Citation: XIAO Xiu-Feng, LIANG Jian-He, TANG Hai-Zhen, YANG Xiao-Juan, LIU Rong-Fang. Preparation and Characterization of TiO₂ Nanotubes Array by Anodic Oxidation in Anionic Modified Glycerol-Based Electrolyte[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(3): 544-550. doi: 10.3969/j.issn.1001-4861.2013.00.004 shu

Preparation and Characterization of TiO₂ Nanotubes Array by Anodic Oxidation in Anionic Modified Glycerol-Based Electrolyte

1.
1. College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, China;

Received Date: 23 April 2012
Available Online: 31 July 2012
Fund Project: 国家自然科学基金(No.30970887,30600149) (No.30970887,30600149)卫生部科学研究基金(No.WKJ2008-02-037) (No.WKJ2008-02-037)福建省杰青项目(No.2011J06019) (No.2011J06019)教育部重点项目(No.209061) (No.209061)福建省纳米材料重点实验室科学基金(No.NM10-03)资助项目。 (No.NM10-03)

High-order TiO₂ nanotube arrays on titanium foils were prepared in glycerol-based electrolyte containing fluorine and water by electrochemical anodic oxidation in this work. The influence of different dianion additives, different oxidation duration and concentration of electrolyte additives on the effect of the morphology of TiO₂ nanotube arrays were investigated. Results showed that the length of TiO₂ nanotube arrays in the modified electrolyte were longer than the samples in the unmodified electrolyte. And with the growth of oxidation duration, the diameter of the nanotubes increased, the wall were thinner; moreover better and longer TiO₂ nanotube arrays can be prepared in the glycerol-based electrolyte with the range of the concentration of (NH₄)₂TiF₆.
- TiO₂ nanotube arrays;anodic oxidation;fluorine titanate amines
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沈阳化工大学材料科学与工程学院沈阳 110142

Preparation and Characterization of TiO2 Nanotubes Array by Anodic Oxidation in Anionic Modified Glycerol-Based Electrolyte

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Preparation and Characterization of TiO₂ Nanotubes Array by Anodic Oxidation in Anionic Modified Glycerol-Based Electrolyte