Citation: ZHOU Xiao-Shuang, YOU Zhong-Lu, XIAN Dong-Mei, DONG Da-Peng. Synthesis, Crystal Structure, Thermal Stability, and Magnetic Property of an End-to-End Azido-Bridged Dinuclear Schiff Base Copper(Ⅱ) Complex[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 850-854. doi: 10.3969/j.issn.1001-4861.2013.00.111 shu

Synthesis, Crystal Structure, Thermal Stability, and Magnetic Property of an End-to-End Azido-Bridged Dinuclear Schiff Base Copper(Ⅱ) Complex

1.
Department of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, Liaoning 116029, China

Received Date: 12 July 2012
Available Online: 21 December 2012
Fund Project: 国家自然科学基金(No.20901036) (No.20901036) 辽宁省高校优秀青年人才支持计划(No.LJQ2011114)资助项目。 (No.LJQ2011114)

A new dinuclear azido-bridged copper(Ⅱ) complex [Cu₂L₂( μ_1,3-N₃)₂] bearing crystallographic two-fold rotation axis symmetry has been synthesized from the tridentate Schiff base ligand 5-(ethylmethylamino)-2-[(2-morpholin-4-ylethylimino)methyl]phenol (HL) and sodium azide with copper(Ⅱ) acetate in methanol. The complex was characterized by elemental analyses, infrared spectroscopy, and X-ray single crystal determination. Crystal of the complex is crystallize as orthorhombic space group P2₁2₁2, with a=0.974 6(1), b=1.378 4(2), c=1.504 1(2) nm, V=2.023 3(5) nm³, Z=2, R₁=0.063 8, wR₂=0.166 8. Thermal stability and magnetic property of the complex were studied. CCDC: 890948.
- synthesis;crystal structure;copper(Ⅱ) complex;Schiff base;thermal stability;magnetic property
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沈阳化工大学材料科学与工程学院沈阳 110142