Citation: Heng Chen, Longhui Nie, Kai Xu, Yiqiong Yang, Caihong Fang. Remarkable Photocatalytic H₂O₂ Production Efficiency over Ultrathin g-C₃N₄ Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination[J]. Acta Physico-Chimica Sinica, ;2024, 40(11): 240601. doi: 10.3866/PKU.WHXB202406019 shu

Remarkable Photocatalytic H₂O₂ Production Efficiency over Ultrathin g-C₃N₄ Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination

School of Materials and Chemical Engineering, Hubei University of Technology, Wuhan 430068, China

Corresponding author: Longhui Nie, nielonghui@mail.hbut.edu.cn
Received Date: 17 June 2024
Revised Date: 18 July 2024
Accepted Date: 18 July 2024
Available Online: 5 August 2024
Fund Project: the Natural Science Foundation of China 51572074Open Fund of Key Laboratory of Drug Analysis and Anti-drug Technology of the Ministry of Public Security YNPL-B2021002

The generation of hydrogen peroxide (H₂O₂) from water and oxygen redox reaction by photocatalysis has acquired increasing attention owing to its green and clean properties. Aiming at the low intrinsic photocatalytic activity of carbon nitride (g-C₃N₄), here, an ultrathin g-C₃N₄ nanosheet photocatalyst with a large surface area and enhanced crystallinity was fabricated by a two-step thermal polymerization technique. The calcination parameters showed a significant impact on the structural properties and catalytic performance of g-C₃N₄. The remarkable H₂O₂ yield (3177.0 µmol·g^-1·h^-1) of CN-T-1 (by two-step calcination, 1 ℃·min^-1 optimal heating rate) was 3.7 times that (858.6 µmol·g^-1·h^-1) of CN-O-1 (by one-step calcination, 1 ℃·min^-1 heating rate) and higher than those of pure g-C₃N₄ in literature. Most of the H₂O₂ yield for CN-T-1 remained after five cycles, showing good stability. The enhanced catalytic performance of CN-T-1 than CN-O-1 is owing to its larger specific surface area, enhanced crystallinity, higher oxygen adsorption ability and photogenerated carrier separation efficiency, longer lifetime of carriers, and slightly larger bandgap (3.07 eV, +0.26 eV bigger than CN-O-1) with more positive valence band position owing to ultrathin layers. The •O₂^- radicals were verified to be the primary active species. A two-step single electron ORR pathway (O₂ + e^- → •O₂^- → H₂O₂) was confirmed for H₂O₂ production over CN-T-1.
- Photocatalytic,
- H₂O₂ production,
- g-C₃N₄ nanosheet,
- photocatalytic mechanism
1. [1]
  You, Q.; Zhang, C.; Cao, M.; Wang, B.; Huang, J.; Wang, Y.; Deng, S.; Yu, G. Appl. Catal. B 2023, 321, 121941. doi: 10.1016/j.apcatb.2022.121941 doi: 10.1016/j.apcatb.2022.121941
