Citation: LV Xu-Yan, LIU Jian-Feng, LIU Yan, GAO Ling-Ling, XIAO Li-Qun, HU Tuo-Ping. Syntheses and Crystal Structures of Zn(Ⅱ) and Cd(Ⅱ) Complexes Based on 2,3,5,6-Tetrabromoterephthalic Acid and 1,3-Bis(4-pyridyl)propane[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 1096-1102. doi: 10.3969/j.issn.1001-4861.2013.00.175 shu

Syntheses and Crystal Structures of Zn(Ⅱ) and Cd(Ⅱ) Complexes Based on 2,3,5,6-Tetrabromoterephthalic Acid and 1,3-Bis(4-pyridyl)propane

1.
Department of Chemistry, College of Science, North University of China, Taiyuan 030051, China

Corresponding author: HU Tuo-Ping,
Received Date: 26 July 2012
Available Online: 23 January 2013
Fund Project: 国家国际科技合作(No.2011DFA51980) (No.2011DFA51980)省自然科学基金(No.2011081022)资助项目。 (No.2011081022)

The complexes of [Zn(TBTA)(BPP)]_n (1) and [Cd(TBTA)(BPP)₂(H₂O)₂]_n (2) based on 2,3,5,6-tetrabromo-terephthalic acid (H₂TBTA) and 1,3-bis(4-pyridyl)propane (BPP) have been constructed in CH3OH/H₂O solution at room temperature. The structures and properties were characterized by the single-crystal X-ray diffraction, elemental analyses, IR spectra and thermogravimetric analyses. The results indicate the complex 1 is two dimension (2D) wave-like layer network, and the complex 2 is one dimension (1D) chain structure, and the carboxyl groups in H₂TBTA ligands coordinate with metal ions in monodentate mode, and the H-bonding interactions contribute to the stabilities of the structures of the complexes. CCDC: 854381, 1; 854380, 2.
- 2,3,5,6-tetrabromoterephthalic acid;1,3-bis(4-pyridyl)propane;Zn(Ⅱ) complex;Cd(Ⅱ) complex;H-bonding interactions
1. [1]
  [1] Surblé S, Serre C, Mellot-Draznieks C, et al. Chem. Commun., 2006,6:284-286
2. [2]
  [2] Yaghi O M, O'Keeffe M, Ockwig N W, et al. Nature, 2003, 423(6941):705-714
3. [3]
  [3] Huang Y G, Wu B L, Yuan D Q, et al. Inorg. Chem., 2007, 46(4):1171-1176
4. [4]
  [4] Wu C D, Hu A, Zhang L, et al. J. Am. Chem. Soc., 2005, 127(25):8940-8941
5. [5]
  [5] Gao X M, Li D S, Wang J J, et al. Cryst. Eng. Commun., 2008,10:479-482
6. [6]
  [6] Zhang J P, Chen X M. J. Am. Chem. Soc., 2008,130:6010- 6017
7. [7]
  [7] Kahn O. Acc. Chem. Res., 2000,33(10):647-657
8. [8]
  [8] Kesanli B, Lin W. Coord. Chem. Rev., 2003,246:305-326
9. [9]
  [9] Kitagawa S, Kitaura R, Noro S. Angew. Chem. Int. Ed., 2004,43(18):2334-2375
10. [10]
  [10] Le Bozec H, Le Bouder T, Maury O, et al. J. Opt. A. P : Pure Appl. Opt., 2002,4:S189-S196
11. [11]
  [11] Maury O, Le Bozec H. Acc. Chem. Res., 2005,38(9):691- 704
12. [12]
  [12] Evans O R, W Lin. Acc. Chem. Res., 2002,35(7):511-522
13. [13]
  [13] Liu Y L, Eubank J F, Cairns A J, et al. Angew. Chem. Int. Ed., 2007,46:3278-3283
14. [14]
  [14] Maspoch D, Ruiz-Molina D, Veciana J. Chem. Soc. Rev., 2007,36:770-818
15. [15]
  [15] Férey G. Chem. Soc. Rev., 2008,37(1):191-214
16. [16]
  [16] Kitagawa S, Matsuda R. Coord. Chem. Rev., 2007,251:2490 -2509
17. [17]
  [17] Hao H Q, Liu W T, Lin Z J, et al. CrystEngComm., 2009, 11:967-971
18. [18]
  [18] Ye B H, Tong M L, Chen X M. Coord. Chem. Rev., 2005, 249(5-6):545-565
19. [19]
  [19] Huang Y G, Yuan D Q, Pan L, et al. Inorg. Chem., 2007, 46:9609-9615
20. [20]
  [20] Hu S, Chen J C, Tong M L, et al. Angew. Chem. Int. Ed., 2005,44:5471-5475
21. [21]
  [21] An H Y, Wang E B, Xiao D R, et al. Angew. Chem. Int. Ed., 2006,45:904-908
22. [22]
  [22] Sun D F, Collins D J, Ke Y X, et al. Chem.-Eur. J., 2006, 12:3768-3776
23. [23]
  [23] Brammer L. Chem. Soc. Rev., 2004,33:476-489
24. [24]
  [24] Li X L, Chen K, Liu Y, et al. Angew. Chem, Int. Ed., 2007, 46(36):6820-6823
25. [25]
  [25] Du M, Li C P, Zhao X J. Cryst. Growth Des., 2006,6(1):335- 341
26. [26]
  [26] Li C P, Chen J, Du M. CrystEngComm., 2010,12:4392-4402
27. [27]
  [27] Li C P, Tian Y L, Guo Y M. Polyhedron, 2009,28:505-510
28. [28]
  [28] JIN Mei-Fang(靳梅芳), DAI Fang-Na(戴昉纳), SUN Dao- Feng(孙道峰). Chinese J. Struct. Chem.(Jiegou Huaxue), 2010,29(12):1834-1840
29. [29]
  [29] Sheldrick G M. SHELXS97, Program for the Solution of Crystal Structure, Germany: University of Gottingen, 1997.
30. [30]
  [30] Sheldrick G M. SHELXL97, Program for the Refinement of Crystal Structure, Germany: University of Gottingen, 1997.
31. [31]
  [31] Marinho M V, Yoshida M I, Guedes K J, et al. Inorg. Chem., 2004,43(4):1539-1544
32. [32]
  [32] Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 5th Ed. New York: Wiley Inters- cience, 1997.
33. [33]
  [33] Miao M M, Liao D Z, Jiang Z H, et al. Transition Met. Chem., 1997,22(1):39-41
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沈阳化工大学材料科学与工程学院沈阳 110142