Citation: Jingshuo Zhang, Yue Zhai, Ziyun Zhao, Jiaxing He, Wei Wei, Jing Xiao, Shichao Wu, Quan-Hong Yang. Research Progress of Functional Binders in Silicon-Based Anodes for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, ;2024, 40(6): 230600. doi: 10.3866/PKU.WHXB202306006 shu

Research Progress of Functional Binders in Silicon-Based Anodes for Lithium-Ion Batteries

Jingshuo Zhang ¹ ,
Yue Zhai ¹ ,
Ziyun Zhao ¹ ,
Jiaxing He ¹ ,
Wei Wei ³ ,
Jing Xiao ^{1, 3, 4} ,
Shichao Wu ^{1, 2,,} ,
Quan-Hong Yang ^{1, 2, 3, 4,,}

1.
Nanoyang Group, Tianjin Key Laboratory of Advanced Carbon and Electrochemical Energy Storage, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), and National Industry-Education Integration Platform of Energy Storage, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China
2.
Haihe Laboratory of Sustainable Chemical Transformations, Tianjin 300192, China
3.
Tianmu Lake Institute of Advanced Energy Storage Technologies, Liyang 213300, Jiangsu Province, China
4.
Joint School of National University of Singapore and Tianjin University, International Campus of Tianjin University, Fuzhou 350207, China

Corresponding author: Shichao Wu, Quan-Hong Yang,
Received Date: 2 June 2023
Revised Date: 5 July 2023
Accepted Date: 20 July 2023
Available Online: 9 August 2023
Fund Project: the National Key Research and Development Program of China 2021YFF0500600the National Natural Science Foundation of China U2001220the National Natural Science Foundation of China 52272231