2. [2]
  Xie, K.; Zhuang, X.; Luo, X.; Jing, Z.; Song, X.; Hou, A.; Gao, A. Green Chem. 2023, 25, 4438. doi: 10.1039/d3gc00963g doi: 10.1039/d3gc00963g
3. [3]
  Li, X.; Li, P.; Li, Y.; Liu, H.; Yang, Z.; Chen, Y.; Liao, X. J. Environ. Chem. Eng. 2023, 11, 110594. doi: 10.1016/j.jece.2023.110594 doi: 10.1016/j.jece.2023.110594
4. [4]
  Yuan, J.; Chen, Q.; Xiao, Y.; Li, D.; Jiang, X.; Wu, P. Appl. Surf. Sci. 2023, 630, 157463. doi: 10.1016/j.apsusc.2023.157463 doi: 10.1016/j.apsusc.2023.157463
5. [5]
  Du, R.; Xiao, K.; Li, B.; Han, X.; Zhang, C.; Wang, X.; Zuo, Y.; Guardia, P.; Li, J.; Chen, J.; et al. Chem. Eng. J. 2022, 441, 135999doi: 10.1016/j.cej.2022.135999 doi: 10.1016/j.cej.2022.135999
6. [6]
  Wang, Y.; Yang, Z.; Zhang, C.; Feng, Y.; Shao, H.; Chen, J.; Hu, J.; Zhang, L. Ultrason. Sonochem. 2023, 99, 106582. doi: 10.1016/j.ultsonch.2023.106582 doi: 10.1016/j.ultsonch.2023.106582
7. [7]
  Ding, Y.; Maitra, S.; Esteban, D.; Bals, S.; Vrielinck, H.; Barakat, T.; Roy, S.; Tendeloo, G.; Liu, J.; Li, Y.; et al. Cell Rep. Phys. Sci. 2022, 3, 100874. doi: 10.1016/j.xcrp.2022.100874 doi: 10.1016/j.xcrp.2022.100874
8. [8]
  Gan, W; Guo, J.; Fu, X.; Jin, J.; Zhang, M.; Chen, R.; Ding, C.; Lu, Y.; Li, J.; Sun, Z. Sep. Purif. Technol. 2023, 317, 123791. doi: 10.1016/j.seppur.2023.123791 doi: 10.1016/j.seppur.2023.123791
9. [9]
  Yang, Y.; Liu, J.; Gu, M.; Cheng, B.; Wang, L.; Yu, J. Appl. Catal. B 2023, 333, 122780. doi: 10.1016/j.apcatb.2023.122780 doi: 10.1016/j.apcatb.2023.122780
10. [10]
  Zhao, Y.; Zhang, S.; Wu, Z.; Zhu, B.; Sun, G.; Zhang, J. Chin. J. Catal. 2024, 60, 219. doi: 10.1016/S1872-2067(23)64645-5 doi: 10.1016/S1872-2067(23)64645-5
11. [11]
  Han, G.; Xu, F.; Cheng, B.; Li, Y.; Yu, J.; Zhang, L. Acta Phys. -Chim. Sin. 2022, 38, 2112037. doi: 10.3866/PKU.WHXB202112037 doi: 10.3866/PKU.WHXB202112037
12. [12]
  Yin, X.; Shi, H.; Wang, Y.; Wang, X.; Wang, P.; Yu, H. Acta Phys. -Chim. Sin. 2024, 40, 2312007. doi: 10.3866/PKU.WHXB202312007 doi: 10.3866/PKU.WHXB202312007
13. [13]
  Zhu, Z.; Bao, L.; Pestov, D.; Xu, P.; Wang, W. Chem. Eng. J. 2023, 453, 139956. doi: 10.1016/j.cej.2022.139956 doi: 10.1016/j.cej.2022.139956
14. [14]
  Shi, H.; Li, Y.; Wang, X.; Yu, H.; Yu, J. Appl. Catal. B 2021, 297, 120414. doi: 10.1016/j.apcatb.2021.120414 doi: 10.1016/j.apcatb.2021.120414
15. [15]
  Zhao, Y.; Wang, L.; Malpass-Evans, R.; McKeown, N.; Carta, M.; Lowe, J.; Lyall, C.; Castaing, R.; Fletcher, P.; Kociok-Köhn, G.; et al. ACS Appl. Mater. Interf. 2022, 14, 19938. doi: 10.1021/acsami.1c23960 doi: 10.1021/acsami.1c23960
