Citation: YUAN Wei, LIU Fang, ZHANG Zhao. Preparation and Characterization of Mesoporous Nickel Oxide Templated by Different Mixed Surfactants[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(4): 803-809. doi: 10.3969/j.issn.1001-4861.2013.00.052 shu

Preparation and Characterization of Mesoporous Nickel Oxide Templated by Different Mixed Surfactants

1.
College of Chemical Engineering, Sichuan University, Chengdu 610065, China

Received Date: 28 August 2012
Available Online: 30 October 2012
Fund Project: 国家自然科学基金(No.51004074)资助项目。 (No.51004074)

Mesoporous nickel oxide was prepared by hydrothermal method using Ni(NO₃)₂·6H₂O as the nickel source, urea as the precipitant and mixed surfactant SDS/P123, CTAB/P123, CTBA/SDS as the template, at a low consumption of total surfactant. The precursor and final products were characterized by TG-DSC, FTIR, XRD, N₂ adsorption-desorption, SEM and TEM. Electrochemical performances were examined by cyclic voltammetry, constant current charge-discharge and electrical impedance spectroscopy. The results show that NiO templated by mixed surfactant SDS/P123 has the highest specific surface area, pore volume and capacitance of 209 m²·g^-1, 0.407 cm³·g^-1 and 265 F·g^-1, respectively, when the mass ratio of m_SDS:m_P123=2:1.
- mesoporous materials;nickel oxide;template method;electrochemistry;mixed surfactant
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沈阳化工大学材料科学与工程学院沈阳 110142