feng. Synthesis, Crystal Structure and Magnetic Properties of a Manganese(Ⅱ) Coordination Polymer Based on 2,2'-Disulfanediyldibenzoic Acid and 2,3,5,6-Tetrafluoro-1,4-bis(imidazol-1-yl-methyl) benzene)[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1277-1282. doi: 10.3969/j.issn.1001-4861.2013.00.184 shu

Synthesis, Crystal Structure and Magnetic Properties of a Manganese(Ⅱ) Coordination Polymer Based on 2,2'-Disulfanediyldibenzoic Acid and 2,3,5,6-Tetrafluoro-1,4-bis(imidazol-1-yl-methyl) benzene)

1.
School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University, Nanjing 211171, China

Received Date: 22 May 2012
Available Online: 31 January 2013
Fund Project: 国家自然科学基金(No. 21271106)资助项目。 (No. 21271106)

A new two-dimensional coordination polymer of [Mn(DSBA)(FBIX)_0.5]_n (1) (H₂DSBA=2,2'-disulfanediyl-dibenzoic acid and FBIX=2,3,5,6-tetrafluoro-1,4-bis(imidazol-1-yl-methyl) benzene) has been prepared and chara-cterized by elemental analysis, IR spectroscopy, TGA and single-crystal X-ray diffraction. The crystal is of monoclinic, space group P2₁/c with a=1.050 41(12) nm, b=1.160 23(13) nm, c=1.940 36(18) nm, β=116.647(3)°, V=2.113 6(4) nm³, D_c=1.617 g·cm^-3, Z=4, F(000)=1 040, Goof=1.052, R₁=0.057 9, wR₂=0.097 0. Complex 1 shows a two-dimensional layer structure based on paddle-wheel building units. Magnetic-property studies show that antiferromagnetic exchange interactions propagate among the Mn(Ⅱ) ions. CCDC: 834854.
- manganese(Ⅱ) complex;hydrothermal synthesis;crystal structure;magnetism
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沈阳化工大学材料科学与工程学院沈阳 110142