16. [16]
  Yin, F.; Qin, P.; Xu, J.; Cao, S. Acta Phys. -Chim. Sin. 2023, 39, 2212062. doi: 10.3866/PKU.WHXB202212062 doi: 10.3866/PKU.WHXB202212062
17. [17]
  Chu, C.; Miao, W.; Li, Q.; Wang, D.; Liu, Y.; Mao, S. Chem. Eng. J. 2022, 428, 132531. doi: 10.1016/j.cej.2021.132531 doi: 10.1016/j.cej.2021.132531
18. [18]
  Khamesan, A.; Esfahani, M.; Ghasemi, J.; Farzin, F.; Parsaei-Khomami, A.; Mousavi, M. Adv. Powder Technol. 2022, 33, 103777. doi: 10.1016/j.apt.2022.103777 doi: 10.1016/j.apt.2022.103777
19. [19]
  Jian, L.; Dong, Y.; Zhao, H.; Pan, C.; Wang, G.; Zhu, Y. Appl. Catal. B 2024, 342, 123340. doi: 10.1016/j.apcatb.2023.123340 doi: 10.1016/j.apcatb.2023.123340
20. [20]
  Zan, Z.; Li, X.; Gao, X.; Huang, J.; Luo, Y.; Han, L. Acta Phys. -Chim. Sin. 2023, 39, 2209016. doi: 10.3866/PKU.WHXB202209016 doi: 10.3866/PKU.WHXB202209016
21. [21]
  Deng, J.; Zhu, S.; Zheng, J.; Nie, L. J. Colloid Interface Sci. 2020, 569, 320. doi: 10.1016/j.jcis.2020.02.100 doi: 10.1016/j.jcis.2020.02.100
22. [22]
  Hu, H.; Hu, Y.; Kong, W.; Tao, Y.; Jiang, Q.; Wang, J.; Li, C.; Xie, H.; Shi, Y.; Li, Y.; et al. J. Environ. Chem. Eng. 2023, 11, 111108. doi: 10.1016/j.jece.2023.111108 doi: 10.1016/j.jece.2023.111108
23. [23]
  Zhang, H.; Cheng, L.; Hu, M.; Li, M.; Zheng, J.; Xin, S.; Fang, C.; Chen, H.; Yang, Y.; Nie, L. Chin. J. Inorg. Chem. 2023, 39, 2121. doi: 10.11862/CJIC.2023.175 doi: 10.11862/CJIC.2023.175
24. [24]
  Ding, C.; Lu, X.; Tao, B.; Yang, L.; Xu, X.; Tang, L.; Chi, H.; Yang, Y.; Meira, D.; Wang, L.; et al. Adv. Funct. Mater. 2023, 33, 2302824. doi: 10.1002/adfm.202302824 doi: 10.1002/adfm.202302824
25. [25]
  Li, H.; Li, F.; Yu, J.; Cao, S. Acta Phys. -Chim. Sin. 2021, 37, 2010073. doi: 10.3866/PKU.WHXB202010073 doi: 10.3866/PKU.WHXB202010073
26. [26]
  Balakrishnan, A.; Kunnel, E.; Sasidharan, R.; Chinthala, M.; Kumar, A. Chem. Eng. J. 2023, 475, 146163. doi: 10.1016/j.cej.2023.146163 doi: 10.1016/j.cej.2023.146163
27. [27]
  Gea, T.; Jin, X.; Cao, J.; Chen, Z.; Xu, Y.; Xie, H.; Su, F.; Li, X.; Lan, Q.; Ye, L. J. Taiwan Inst. Chem. Eng. 2021, 129, 104. doi: 10.1016/j.jtice.2021.09.036 doi: 10.1016/j.jtice.2021.09.036
28. [28]
  Liu, W.; Song, C.; Kou, M.; Wang, Y.; Deng, Y.; Shimada, T.; Ye, L. Chem. Eng. J. 2021, 425, 130615. doi: 10.1016/j.cej.2021.130615 doi: 10.1016/j.cej.2021.130615
29. [29]
  Zhang, Z.; Zheng, Y.; Xie, H.; Zhao, J.; Guo, X.; Zhang, W.; Fu, Q.; Wang, S.; Xu, Q.; Huang, Y. J. Alloy. Compd. 2022, 904, 164028. doi: 10.1016/j.jallcom.2022.164028 doi: 10.1016/j.jallcom.2022.164028
