Citation: Yang Qi, Xie Gang, Chen Sanping, Zhang Yifan, Guo Peiyu, Gao Shengli. Learning the Stability and Activation of Chemical Bond of the Nitrogen Molecule from Ammonia Synthesis[J]. University Chemistry, ;2015, 30(6): 33-44. doi: 10.3866/pku.DXHX20150633 shu

Learning the Stability and Activation of Chemical Bond of the Nitrogen Molecule from Ammonia Synthesis

1.
College of Chemistry and Materials Science, Northwest University, Xi'an 710069, Shaanxi, China

Corresponding author: Chen Sanping,
Fund Project: 第三批国家级精品资源共享课(教高函[2013]132号) (教高函[2013]132号)国家级教学团队《无机化学和分析化学基础课教学团队》(教高函、[2007]23号) (教高函、[2007]23号)国家基础科学人才培养基金(No.J1210057) (No.J1210057)

This paper discusses the stability of the nitrogen molecule based on the chemical bond, and then introduces researches related to the nitrogen chemical bond activation from the industrial ammonia synthesis. The authors desire to explore a new approach for teaching elemental chemistry. The aim is to lead students to study and use the knowledge to learn the natural world, and improve the ability to analyze and solve problems.
- Ammonia synthesis,
- Nitrogenase,
- Nitrogen complex,
- Teaching method
1. [1]
  [1] Theodore G.The Elements:A Visual Exploration of Every Known Atom in the Universe.New York:BlackDog & Leventhal,2009
2. [2]
  [2] Haynes W H.Handbook of Chemistry and Physics.91st ed.Boca Raton:CRC,2010-2011
3. [3]
  [3] Al-Joboury M I,May D P,Turner D W.J Chem Soc,1965,44:44616
4. [4]
  [4] Turner D W,May D P.J Chem Phys,1966,45:471
5. [5]
  [5] Mulliken R S.Can J Chem,1958,36:10
6. [6]
  [6] Sellmann D.Angew Chem Int Ed,1974,13(10):639
7. [7]
  [7] Heidemann.Chem Ztg,1921,45:1073
8. [8]
  [8] Andersen E B.Z Physik,1922,10:54
9. [9]
  [9] Storch H H,Olson A R.J Am Chem Soc,1923,45:1605
10. [10]
  [10] Modak J M.Resonance,2002,7:69
11. [11]
  [11] Freund H J,Knozinger H.J Phys Chem B,2004,108(38):14183
12. [12]
  [12] Ertl G,Vac J.Sci Tech A,1983,1:1247
13. [13]
  [13] 马秀芳,邓辉球,李微雪.科技导报,2007,25(24):25
14. [14]
  [14] Kitano M,Inoue Y,Yamazaki Y,et al.Nature Chem,2012,4:934
15. [15]
  [15] 徐晔,张金池,王广林,等.生物学杂志,2011,28(4):61
16. [16]
  [16] 张纯喜.化学进展,1997,9(2):131
17. [17]
  [17] 黄静伟,张鸿图,万惠霖,等.生物化学与生物物理进展,1996,23(1):18
18. [18]
  [18] 周朝晖,颜文斌,张凤章,等.厦门大学学报(自然科学版),2001,40(2):321
19. [19]
  [19] 王友绍,李季伦.自然科学进展,2000,10(6):482
20. [20]
  [20] Burris R H.J Biol Chem,1991,266(15):9339
21. [21]
  [21] Robson R L,Eady R R,Richardson T H,et al.Nature,1986,322:388
22. [22]
  [22] Simpson F B,Burris R H.Science,1984,224:1095
23. [23]
  [23] Johnson W H O.Science,1992,257:1639
24. [24]
  [24] Kim J,Rees D C.Biochem J,1994,33(2):389
25. [25]
  [25] Thoreley R N F,Lowe D J.Biochem J,1983,215(2):393
26. [26]
  [26] Thoreley R N F,Lowe D J.Kinetics and Mechanism of the Nitrogenaseenzyme System.New York:Weily,1985
27. [27]
  [27] Chan M K,Kim J,Rees D C.Science,1993,260:792
28. [28]
  [28] Deng H,Hoffmann R.Angew Chem Int Ed,1993,32(7):1062
29. [29]
  [29] Dance I G.Aust J Chem,1994,47(5):979
30. [30]
  [30] Zhong S J,Liu C W.Polyhedron,1997,16(4):653
31. [31]
  [31] 吴新涛,卢嘉锡.科学通报,1995,40(7):577
32. [32]