Silicon (Si) has a high theoretical gravimetric capacity (3579 mAh∙g⁻¹ for Li₁₅Si₄), which is almost ten times higher than that of graphite (372 mAh∙g⁻¹) anode. Besides, it has low electrochemical potentials (0.4 V vs. Li⁺/Li), and abundant reserves. Thus, Si becomes a key anode material for the development of high-energy lithium-ion batteries. Nano-Si, typically compounded with graphite, has opened its commercialization. But the specific capacity of commercial Si/graphite composites is generally below 600 mAh∙g⁻¹, which is far below the theoretical specific capacity of Si. In the meanwhile, the high cost, high specific surface area and low tap density of nano-Si limit its volumetric energy density and large-scale production further. Compared to the above materials, micro-Si (1–10 μm) is gaining industry attention for its low cost, as it does not require high-energy ball milling to reduce the particle size. Also, low specific surface area and high tap density conduce to reducing interfacial side reactions and increasing volumetric energy density. Therefore, micro-Si has a particular advantage over application in high volumetric energy density storage devices. However, due to the huge stress caused by significant volume change (300%), there are more severe problems such as particle pulverization, electrode disintegration, conductive network failure and uncontrolled growth of solid electrolyte interphases, which greatly hinder its commercialization. Binders are essential in adapting to Si volume changes to ensure the integrity of the electrode and keeping the tight contact among the active material, conductive additive and current collector to provide a stable conductive network. The development of high-capacity and high-stability micro-Si-based anodes poses greater challenges to the design of binders. In this review, we first clarify the binding mechanism of binders, factors that influence the bonding forces, and design strategies of binders for relieving the volume change of Si electrodes. As a major part, we systematically discuss the strategies and corresponding mechanisms of functional binders for silicon-based anodes from aspects of self-healing binders, conductive binders, ion-conductive binders, and the facilitating effect of functional binders on the stable SEI (Solid Electrolyte Interphase) formation. Finally, the existing problems and challenges are pointed out in terms of long-cycle stability, initial Coulombic efficiency (ICE) and binder ratio under commercial loading. We put forward the promising directions for developing functional binders towards the practical use of micro-Si anode: an ideal binder should be multifunctional and helpful to robust electron/ion conductive networks and stable SEI throughout the long cycling life of micro-Si, where the polymer molecular structure of functional binders can be systematically designed by artificial intelligence and machine learning technologies.
- Lithium-ion battery,
- Silicon-based anode,
- Functional binder,
- Self-healing polymer,
- Conductive polymer
1. [1]
  Yin, H. Y.; Yu, Y.; Li, Z. C, ; Zhang, G. H.; Feng, Y. J. Acta Phys. -Chim. Sin. 2019, 35, 1341. doi: 10.3866/PKU.WHXB201904042
2. [2]
  Kwon, T. W.; Choi, J. W.; Coskun, A. Chem. Soc. Rev. 2018, 47, 2145. doi: 10.1039/c7cs00858a doi: 10.1039/c7cs00858a
3. [3]
  Tan, D. H. S.; Chen, Y. -T.; Yang, H.; Bao, W.; Sreenarayanan, B.; Doux, J. -M.; Li, W.; Lu, B.; Ham, S. -Y.; Sayahpour, B.; et al. Science 2021, 373, 1494. doi: 10.1126/science.abg7217 doi: 10.1126/science.abg7217
4. [4]
  Kovalenko, I.; Zdyrko, B.; Magasinski, A.; Hertzberg, B.; Milicev, Z.; Burtovyy, R.; Luzinov, I.; Yushin, G. Science 2011, 334, 75. doi: 10.1126/science.1209150 doi: 10.1126/science.1209150
5. [5]
  Choi, S.; Kwon, T. -W.; Coskun, A.; Choi, J. W. Science 2017, 357, 279. doi: 10.1126/science.aal4373 doi: 10.1126/science.aal4373
6. [6]
  Xiao, J.; Han, J.; Kong, D.; Shi, H.; Du, X.; Zhao, Z.; Chen, F.; Lan, P.; Wu, S.; Zhang, Y.; et al. Energy Storage Mater. 2022, 50, 554. doi: 10.1016/j.ensm.2022.05.034 doi: 10.1016/j.ensm.2022.05.034
7. [7]
  Ren, Y.; Xiang, L.; Yin, X.; Xiao, R.; Zuo, P.; Gao, Y.; Yin, G.; Du, C. Adv. Funct. Mater. 2022, 32, 2110046. doi: 10.1002/adfm.202110046 doi: 10.1002/adfm.202110046
8. [8]
  Pan, S.; Han, J.; Wang, Y.; Li, Z.; Chen, F.; Guo, Y.; Han, Z.; Xiao, K.; Yu, Z.; Yu, M.; et al. Adv. Mater. 2022, 34, 2203617. doi: 10.1002/adma.202203617 doi: 10.1002/adma.202203617
9. [9]
