Citation: Yikai Wang, Xiaolin Jiang, Haoming Song, Nan Wei, Yifan Wang, Xinjun Xu, Cuihong Li, Hao Lu, Yahui Liu, Zhishan Bo. 氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池[J]. Acta Physico-Chimica Sinica, ;2025, 41(3): 240600. doi: 10.3866/PKU.WHXB202406007 shu

氰基修饰的苝二酰亚胺衍生物作为膜厚不敏感型阴极界面材料用于高效有机太阳能电池

Yikai Wang ¹ ,
Xiaolin Jiang ² ,
Haoming Song ¹ ,
Nan Wei ¹ ,
Yifan Wang ² ,
Xinjun Xu ¹ ,
Cuihong Li ¹ ,
Hao Lu ² ,
Yahui Liu ² ,
Zhishan Bo ¹

1.
Beijing Key Laboratory of Energy Conversion and Storage Materials, College of Chemistry, Beijing Normal University, Beijing 100875, China;
2.
College of Textiles & Clothing, State Key Laboratory of Bio-fibers and Eco-textiles, Qingdao University, Qingdao 266071, Shandong Province, China

Received Date: 6 June 2024
Revised Date: 10 July 2024
Accepted Date: 11 July 2024

Fund Project: The project was supported by the National Natural Science Foundation of China (22375024, 21975031, 51933001, and 21734009).

开发膜厚不敏感型阴极界面材料是当前有机太阳能电池(OSCs)研究的重点和难点之一。在本研究中，我们设计并合成了一种低成本的氰基修饰的苝二酰亚胺衍生物PDINBrCN作为阴极界面层材料，PDINBrCN表现出良好的加工性和调节电极功函数的能力，当用作D18:L8-BO器件中的阴极界面层时，PDINBrCN在10 nm的膜厚度下实现了18.83%的光电转换效率(PCE)，即使当膜厚度增加到50 nm时，器件仍然保持17.90%的PCE。因此，PDINBrCN有望成为一种高效、低成本的阴极界面层材料。
- Cathode interlayer material,
- Organic solar cell,
- Power conversion efficiency,
- Thickness-insensitive property,
- Cyano group
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