Citation: LI Sha, ZHOU Hui, FAN Jie, XIAO Li-Ping. Synthesis of Mesoporous Aluminum Silicates and Their Catalytic Activity in Friedel-Crafts Alkylation Reaction[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 896-902. doi: 10.3969/j.issn.1001-4861.2013.00.160 shu

Synthesis of Mesoporous Aluminum Silicates and Their Catalytic Activity in Friedel-Crafts Alkylation Reaction

1.
Department of Chemistry, Zhejiang University, Hangzhou 310027, China

Corresponding author: XIAO Li-Ping,
Received Date: 16 December 2012
Available Online: 29 January 2013
Fund Project: 国家自然科学基金(No.21271153) (No.21271153)浙江省创新团队项目(No.2012R10014-06) (No.2012R10014-06)吉林大学无机合成与制备化学国家重点实验室开放基金 (2012-03)资助项目。 (2012-03)

Ordered mesoporous aluminum silicates with strong acid sites were synthesized by sol-gel method. The resulted materials' structures were characterized by XRD, TEM, ²⁷Al NMR, NH₃-TPD and Py-FT-IR. The amount of surfactant and the Si/Al mole ratio would both affect the materials' meso-structure; while, the amount of HAc has little effect on the structure. TEM analysis confirmed that these aluminum silicates with different Si/Al mole ratios have an ordered 2D hexagonal regularity. Friedel-Crafts alkylation reaction of anisole and benzyl alcohol was used as the probe reaction to detect the acidic properties of these aluminum silicates. The Si/Al mole ratio played an important role in catalytic activity and the aluminum silicates with n_Si/n_Al=10 showed the best acid catalytic activity. NH₃-TPD and Py-FT-IR suggested that the aluminum silicates with n_Si/n_Al=10 had much more Brönsted acidic sites than that of other Si/Al ratios.
- mesoporous materials;aluminum silicate;acid catalysis;Friedel-Crafts alkylation reaction
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