30. [30]
  Shi, J.; Luo, Y.; Yang, T.; Wang, H.; Ju, C.; Pu, K.; Shi, J.; Zhao, T.; Xue, J.; Li, Y.; et al. J. Colloid Interface Sci. 2022, 628, 259. doi: 10.1016/j.jcis.2022.07.137 doi: 10.1016/j.jcis.2022.07.137
31. [31]
  Zhang, Y.; Liang, C.; Feng, H.; Liu, W. Chem. Eng. J. 2022, 446, 137379. doi: 10.1016/j.cej.2022.137379 doi: 10.1016/j.cej.2022.137379
32. [32]
  Nie, L.; Chen, H.; Wang, J.; Yang, Y.; Fang, C. Inorg. Chem. 2024, 63, 4770. doi: 10.1021/acs.inorgchem.4c00075 doi: 10.1021/acs.inorgchem.4c00075
33. [33]
  Xia, Y.; Zhu, B.; Qin, X.; Ho, W.; Yu, J. Chem. Eng. J. 2023, 467, 143528. doi: 10.1016/j.cej.2023.143528 doi: 10.1016/j.cej.2023.143528
34. [34]
  Zheng, J.; Xu, Z.; Xin, S.; Zhu, B.; Nie, L. Dalton Trans. 2022, 51, 12883. doi: 10.1039/d2dt01748b doi: 10.1039/d2dt01748b
35. [35]
  Zheng, J.; Xu, Z.; Xin, S.; Nie, L. Mat. Lett. 2022, 325, 132912. doi: 10.1016/j.matlet.2022.132912 doi: 10.1016/j.matlet.2022.132912
36. [36]
  Cong, Y.; Zhang, S.; Zheng, Q.; Li, X.; Zhang, Y.; Lv, S. J. Colloid Interface Sci. 2023, 650, 1013. doi: 10.1016/j.jcis.2023.07.075 doi: 10.1016/j.jcis.2023.07.075
37. [37]
  Liu, B.; Bie, C.; Zhang, Y.; Wang, L.; Li, Y.; Yu, J. Langmuir 2021, 37, 14114. doi: 10.1021/acs.langmuir.1c02360 doi: 10.1021/acs.langmuir.1c02360
38. [38]
  Yuan, J.; Tian, N.; Zhu, Z.; Yu, W.; Li, M.; Zhang, Y.; Huang, H. Chem. Eng. J. 2023, 467, 143379. doi: 10.1016/j.cej.2023.143379 doi: 10.1016/j.cej.2023.143379
39. [39]
  Luo, H.; Shan, T.; Zhou, J.; Huang, L.; Chen, L.; Sa, R.; Yamauchi, Y.; You, J.; Asakura, Y.; Yuan, Z.; et al. Appl. Catal. B 2023, 337, 122933. doi: 10.1016/j.apcatb.2023.122933 doi: 10.1016/j.apcatb.2023.122933
40. [40]
  Chen, J.; Yan, Z.; Chen, Y.; Yao, K.; Xu, Z. Appl. Surf. Sci. 2023, 634, 157637. doi: 10.1016/j.apsusc.2023.157637 doi: 10.1016/j.apsusc.2023.157637
41. [41]
  Wang, W.; Zhang, W.; Cai, Y.; Wang, Q.; Deng, J.; Chen, J.; Jiang, Z.; Zhang, Y.; Yu, C. Nano Res. 2023, 16, 2177. doi: 10.1007/s12274-022-4976-0 doi: 10.1007/s12274-022-4976-0
42. [42]
  Xie, H.; Zheng, Y.; Guo, X.; Liu, Y.; Zhang, Z.; Zhao, J.; Zhang, W.; Wang, Y.; Huang, Y. ACS Sustain. Chem. Eng. 2021, 9, 6788. doi: 10.1021/acssuschemeng.1c01012 doi: 10.1021/acssuschemeng.1c01012
43. [43]
  Li, T.; Zhang, X.; Hu, C.; Li, X.; Zhang, P.; Chen, Z. J. Environ. Chem. Eng. 2022, 10, 107116. doi: 10.1016/j.jece.2021.107116 doi: 10.1016/j.jece.2021.107116
44. [44]