  [32] Tsai K R,Wan H L.J Cluster Science,1995,6(4):485
33. [33]
  [33] 黄静伟,张风章,许良树,等.高等学校化学学报,1995,16(6):920
34. [34]
  [34] Shah V K,Brill W J.Proc Natl Acad Sci, 1977,74(8):3249
35. [35]
  [35] Camahan J E,Morteson L E,Mower H F,et al.Biochim Biophys Acta,1960,38:188
36. [36]
  [36] Camahan J E,Morteson L E,Mower H F,et al.Biochim Biophys Acta,1960,44:520
37. [37]
  [37] Morteson L E.Nitrogen Fixatin in Extracts of Clostridium Pasteuranium.Ohio:Antioch Press,1965
38. [38]
  [38] Kennedy C K,Eady P R,Kondorpsi E,et al.Biochem J,1976,155:383
39. [39]
  [39] Kim J,Rees D C.Nature,1992,360:553
40. [40]
  [40] Kim J,Rees D C.Science,1992,257:1677
41. [41]
  [41] Kim J,Woo D,Rees D C.Biochem,1993,32:7104
42. [42]
  [42] Kim J,Rees D C.Biochem,1994,33:389
43. [43]
  [43] Einsle O,Tezcan F A,Andrade S L A,et al.Science,2002,297:1696
44. [44]
  [44] Kyle M,Lancaster M R,Patrick E,et al.Science,2011,334:974
45. [45]
  [45] Thomas S,Müge A,Limei Z,et al.Science,2011,940
46. [46]
  [46] Ellison J J,Ruhlandt-Senge K,Power P P.Angew Chem Int Ed,1994,33(11):1178
47. [47]
  [47] Scott M J,Holm R H.Angew Chem Int Ed,1993,32(4):564
48. [48]
  [48] Demadis K D,Campana C F,Coucouvanis D J.J Am Chem Soc,1995,117(29):7832
49. [49]
  [49] Cen W,MacDonnell F M,Scott M I,et al.Inorg Chem,1994,33(25):5809
50. [50]
  [50] Leigh G J,Jimenez-Tenorio M J.J Am Chem Soc,1991,113(15):5862
51. [51]
  [51] 张致贵,刘喜生,樊玉国.科学通报,1985,30(12):913
52. [52]
  [52] Strasdeit H,Krebs B,Henkel G.Inorg Chem,1984,23(13):1816
53. [53]
  [53] Hagen K S,Watson A D,Hlm R H.J Am Chem Soc,1983,105(12):3905
54. [54]
  [54] Christou G,Sabat M,Ibers J A,et al.Inorg Chem,1982,21(9):3518
55. [55]
  [55] 张致贵,樊玉国,李宇,等.科学通报,1986,31(21):1634
56. [56]
  [56] Evans W J,Ulibarri T A,Ziller J W.J Am Chem Soc,1988,110:6877
57. [57]
  [57] Camenznd M J.Chem Commun,1986,1137
58. [58]
  [58] Sellmann D.Angew Chem Int Ed,1974,13:639
59. [59]
  [59] Chatt J,Leigh G J.Chem Soc Rev,1972,1:121
60. [60]
  [60] Dallen A,Harria R O,Loescher B R,et al.Chem Rev,1973,11:73
61. [61]
  [61] Chatt J,Dilworth J R,Richards R L.Chem Rev,1978,78:589
62. [62]
  [62] 项斯芬,严宣申,曹庭礼,等.无机化学丛书.第四卷.北京:科学出版社,1995
63. [63]
  [63] 席振峰,金斗满.化学通报,1991(3):1
64. [64]
  [64] Vol'pin M E,Shur V B.Doklady Akad Nauk SSSR,1964,156:1102
65. [65]
  [65] Vol'pin M E,Shur V B,Vestnik.Doklady Akad Nauk SSSR,1965,157:51
66. [66]
  [66] Vol'pin M E,Shur V B,Bichin L P.Doklady Akad Nauk SSSR,1965,157:720
67. [67]
  [67] Allen A D,Senoff C V.Chem Commu,1965:621
68. [68]
  [68] 吴永仁.中国中学教学百科全书-化学卷.沈阳:沈阳出版社
69. [69]
  [69] Turder J J,Simpion M B,Poliakoff M,et al.Inorg Chem,1986,22:911
70. [70]
  [70] Davis B R,Payne N C,Ibert J A.Inorg Chem,1969,8:2719
71. [71]
  [71] Merceer M,Crabtrec R H,Ricbards R L.Chem Commun,1973:808
72. [72]
  [72] Merceer M.Dolton Tran,1974:1637
73. [73]
  [73] Hammer R,Klein H F,Friedrich P,et al.Angew Chem Int Ed,1977,16:485
74. [74]
  [74] Kroger C,Tsay Y H.Angew Chem Int Ed,1973,12:998
75. [75]
  [75] Chatt J,Pearman A J,Richards R L.Dolton Trans,1977,1853
76. [76]
  [76] Chatt J,Pearman A J,Richards R L.Nature,1975,253:39
77. [77]
