Citation: YANG Ying, CUI Jia-Rui, YI Peng-Fei, XIAO Si, GUO Xue-Yi. Effect of NiO Nanoparticles on Magnetic Quasi-Solid Dye-Sensitized Solar Cells[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(5): 1007-1012. doi: 10.3969/j.issn.1001-4861.2013.00.076 shu

Effect of NiO Nanoparticles on Magnetic Quasi-Solid Dye-Sensitized Solar Cells

YANG Ying ¹ ,
CUI Jia-Rui ¹ ,
YI Peng-Fei ¹ ,
XIAO Si ² ,
GUO Xue-Yi ^1,,

1.
1. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China;

Corresponding author: GUO Xue-Yi,
Received Date: 14 September 2012
Available Online: 30 October 2012
Fund Project:

A magnetic polymer electrolyte using agarose as polymer matrix, NMP as solvent and NiO nanoparticles as modifier was investigated and employed in the dye-sensitized solar cell (DSSC) in this paper. The influence of NiO nanoparticles content on magnetic polymer electrolyte was characterized by SEM and ionic conductivity test. The photovoltaic properties of the corresponding DSSCs with different concentrations of NiO nanoparticles were studied by photovoltaic performance tests and electrochemical impedance spectra (EIS). The results showed that the optimal concentration of NiO nanoparticles was 1.0wt%, in which concentration the surface morphology of the polymer electrolyte was smooth and this magnetic polymer electrolyte showed the maximum conductivity (2.43×10^-3 S·cm^-1). The photoelectric efficiency and electron lifetime of DSSCs increased initially and then decreased with the increasing of the NiO nanoparticles content, the optimal photoelectric efficiency as well as the longest electron lifetime were achieved at the NiO nanoparticles content of 1.0wt%. At this optimal content, the photoelectric efficiency of DSSC was 1.63%, the voltage, current density and the filling factor of the DSSC was 0.57 V, 5.8 mA·cm^-2 and 0.53, respectively.
- magnetic polymer electrolyte;dye-sensitized solar cell;NiO nanoparticles;ionic conductivity;electrochemical impedance
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