  Wang, T.; Chang, L.; Wu, H.; Yang, W.; Cao, J.; Fan, H.; Wang, J.; Liu, H.; Hou, Y.; Jiang, Y.; et al. J. Colloid Interface Sci. 2022, 612, 434. doi: 10.1016/j.jcis.2021.12.120 doi: 10.1016/j.jcis.2021.12.120
45. [45]
  Wang, K.; Shu, Z.; Zhou, J.; Zhao, Z.; Wen, Y.; Sun, S. J. Colloid Interface Sci. 2023, 648, 242. doi: 10.1016/j.jcis.2023.05.204 doi: 10.1016/j.jcis.2023.05.204
46. [46]
  Zheng, J.; Li, L.; Dai, Z.; Tian, Y.; Fang, T.; Xin, S.; Zhu, B.; Liu, Z.; Nie, L. Appl. Surf. Sci. 2022, 571, 151305. doi: 10.1016/j.apsusc.2021.151305 doi: 10.1016/j.apsusc.2021.151305
47. [47]
  Hu, Q.; Dong, Y.; Ma, K.; Meng, X.; Ding, Y. J. Catal. 2022, 413, 321. doi: 10.1016/j.jcat.2022.06.042 doi: 10.1016/j.jcat.2022.06.042
48. [48]
  Zhou, C.; Song, Y.; Wang, Z.; Liu, J.; Sun, P.; Mo, Z.; Yi, J.; Zhai, L. J. Environ. Chem. Eng. 2023, 11, 110138. doi: 10.1016/j.jece.2023.110138 doi: 10.1016/j.jece.2023.110138
49. [49]
  Tan, L.; Chen, Y.; Li, D.; Wang, S.; Ao, Z. Nanomaterials 2022, 12, 3089. doi: 10.3390/nano12183089 doi: 10.3390/nano12183089
50. [50]
  Chu, Y.; Zheng, X.; Fan, J. Chem. Eng. J. 2022, 431, 134020. doi: 10.1016/j.cej.2021.134020 doi: 10.1016/j.cej.2021.134020
51. [51]
  Tang, R.; Zhou, Y.; Xiong, S.; Deng, Y.; Li, L.; Zhou, Z.; Zeng, H.; Wang, J.; Zhao, J.; Gong, D. J. Colloid Interface Sci. 2023, 630, 127. doi: 10.1016/j.jcis.2022.09.131 doi: 10.1016/j.jcis.2022.09.131
52. [52]
  Zhang, H.; Bai, X. J. Colloid Interface Sci. 2022, 627, 541. doi: 10.1016/j.jcis.2022.07.077 doi: 10.1016/j.jcis.2022.07.077
53. [53]
  Li, D.; Wen, C.; Huang, J.; Zhong, J.; Chen, P.; Liu, H.; Wang, Z.; Liu, Y.; Lv, W.; Liu, G. Appl. Catal. B 2022, 307, 121099. doi: 10.1016/j.apcatb.2022.121099 doi: 10.1016/j.apcatb.2022.121099
54. [54]
  Zhang, P.; Zhang, J.; Wang, D.; Zhang, F.; Zhao, Y.; Yan, M.; Zheng, C.; Wang, Q.; Long, M.; Chen, C. Appl. Catal. B 2022, 318, 121749. doi: 10.1016/j.apcatb.2022.121749 doi: 10.1016/j.apcatb.2022.121749
55. [55]
  Salehian, S.; Heydari, H.; Khansanami, M.; Vatanpour, V.; Mousavi, S. Sep. Purif. Technol. 2022, 285, 120291. doi: 10.1016/j.seppur.2021.120291 doi: 10.1016/j.seppur.2021.120291
56. [56]
  Shan, Y.; Guo, Y.; Wang, Y.; Du, X.; Yu, J.; Luo, H.; Wu, H.; Boury, B.; Xiao, H.; Huang, L.; et al. J. Colloid Interface Sci. 2021, 599, 507. doi: 10.1016/j.jcis.2021.04.111 doi: 10.1016/j.jcis.2021.04.111
57. [57]
  Chen, J.; Gao, W.; Lu, Y.; Ye, F.; Huang, S.; Peng, Y.; Yang, X.; Cai, Y.; Qu, J.; Hu, J. ACS Appl. Nano Mater. 2023, 6, 3927. doi: 10.1021/acsanm.3c00092 doi: 10.1021/acsanm.3c00092
58. [58]
