Citation: MENG Wei, ZHANG Ling-Yan, JIANG Xiao-Hong, LU Lu-De, WANG Xin. SERS of Crystal Violet Adsorbed on Submicrometer Rod-Like ZnO[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 571-576. doi: 10.3969/j.issn.1001-4861.2013.00.082 shu

SERS of Crystal Violet Adsorbed on Submicrometer Rod-Like ZnO

1.
1. Key Laboratory for Soft Chemistry and Functional Materials of Ministry Education, Nanjing University of Science and Technology, Nanjing 210094, China;

Received Date: 21 September 2012
Available Online: 13 November 2012
Fund Project: 国家自然科学基金(No.50972059)资助项目。 (No.50972059)

Submicrometer rod-like ZnO was prepared by wet-chemical technique at 70 ℃. The material was characterized by UV-vis spectroscopy (UV-Vis), scanning electron microscopy (SEM), X-ray diffraction (XRD) and Raman spectroscopy. The optimized geometry of crystal violet (CV) was calculated at DFT/B3LYP level with 6-311G* basis set. Meanwhile, the surface-enhanced Raman scattering (SERS) activity of submicrometer rod-like ZnO was investigated using CV as a probe molecular. Results show that the rod-like submicrometer ZnO has high purity and crystallinity, which belongs to the Wurtzite-type structure. The enhancement factor of CV adsorbed on rod-like ZnO is up to 1.2×10², which is attributed to chemical enhancement.
- SERS;rod-like ZnO;crystal violet;DFT
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