Citation: WANG Jun-Wen, DONG Gui-Ying, ZHAO Yan-Qin, LIU Li-Wei. Synthesis, Structure and Catalytic Property of a 1D Cobalt(Ⅱ) Coordination Polymer Based on 1,4-Cyclohexanedicrboxylic Acid and Bis(benzimidazole) Ligands[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1263-1268. doi: 10.3969/j.issn.1001-4861.2013.00.170 shu

Synthesis, Structure and Catalytic Property of a 1D Cobalt(Ⅱ) Coordination Polymer Based on 1,4-Cyclohexanedicrboxylic Acid and Bis(benzimidazole) Ligands

1.
1. School of Chemical and Materials Science, Shanxi Normal University, Linfen, Shanxi 041004, China;

Received Date: 16 August 2012
Available Online: 1 February 2013
Fund Project: 山西省自然科学基金(No.2011011006-4) (No.2011011006-4)山西省教育厅基金(No.2010111)资助项目。 (No.2010111)

A Co(Ⅱ) coordination polymer has been synthesized hydrothermally, namely, {[Co(L)(chdc)]2H₂O}_n (1), (L=1,3-bis-(benzimidazole-1-yl-methylene)-benzene, H₂chdc=1,4-cyclohexanedicrboxylic acid). Structure analysis indicates that complex 1 belongs to monoclinic system, space group C2/c, a=1.450 4(1) nm, b=1.834 9(2) nm, c=2.128 7(2) nm, β=94.325(1)°, V=5.649 2(9) nm³, Z=4. Compound 1 exhibits a looped-like chain structure, then the chains are connected into 2D supramolecular structure by interchain π-π satcking interaction. Complex 1 possesses a remarkable activity for degradation of Congo red in a Fenton-like process. CCDC: 892179.
- cobalt(Ⅱ) complex;catalysis;crystal structure;Fenton-like process;synthesis
1. [1]
  [1] Li B, Zang S Q, Li H Y, et al. J. Organomet. Chem., 2012, 708-709:112-117
2. [2]
  [2] Li J R, Sculley J, Zhou H C. Chem. Rev., 2012,112:869-932
3. [3]
  [3] Song R F, Xie Y B, Li J R, et al. Dalton Tran., 2003:4742- 4748
4. [4]
  [4] Corma A, García H, Llabrés i Xamena F X. Chem. Rev., 2010,110:4606-4655
5. [5]
  [5] Leong W L, Vittal J J. Chem. Rev., 2011,111:688-764
6. [6]
  [6] O'keeffe M, Yaghi M O. Chem. Rev., 2012,112:675-702
7. [7]
  [7] Stock N, Biswas S. Chem. Rev., 2012,112:933-969
8. [8]
  [8] Zhou H C, Long J R,Yaghi O M. Chem. Rev., 2012,112:673- 674
9. [9]
  [9] Cui G H, He C H, Jiao C H, et, al. CrystEngComm, 2012, 14:4210-4216
10. [10]
  [10] ZHOU Xian-Li(周先礼), ZHANG Bing-Jun(张秉君), WANG Cui-Juan(王萃娟), et al. Chinese J. Inorg. Chem.(Wuji Huaxue Xuebao), 2012,28:1736-1742
11. [11]
  [11] Hartog R D, Harvey M R, Hummel J J A, et al. Inorg. Chim. Acta, 2011,376:664-670
12. [12]
  [12] Zhao L Z, Li P, Cao B L, et al. Acta Crystallogr. Sect. E, 2009,65:m613-m613
13. [13]
  [13] Geng J C, Qin L, He C H, et al. Transition Met. Chem., 2012,37:579-585
14. [14]
  [14] LIU Tong-Fei(刘同飞), CUI Guang-Hua(崔广华), JIAO Cui- Huan(焦翠欢), et al. Chinese. J. Inorg. Chem.(Wuji Huaxue Xuebao), 2011,27:1417-1422
15. [15]
  [15] Cai Y P, Su C Y, Zhang H X, et al., et al. Z. Anorg. Allg. Chem., 2002,628:2321-2328
16. [16]
  [16] Li J, Li L, Hou H, et al. J. Organomet. Chem., 2009,694: 1359-1368
17. [17]
  [17] Wang X L, Hou L L, Zhang J W, et al. CrystEngComm, 2012,14:3936-3944
18. [18]
  [18] Aakeröy C B, Desper J, Elisabeth E, et al. Z. Kristallogr., 2005,220:325-332
19. [19]
  [19] Sheldrick G M. Acta Cryst, 2008,A64:112-122
20. [20]
  [20] Spek A L, Platon A. Multipurpose Crystallographic Tool. Utrecht, The Netherlands: Utrecht University, 2000.
21. [21]
  [21] Wang J, Ren Z G, Dai M, et al. CrystEngComm, 2011,13: 5111-5118
22. [22]
  [22] Deacon G B, Phillips R J. Coord. Chem. Rev., 1980,33:227- 250
23. [23]
  [23] Keypour H, Shayesteh M, Golbedaghi R, et al. J. Coord. Chem., 2012,65:1004-1016
24. [24]
  [24] Ocampo A M. Thesis for the Doctorate of Washington State University. 2009.
25. [25]
  [25] Jiao C H, He C H, Cui G H, et al. Transition Met. Chem., 2012,37:17-23
1. [1]
  Jing WU , Puzhen HUI , Huilin ZHENG , Pingchuan YUAN , Chunfei WANG , Hui WANG , Xiaoxia GU . Synthesis, crystal structures, and antitumor activities of transition metal complexes incorporating a naphthol-aldehyde Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2422-2428. doi: 10.11862/CJIC.20240278
2. [2]