  Deng, L.; Sun, J.; Sun, J.; Wang, X.; Shen, T.; Zhao, R.; Zhang, Y.; Wang, B. Appl. Surf. Sci. 2022, 597, 153586. doi: 10.1016/j.apsusc.2022.153586 doi: 10.1016/j.apsusc.2022.153586
59. [59]
  Chen, A.; Li, C.; Liu, C.; Sun, W. Appl. Surf. Sci. 2023, 628, 157359. doi: 10.1016/j.apsusc.2023.157359 doi: 10.1016/j.apsusc.2023.157359
60. [60]
  Hu, S.; Qu, X.; Li, P.; Wang, F.; Li, Q.; Song, L.; Zhao, Y.; Kang, X. Chem. Eng. J. 2018, 334, 410. doi: 10.1016/j.cej.2017.10.016 doi: 10.1016/j.cej.2017.10.016
61. [61]
  Lu, N.; Liu, N.; Hui, Y.; Shang, K.; Jiang, N.; Li, J.; Wu, Y. Chemosphere 2020, 241, 124927. doi: 10.1016/j.chemosphere.2019.124927 doi: 10.1016/j.chemosphere.2019.124927
62. [62]
  Liu, W.; Xu, R.; Wang, Y.; Huang, N.; Shimada, T.; Ye, L. Int. J. Hydrog. Energy 2022, 47, 16005. doi: 10.1016/j.ijhydene.2022.03.106 doi: 10.1016/j.ijhydene.2022.03.106
63. [63]
  Hu, J.; Chen, C.; Yang, H.; Yang, F.; Qu, J.; Yang, X.; Sun, W.; Dai, L.; Li, C. Appl. Catal. B 2022, 317, 121723. doi: 10.1016/j.apcatb.2022.121723 doi: 10.1016/j.apcatb.2022.121723
64. [64]
  Chen, F.; Wang, H.; Hu, H.; Gan, J.; Su, M.; Xu, H.; Wei, C. Colloids Surf. A 2021, 631, 127710. doi: 10.1016/j.colsurfa.2021.127710 doi: 10.1016/j.colsurfa.2021.127710
65. [65]
  Niu, P.; Zhang, L.; Liu, G.; Cheng, H. Adv. Funct. Mater. 2012, 22, 4763. doi: 10.1016/j.apsusc.2018.06.134 doi: 10.1016/j.apsusc.2018.06.134
66. [66]
  Chen, B.; Xu, J.; Dai, G.; Sun, X.; Situ, Y.; Huang, H. Sep. Purif. Technol. 2022, 299, 121688. doi: 10.1016/j.seppur.2022.121688 doi: 10.1016/j.seppur.2022.121688
67. [67]
  Xue, Y.; Ma, C.; Yang, Q.; Wang, X.; An, S.; Zhang, X.; Tian, J. Chem. Eng. J. 2023, 457, 141146. doi: 10.1016/j.cej.2022.141146 doi: 10.1016/j.cej.2022.141146
68. [68]
  Lu, K.; Wei, Q.; Bao, X.; Xiao, Z.; Cheng, X.; Liu, X.; Wang, Z.; Li, H.; Huang, B. Appl. Surf. Sci. 2023, 609, 155242. doi: 10.1016/j.apsusc.2022.155242 doi: 10.1016/j.apsusc.2022.155242
69. [69]
  Feng, S.; Zhang, Y.; Xu, H.; Gong, X.; Hua, J. J. Alloy. Compd. 2023, 938, 168500. doi: 10.1016/j.jallcom.2022.168500 doi: 10.1016/j.jallcom.2022.168500
70. [70]
  Ni, L.; Xiao, Y.; Zhou, X.; Jiang, Y.; Liu, Y.; Zhang, W.; Zhang, J.; Liu, Z. Inorg. Chem. 2022, 61, 19552. doi: 10.1021/acs.inorgchem.2c03491 doi: 10.1021/acs.inorgchem.2c03491
71. [71]
  Meng, Z.; Zhang, J.; Jiang, C.; Trapalis, C.; Zhang, L.; Yu, J. Small 2023, 20, 2308952. doi: 10.1002/smll.202308952 doi: 10.1002/smll.202308952
72. [72]
  Qiu, J.; Meng, K.; Zhang, Y.; Cheng, B.; Zhang, J.; Wang, L.; Yu, J. Adv. Mater. 2024, 36, 2400288. doi: 10.1002/adma.202400288 doi: 10.1002/adma.202400288
