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Citation: ZENG Xiao-Zhe, ZHANG Ai-Yun, LI Yan-Wei. Synthesis, Structure and Properties Study of Two Lanthanide (Ⅲ) Coordination Polymers Constructed from 2,5-Pyridinedicarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1269-1276. doi: 10.3969/j.issn.1001-4861.2013.00.173 shu

Synthesis, Structure and Properties Study of Two Lanthanide (Ⅲ) Coordination Polymers Constructed from 2,5-Pyridinedicarboxylic Acid

  • 1.

    Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, China

  • Received Date: 2 September 2012
    Available Online: 3 January 2013

    Fund Project: 河南省高等院校自然科学研究课题(2009A150011)资助项目。 (2009A150011)

  • Two new complexes, namely {[La(pydc)(OAc)(H2O)]·2H2O}n(1) and {[Tm2Cu(pydc)4(H2O)6]·2H2O}n(2) (H2pydc=2,5-pyridinedicarboxylic acid), have been synthesized and structurally characterized. Structure analyses reveal that complex 1 has intricate 3D micropore framework with 1D square channels, which is constructed by 2,5-pyridinedicarboxylate and acetate ligands. Complex 2 shows a 3D open framework in which 2,5-pydc2- dianion ligand adopts μ2-η1-η1- and μ4-bridge coordination mode. In addition, thermal stability for 1 and 2 and temperature-dependent magnetic susceptibilities for 2 have been investigated in detail. CCDC: 884201, 1;884200, 2.
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