  [77] Collman J,Hutchinson J E,Lopez M A,et al.J Am Chem Soc,1991,113:2794
78. [78]
  [78] Taqui Khan M M.Angew Chem Int Ed,1988,27:923
79. [79]
  [79] Nast R,Ronner M.Z Anorg Chem,1956,285:278
80. [80]
  [80] 忻飞波,郑丽敏,忻新泉.无机化学学报,1992,8(1):82
81. [81]
  [81] Nishibayashi Y,Iwai S,Hidai M.Science,1988,279:540
82. [82]
  [82] Knobloch D J,Lobkovsky E,Chirik P J.Nature Chem,2010,2:30
83. [83]
  [83] Mailhiot C,Yang L H,McMahan A K.Phys Rev B,1992,46:14419
84. [84]
  [84] Zahariev F,Hu A,Hopper J,et al.Phys Rev B,2005,72:214108
85. [85]
  [85] Martin R M.Phys Rev Lett,2003,91:105501
86. [86]
  [86] Eremets M I,Gavriliuk A G,Trojan I A,et al.Nat Mater,2004,3:558
87. [87]
  [87] 王晓丽.高压下固态氮的相变研究与新型碳氮超硬材料的理论设计.长春:吉林大学,2011
88. [88]
  [88] Wang X L,Bao K,Tian F B,et al.J Chem Phys,2010,133:044512
89. [89]
  [89] Wang X L,Bao K,Wang L C,et al.J Chem Phys,2010,132:024502
90. [90]
  [90] Wang X L,He Z,Ma Y M,et al.J Phys Condens Matter,2007,19:425226
91. [91]
  [91] Wang L C,Bao K,Meng X.J Chem Phys,2011,134:024517
92. [92]
  [92] Polymeric Nitrogen Synthesized.http://phys.org/news693.html,2004-08-05/2014-06-16
93. [93]
  [93] Fabian J,Lewars E.Cana J Chem, 2004,82(1):50
94. [94]
  [94] U N Patil,Dhumal N R,Gejji S P.Theore Chim Acta,2004,112:27
95. [95]
  [95] Glukhovtsev M N,Jiao H J,Schleyer P R,et al.Inorg Chem,1996,35:7124
96. [96]
  [96] 谢钢,杨奇,陈三平,等.大学化学,2012,27(5):36
97. [97]
  [97] 陈三平,谢钢,杨奇,等.大学化学,2012,27(3):13
1. [1]
  Fan Yang , Yanhong Bai , Pin Gao , Xinhua Duan , Yunchuan Xie . Exploration and Practice of Teaching Reform in Polymer Chemistry Experiment Course. University Chemistry, 2025, 40(10): 63-71. doi: 10.12461/PKU.DXHX202412013
2. [2]
  Quanliang Chen , Zhaohui Zhou . Research on the Active Site of Nitrogenase over Fifty Years. University Chemistry, 2024, 39(7): 287-293. doi: 10.3866/PKU.DXHX202310133
3. [3]
  Renxiu Zhang , Xin Zhao , Yunfei Zhang . Application of Electrochemical Synthesis in the Teaching of Organic Chemistry. University Chemistry, 2025, 40(4): 174-180. doi: 10.12461/PKU.DXHX202406116
4. [4]
  Guoxian Zhu , Jing Chen , Rongkai Pan . Enhancing the Teaching Quality of Atomic Structure: Insights and Strategies. University Chemistry, 2024, 39(3): 376-383. doi: 10.3866/PKU.DXHX202305027
5. [5]
  Liqiang Huang , Peng Lin . 数-图分析法解释仪器分析实验课程教学中的难点. University Chemistry, 2025, 40(6): 353-359. doi: 10.12461/PKU.DXHX202407074
6. [6]
  Yehong Zhou , Li Wang , Shaomin Shuang . Pedagogical Practice and Challenges of Teaching Chemistry Courses in English for Postgraduate Students in the Context of Internationalized Education. University Chemistry, 2025, 40(9): 368-374. doi: 10.12461/PKU.DXHX202410084
7. [7]
  Zhentong Zhu , Peiyao Du , Chaoqin Zeng , Rui Zhou , Xiaoyan He , Bingzhang Lu , Xiaoquan Lu . Discussion on Teaching Methods for Bilingual Courses in Instrumental Analysis for Chemistry Majors. University Chemistry, 2025, 40(10): 39-45. doi: 10.12461/PKU.DXHX202411014
8. [8]
  Guojie Xu , Fang Yu , Yunxia Wang , Meng Sun . Introduction to Metal-Catalyzed β-Carbon Elimination Reaction of Cyclopropenones. University Chemistry, 2024, 39(8): 169-173. doi: 10.3866/PKU.DXHX202401060