73. [73]
  Cheng, C.; Yu, J.; Xu, D.; Wang, L.; Liang, G.; Zhang, L.; Jaroniec, M. Nat. Commun. 2024, 15, 1313. doi: 10.1038/s41467-024-45604-5 doi: 10.1038/s41467-024-45604-5
74. [74]
  Zhang, X.; Gao, D.; Zhu, B.; Cheng, B.; Yu, J.; Yu, H. Nat. Commun. 2024, 15, 3212. doi: 10.1038/s41467-024-47624-7 doi: 10.1038/s41467-024-47624-7
75. [75]
  Yang, Y.; Zeng, G.; Huang, D.; Zhang, C.; He, D.; Zhou, C.; Wang, W.; Xiong, W.; Li, X.; Li, B.; et al. Appl. Catal. B 2020, 272, 118970. doi: 10.1016/j.apcatb.2020.118970 doi: 10.1016/j.apcatb.2020.118970
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7. [7]
  Zijian Jiang , Yuang Liu , Yijian Zong , Yong Fan , Wanchun Zhu , Yupeng Guo . Preparation of Nano Zinc Oxide by Microemulsion Method and Study on Its Photocatalytic Activity. University Chemistry, 2024, 39(5): 266-273. doi: 10.3866/PKU.DXHX202311101
8. [8]
  Yadan Luo , Hao Zheng , Xin Li , Fengmin Li , Hua Tang , Xilin She . Modulating reactive oxygen species in O, S co-doped C₃N₄ to enhance photocatalytic degradation of microplastics. Acta Physico-Chimica Sinica, 2025, 41(6): 100052-0. doi: 10.1016/j.actphy.2025.100052
9. [9]
  Jiawei Hu , Kai Xia , Ao Yang , Zhihao Zhang , Wen Xiao , Chao Liu , Qinfang Zhang . Interfacial Engineering of Ultrathin 2D/2D NiPS₃/C₃N₅ Heterojunctions for Boosting Photocatalytic H₂ Evolution. Acta Physico-Chimica Sinica, 2024, 40(5): 2305043-0. doi: 10.3866/PKU.WHXB202305043
10. [10]
  Linfeng Xiao , Wanlu Ren , Shishi Shen , Mengshan Chen , Runhua Liao , Yingtang Zhou , Xibao Li . Enhancing Photocatalytic Hydrogen Evolution through Electronic Structure and Wettability Adjustment of ZnIn₂S₄/Bi₂O₃ S-Scheme Heterojunction. Acta Physico-Chimica Sinica, 2024, 40(8): 2308036-0. doi: 10.3866/PKU.WHXB202308036
11. [11]
  Qin Li , Huihui Zhang , Huajun Gu , Yuanyuan Cui , Ruihua Gao , Wei-Lin Dai . In situ Growth of Cd_0.5Zn_0.5S Nanorods on Ti₃C₂ MXene Nanosheet for Efficient Visible-Light-Driven Photocatalytic Hydrogen Evolution. Acta Physico-Chimica Sinica, 2025, 41(4): 2402016-0. doi: 10.3866/PKU.WHXB202402016
12. [12]
  Jingzhuo Tian , Chaohong Guan , Haobin Hu , Enzhou Liu , Dongyuan Yang . Waste plastics promoted photocatalytic H₂ evolution over S-scheme NiCr₂O₄/twinned-Cd_0.5Zn_0.5S homo-heterojunction. Acta Physico-Chimica Sinica, 2025, 41(6): 100068-0. doi: 10.1016/j.actphy.2025.100068
13. [13]