  Xinting XIONG , Zhiqiang XIONG , Panlei XIAO , Xuliang NIE , Xiuying SONG , Xiuguang YI . Synthesis, crystal structures, Hirshfeld surface analysis, and antifungal activity of two complexes Na(Ⅰ)/Cd(Ⅱ) assembled by 5-bromo-2-hydroxybenzoic acid ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1661-1670. doi: 10.11862/CJIC.20240145
3. [3]
  Jiaming Xu , Yu Xiang , Weisheng Lin , Zhiwei Miao . Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies. University Chemistry, 2024, 39(3): 239-257. doi: 10.3866/PKU.DXHX202309093
4. [4]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
5. [5]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
6. [6]
  Jingjing QING , Fan HE , Zhihui LIU , Shuaipeng HOU , Ya LIU , Yifan JIANG , Mengting TAN , Lifang HE , Fuxing ZHANG , Xiaoming ZHU . Synthesis, structure, and anticancer activity of two complexes of dimethylglyoxime organotin. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1301-1308. doi: 10.11862/CJIC.20240003
7. [7]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
8. [8]
  Jingyu Cai , Xiaoyu Miao , Yulai Zhao , Longqiang Xiao . Exploratory Teaching Experiment Design of FeOOH-RGO Aerogel for Photocatalytic Benzene to Phenol. University Chemistry, 2024, 39(4): 169-177. doi: 10.3866/PKU.DXHX202311028
9. [9]
  Linjie ZHU , Xufeng LIU . Electrocatalytic hydrogen evolution performance of tetra-iron complexes with bridging diphosphine ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 321-328. doi: 10.11862/CJIC.20240207
10. [10]
  Shiyan Cheng , Yonghong Ruan , Lei Gong , Yumei Lin . Research Advances in Friedel-Crafts Alkylation Reaction. University Chemistry, 2024, 39(10): 408-415. doi: 10.12461/PKU.DXHX202403024
11. [11]
  Xin MA , Ya SUN , Na SUN , Qian KANG , Jiajia ZHANG , Ruitao ZHU , Xiaoli GAO . A Tb₂ complex based on polydentate Schiff base: Crystal structure, fluorescence properties, and biological activity. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1347-1356. doi: 10.11862/CJIC.20230357
12. [12]
  Xiaoling LUO , Pintian ZOU , Xiaoyan WANG , Zheng LIU , Xiangfei KONG , Qun TANG , Sheng WANG . Synthesis, crystal structures, and properties of lanthanide metal-organic frameworks based on 2, 5-dibromoterephthalic acid ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1143-1150. doi: 10.11862/CJIC.20230271
13. [13]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . 杂多酸H₃PW₁₂O₄₀高效催化MgH₂储氢. Acta Physico-Chimica Sinica, 2025, 41(1): 2308032-. doi: 10.3866/PKU.WHXB202308032
14. [14]
  Xiaowei TANG , Shiquan XIAO , Jingwen SUN , Yu ZHU , Xiaoting CHEN , Haiyan ZHANG . A zinc complex for the detection of anthrax biomarker. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1850-1860. doi: 10.11862/CJIC.20240173
15. [15]
  Yan Liu , Yuexiang Zhu , Luhua Lai . Introduction to Blended and Small-Class Teaching in Structural Chemistry: Exploring the Structure and Properties of Crystals. University Chemistry, 2024, 39(3): 1-4. doi: 10.3866/PKU.DXHX202306084
16. [16]
  Weina Wang , Fengyi Liu , Wenliang Wang . “Extracting Commonality, Delving into Typicals, Deriving Individuality”: Constructing a Knowledge Graph of Crystal Structures. University Chemistry, 2024, 39(3): 36-42. doi: 10.3866/PKU.DXHX202308029
17. [17]
  Junqiao Zhuo , Xinchen Huang , Qi Wang . Symbol Representation of the Packing-Filling Model of the Crystal Structure and Its Application. University Chemistry, 2024, 39(3): 70-77. doi: 10.3866/PKU.DXHX202311100
18. [18]
  Wenyan Dan , Weijie Li , Xiaogang Wang . The Technical Analysis of Visual Software ShelXle for Refinement of Small Molecular Crystal Structure. University Chemistry, 2024, 39(3): 63-69. doi: 10.3866/PKU.DXHX202302060
19. [19]
  Jinfeng Chu , Lan Jin , Yu-Fei Song . Exploration and Practice of Flipped Classroom in Inorganic Chemistry Experiment: a Case Study on the Preparation of Inorganic Crystalline Compounds. University Chemistry, 2024, 39(2): 248-254. doi: 10.3866/PKU.DXHX202308016
20. [20]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 100035-. doi: 10.3866/PKU.WHXB202406014

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(228)
HTML views(35)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142