9. [9]
  Xiaopeng Huang , Yuxin Wang , Shunsong Zhang , Yili Wang , Zihang Xu , Kaojin Wang , Xiaoxia Zhu . Exploration of Diversified Reforms in English for Chemical Professionals. University Chemistry, 2026, 41(3): 282-290. doi: 10.12461/PKU.DXHX202503090
10. [10]
  Shangwen Luo , Jianguo Fang , Yanlong Yang , Shihui Dong . 化学生物学课程双语教学实践与探索. University Chemistry, 2025, 40(8): 124-129. doi: 10.12461/PKU.DXHX202410096
11. [11]
  Xu Long , Shuan Zhang , Qinghua Meng , Xiaorong Li . Practice of Ideological and Political Education in Analytical Chemistry from the Perspective of New Medicine: Redox Titration. University Chemistry, 2025, 40(11): 108-114. doi: 10.12461/PKU.DXHX202412025
12. [12]
  Peifeng Su , Xin Lu . Development of Undergraduate Quantum Mechanics Module in Chemistry Department under the “Double First Class” Initiative. University Chemistry, 2024, 39(8): 99-103. doi: 10.3866/PKU.DXHX202401087
13. [13]
  Dongdong Yao , JunweiGu , Yi Yan , Junliang Zhang , Yaping Zheng . Teaching Phase Separation Mechanism in Polymer Blends Using Process Representation Teaching Method: A Teaching Design for Challenging Theoretical Concepts in “Polymer Structure and Properties” Course. University Chemistry, 2025, 40(4): 131-137. doi: 10.12461/PKU.DXHX202408125
14. [14]
  Yuyang Zhang , Yuqing Zhang , Quanxing Mao , Zixuan Chen , Ying Xiong . Application of Real-World Problem-Oriented Teaching Methods in Analytical Chemistry Course. University Chemistry, 2025, 40(10): 17-22. doi: 10.12461/PKU.DXHX202411072
15. [15]
  Hong RAO , Yang HU , Yicong MA , Chunxin LÜ , Wei ZHONG , Lihua DU . Synthesis and in vitro anticancer activity of phenanthroline-functionalized nitrogen heterocyclic carbene homo- and heterobimetallic silver/gold complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2429-2437. doi: 10.11862/CJIC.20240275
16. [16]
  Jiaxun Wu , Mingde Li , Li Dang . The R eaction of Metal Selenium Complexes with Olefins as a Tutorial Case Study for Analyzing Molecular Orbital Interaction Modes. University Chemistry, 2025, 40(3): 108-115. doi: 10.12461/PKU.DXHX202405098
17. [17]
  Hong Wu , Yuxi Wang , Hongyan Feng , Xiaokui Wang , Bangkun Jin , Xuan Lei , Qianghua Wu , Hongchun Li . Application of Computational Chemistry in the Determination of Magnetic Susceptibility of Metal Complexes. University Chemistry, 2025, 40(3): 116-123. doi: 10.12461/PKU.DXHX202405141
18. [18]
  Tingyu Zhu , Hui Zhang , Wenwei Zhang . Exploration and Practice of Ideological and Political Education in the Course of Experiments on Chemical Functional Molecules: Synthesis and Catalytic Performance Study of Chiral Mn(III)Cl-Salen Complex. University Chemistry, 2024, 39(4): 75-80. doi: 10.3866/PKU.DXHX202311011
19. [19]
  Chi Li , Jichao Wan , Qiyu Long , Hui Lv , Ying Xiong . N-Heterocyclic Carbene (NHC)-Catalyzed Amidation of Aldehydes with Nitroso Compounds. University Chemistry, 2024, 39(5): 388-395. doi: 10.3866/PKU.DXHX202312016
20. [20]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1499)
HTML views(184)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142