  Chenye An , Sikandaier Abiduweili , Xue Guo , Yukun Zhu , Hua Tang , Dongjiang Yang . Hierarchical S-scheme Heterojunction of Red Phosphorus Nanoparticles Embedded Flower-like CeO₂ Triggering Efficient Photocatalytic Hydrogen Production. Acta Physico-Chimica Sinica, 2024, 40(11): 2405019-0. doi: 10.3866/PKU.WHXB202405019
14. [14]
  Xin Zhou , Zhi Zhang , Yun Yang , Shuijin Yang . A Study on the Enhancement of Photocatalytic Performance in C/Bi/Bi₂MoO₆ Composites by Ferroelectric Polarization: A Recommended Comprehensive Chemical Experiment. University Chemistry, 2024, 39(4): 296-304. doi: 10.3866/PKU.DXHX202310008
15. [15]
  Haitao Wang , Lianglang Yu , Jizhou Jiang , Arramel , Jing Zou . S-Doping of the N-Sites of g-C₃N₄ to Enhance Photocatalytic H₂ Evolution Activity. Acta Physico-Chimica Sinica, 2024, 40(5): 2305047-0. doi: 10.3866/PKU.WHXB202305047
16. [16]
  Yingqi BAI , Hua ZHAO , Huipeng LI , Xinran REN , Jun LI . Perovskite LaCoO₃/g-C₃N₄ heterojunction: Construction and photocatalytic degradation properties. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 480-490. doi: 10.11862/CJIC.20240259
17. [17]
  Kun WANG , Wenrui LIU , Peng JIANG , Yuhang SONG , Lihua CHEN , Zhao DENG . Hierarchical hollow structured BiOBr-Pt catalysts for photocatalytic CO₂ reduction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1270-1278. doi: 10.11862/CJIC.20240037
18. [18]
  Hui Wang , Abdelkader Labidi , Menghan Ren , Feroz Shaik , Chuanyi Wang . Recent Progress of Microstructure-Regulated g-C₃N₄ in Photocatalytic NO Conversion: The Pivotal Roles of Adsorption/Activation Sites. Acta Physico-Chimica Sinica, 2025, 41(5): 100039-0. doi: 10.1016/j.actphy.2024.100039
19. [19]
  Yu Wang , Haiyang Shi , Zihan Chen , Feng Chen , Ping Wang , Xuefei Wang . 具有富电子Pt^δ−壳层的空心AgPt@Pt核壳催化剂：提升光催化H₂O₂生成选择性与活性. Acta Physico-Chimica Sinica, 2025, 41(7): 100081-0. doi: 10.1016/j.actphy.2025.100081
20. [20]
  Zhuo WANG , Junshan ZHANG , Shaoyan YANG , Lingyan ZHOU , Yedi LI , Yuanpei LAN . Preparation and photocatalytic performance of CeO₂-reduced graphene oxide by thermal decomposition. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1708-1718. doi: 10.11862/CJIC.20240067

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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Remarkable Photocatalytic H2O2 Production Efficiency over Ultrathin g-C3N4 Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination

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通讯作者: 陈斌, bchen63@163.com

Remarkable Photocatalytic H₂O₂ Production Efficiency over Ultrathin g-C₃N₄ Nanosheet with Large Surface Area and Enhanced Crystallinity by Two-Step Calcination