Citation: Yu Guo, Zhiwei Huang, Yuqing Hu, Junzhe Li, Jie Xu. 钠离子电池中铁基异质结构负极材料的最新研究进展[J]. Acta Physico-Chimica Sinica, ;2025, 41(3): 231101. doi: 10.3866/PKU.WHXB202311015 shu

钠离子电池中铁基异质结构负极材料的最新研究进展

School of Materials Science and Engineering, Anhui University of Technology, Maanshan 243032, Anhui Province, China

Received Date: 9 November 2023
Revised Date: 11 December 2023
Accepted Date: 12 December 2023

Fund Project: The project was supported by the National Natural Science Foundations of China (52104129, 22309003).

由于资源丰富、价格低廉以及较高比容量，铁(Fe)基材料在钠离子电池负极材料中具有广泛应用前景。然而，Fe基负极材料存在电导率低和在充放电过程中发生的较大体积变化等问题，导致其倍率性能和循环稳定性较差，严重限制了其在钠离子电池领域的大规模应用。构建具有异质结构的Fe基电极材料对提高电导率、增强动力学特性、以及缓解循环过程中由于较大体积变化引起的结构破坏至关重要，从而显著提高Fe基电极材料的综合电化学性能。本文详细综述了具有异质结构的Fe基负极材料在钠离子电池中的研究进展，重点阐述了异质结构Fe基电极材料的合成方法、表征手段和储能机制。同时，对异质结构Fe基氧化物、硫化物、磷化物、硒化物负极材料以及双阴离子Fe基负极材料的储钠特性、改性策略和强化机制等最新研究进展进行归纳。最后，对Fe基异质结构负极材料面临的挑战和发展前景进行总结，以期促进Fe基异质结构钠离子电池负极材料的快速发展和实际应用。
- Sodium ion battery,
- Heterostructure,
- Fe-based anode materials,
- Energy storage mechanism,
- Modification strategy
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