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Citation: CHEN Lin-Lin, LIU Jun-Chen, JIANG Zhen-Shen, GAN Gui-Lian, LI Hong. Copper(Ⅱ)-Tuned Photoluminescence of [Ru(bpy)2(dppz)]2+ Enhanced by SDS and DNA in Ethanol and Tris-water Mixtures[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(6): 1176-1184. doi: 10.3969/j.issn.1001-4861.2013.00.169 shu

Copper(Ⅱ)-Tuned Photoluminescence of [Ru(bpy)2(dppz)]2+ Enhanced by SDS and DNA in Ethanol and Tris-water Mixtures

  • 1.

    School of Chemistry and Environment, South China Normal University, Guangzhou 510006, China

  • Received Date: 19 December 2012
    Available Online: 6 February 2013

    Fund Project: 国家自然科学基金(No.21271075) (No.21271075)广东省自然科学基金(No.10351063101000001)资助项目。 (No.10351063101000001)

  • The copper(Ⅱ)-tuned photoluminescence of [Ru(bpy)2(dppz)]2+ (bpy=2,2'-bipyridine and dppz=dipyrido[3,2-a:2',3'-c]phenazine) enhanced by DNA and sodium dodecylsulfate (SDS) has been investigated in ethanol and water mixtures by means of fluorescence spectroscopy, fluorescence microscopic imaging and voltammetry. The photoluminescence of [Ru(bpy)2(dppz)]2+ in the ethanol/Tris-water mixed system (VEthanol:VTris=1:5) is enhanced by DNA and anionic surfactant SDS, whose binding constants with the Ru(Ⅱ) complex are 5.5×105 and 4.2×102 L·mol-1, respectively. The presence of Cu(Ⅱ) ions can quench the photoluminescence of [Ru(bpy)2(dppz)]2+ in the DNA-containing mixed system via the DNA-mediated photoinduced electron transfer, in which the Stern-Volmer constant is 2.0×105 L·mol-1, being far larger than that in the SDS-containing system (9.0×103 L·mol-1). In addition, combined with the effects of SDS, DNA and Cu(Ⅱ) ions on the redox reactions of [Ru(bpy)2(dppz)]2+ on an indium-tin oxide (ITO) electrode, the copper(Ⅱ)-tuned mechanism for the photoluminescence of [Ru(bpy)2(dppz)]2+ enhanced by DNA and SDS is further explored. This study not only helps us better understand the luminescence and quenching mechanisms of DNA intercalators, but also provides a new idea for the fabrication of biomolecular light switches.
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