Citation: Yildiz E, Karadeniz B, Yildiz A M, Rencuzogullari E. Bivalent and Trivalent Transition Metal Complexes of Azo Compounds Derived from Anthraquinone and Their Mutagenic-Teratogenic Effects[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 595-604. doi: 10.3969/j.issn.1001-4861.2013.00.033 shu

Bivalent and Trivalent Transition Metal Complexes of Azo Compounds Derived from Anthraquinone and Their Mutagenic-Teratogenic Effects

1.
1. Department of Chemistry, Arts and Science Faculty, Cukurova University, Balcali 01330, Adana, Turkiye;

Received Date: 25 May 2012
Available Online: 6 September 2012
Fund Project:

4-(5'-aminonaphtalene-3'-sulfonic acid)azo-(2″-N-(4''', 6'''-dichloro-S-triazine) benzene-5″-(β-sulfatoethyl sulfonyl)-2-methyl anthraquinone (2a), 4-(2'-aminobenzenesulfonic acid)azo-(2″-N-(4''', 6'''-dichloro-S-triazine)-3″-benzensulfonic acid)-2-methyl anthraquinone, 4-(5'-aminonaphtalene-3'-sulfonic acid)azo-(2″-N-(4''', 6'''-dichloro-S-triazine)benzen-5″-(β-sulfatoethyl sulfonyl)-2-methyl anthraquinone and 4-(p-(β-sulfatoethyl sulfonyl) azo-(2″-N-(4''', 6'''-dichloro-S-triazine) naphtalene-5″sulfonic acid)-2-methyl anthraquinone with Fe^Ⅲ,Co^Ⅱ metal complexes were prepared and used for determination of mutagenic and teratogenic effects in Ames/Salmonella/Microsome Test and in embryos of rats. 2a-Fe and 2a-Co were not mutagenic for both TA98 and TA100 strains with and without metabolic activator S9mix.
- anthraquinone;azo;metal complex;mutagenicity;teratogenicity
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沈阳化工大学材料科学与工程学院沈阳 110142