  Mu, T.; Sun, Y.; Wang, C.; Zhao, Y.; Doyle-Davis, K.; Liang, J.; Sui, X.; Li, R.; Du, C.; Zuo, P.; et al. Nano Energy 2022, 103, 107829. doi: 10.1016/j.nanoen.2022.107829 doi: 10.1016/j.nanoen.2022.107829
10. [10]
  Han, J.; Tang, D. M.; Kong, D.; Chen, F.; Xiao, J.; Zhao, Z.; Pan, S.; Wu, S.; Yang, Q. H. Sci. Bull. 2020, 65, 1563. doi: 10.1016/j.scib.2020.05.018 doi: 10.1016/j.scib.2020.05.018
11. [11]
  Wu, H.; Chan, G.; Choi, J. W.; Ryu, I.; Yao, Y.; McDowell, M. T.; Lee, S. W.; Jackson, A.; Yang, Y.; Hu, L.; et al. Nat. Nanotechnol. 2012, 7, 310. doi: 10.1038/nnano.2012.35 doi: 10.1038/nnano.2012.35
12. [12]
  Yu, Y.; Gu, L.; Zhu, C.; Tsukimoto, S.; van Aken, P. A.; Maier, J. Adv. Mater. 2010, 22, 2247. doi: 10.1002/adma.200903755 doi: 10.1002/adma.200903755
13. [13]
  Hu, Y. S.; Demir-Cakan, R.; Titirici, M. M.; Muller, J. O.; Schlogl, R.; Antonietti, M.; Maier, J. Angew. Chem. Int. Ed. 2008, 47, 1645. doi: 10.1002/anie.200704287 doi: 10.1002/anie.200704287
14. [14]
  Magasinski, A.; Dixon, P.; Hertzberg, B.; Kvit, A.; Ayala, J.; Yushin, G. Nat. Mater. 2010, 9, 353. doi: 10.1038/nmat2725 doi: 10.1038/nmat2725
15. [15]
  Zhao, Z.; Han, J.; Chen, F.; Xiao, J.; Zhao, Y.; Zhang, Y.; Kong, D.; Weng, Z.; Wu, S.; Yang, Q. H. Adv. Energy Mater. 2022, 12, 2103565. doi: 10.1002/aenm.202103565 doi: 10.1002/aenm.202103565
16. [16]
  Chen, F.; Han, J.; Kong, D.; Yuan, Y.; Xiao, J.; Wu, S.; Tang, D. M.; Deng, Y.; Lv, W.; Lu, J.; et al. Natl. Sci. Rev. 2021, 8, 12. doi: 10.1093/nsr/nwab012 doi: 10.1093/nsr/nwab012
17. [17]
  Chen, J.; Fan, X.; Li, Q.; Yang, H.; Khoshi, M. R.; Xu, Y.; Hwang, S.; Chen, L.; Ji, X.; Yang, C.; et al. Nat. Energy 2020, 5, 386. doi: 10.1038/s41560-020-0601-1 doi: 10.1038/s41560-020-0601-1
18. [18]
  Zhu, T.; Sternlicht, H.; Ha, Y.; Fang, C.; Liu, D.; Savitzky, B. H.; Zhao, X.; Lu, Y.; Fu, Y.; Ophus, C.; et al. Nat. Energy 2023, 8, 129. doi: 10.1038/s41560-022-01176-6 doi: 10.1038/s41560-022-01176-6
19. [19]
  McBrayer, J. D.; Rodrigues, M. -T. F.; Schulze, M. C.; Abraham, D. P.; Apblett, C. A.; Bloom, I.; Carroll, G. M.; Colclasure, A. M.; Fang, C.; Harrison, K. L.; et al. Nat. Energy 2021, 6, 866. doi: 10.1038/s41560-021-00883-w doi: 10.1038/s41560-021-00883-w
20. [20]
  Wang, Q.; Zhu, M.; Chen, G.; Dudko, N.; Li, Y.; Liu, H.; Shi, L.; Wu, G.; Zhang, D. Adv. Mater. 2022, 34, 2109658. doi: 10.1002/adma.202109658 doi: 10.1002/adma.202109658
21. [21]
  Lopez, J.; Mackanic, D. G.; Cui, Y.; Bao, Z. Nat. Rev. Mater. 2019, 4, 312. doi: 10.1038/s41578-019-0103-6 doi: 10.1038/s41578-019-0103-6
22. [22]
  Li, P.; Kim, H.; Myung, S. -T.; Sun, Y. -K. Energy Storage Mater. 2021, 35, 550. doi: 10.1016/j.ensm.2020.11.028 doi: 10.1016/j.ensm.2020.11.028
23. [23]
  Zhao, Y. M.; Yue, F. S.; Li, S. C.; Zhang, Y.; Tian, Z. R.; Xu, Q.; Xin, S.; Guo, Y. G. InfoMat 2021, 3, 460. doi: 10.1002/inf2.12185 doi: 10.1002/inf2.12185
24. [24]
  Kwon, T. -W.; Choi, J. W.; Coskun, A. Joule 2019, 3, 662. doi: 10.1016/j.joule.2019.01.006 doi: 10.1016/j.joule.2019.01.006
25. [25]
  An, H.; Jiang, L.; Li, F.; Wu, P.; Zhu, X.; Wei, S.; Zhou, Y. Acta Phys. -Chim. Sin. 2020, 36, 1905034. doi: 10.3866/PKU.WHXB201905034
26. [26]
  Zhao, Z.; Chen, F.; Han, J.; Kong, D.; Pan, S.; Xiao, J.; Wu, S.; Yang, Q. H. Adv. Energy Mater. 2023, 13, 2300367. doi: 10.1002/aenm.202300367 doi: 10.1002/aenm.202300367
27. [27]
  Chen, H.; Ling, M.; Hencz, L.; Ling, H. Y.; Li, G.; Lin, Z.; Liu, G.; Zhang, S. Chem. Rev. 2018, 118, 8936. doi: 10.1021/acs.chemrev.8b00241 doi: 10.1021/acs.chemrev.8b00241
28. [28]
  Liu, G.; Zheng, H.; Song, X.; Battaglia, V. S. J. Electrochem. Soc. 2012, 159, A214. doi: 10.1149/2.024203jes doi: 10.1149/2.024203jes
29. [29]
  Hernandez, C. R.; Etiemble, A.; Douillard, T.; Mazouzi, D.; Karkar, Z.; Maire, E.; Guyomard, D.; Lestriez, B.; Roué, L. Adv. Energy Mater. 2018, 8, 1701787. doi: 10.1002/aenm.201701787 doi: 10.1002/aenm.201701787
30. [30]
  Zhu, S.; Li, H.; Hu, Z.; Zhang, Q.; Zhao, J.; Zhang, L. Acta Phys. -Chim. Sin. 2022, 38, 2103052. doi: 10.3866/PKU.WHXB202103052
31. [31]
  Wu, S.; Yang, Y.; Liu, C.; Liu, T.; Zhang, Y.; Zhang, B.; Luo, D.; Pan, F.; Lin, Z. ACS Energy Lett. 2020, 6, 290. doi: 10.1021/acsenergylett.0c02342 doi: 10.1021/acsenergylett.0c02342
32. [32]
  Lee, H. A.; Shin, M.; Kim, J.; Choi, J. W.; Lee, H. Adv. Mater. 2021, 33, 2007460. doi: 10.1002/adma.202007460 doi: 10.1002/adma.202007460
33. [33]
  Han, D. Y.; Han, I. K.; Son, H. B.; Kim, Y. S.; Ryu, J.; Park, S. Adv. Funct. Mater. 2023, 33, 2213458. doi: 10.1002/adfm.202213458 doi: 10.1002/adfm.202213458
34. [34]
  Xu, Z.; Yang, J.; Zhang, T.; Nuli, Y.; Wang, J.; Hirano, S. -I. Joule 2018, 2, 950. doi: 10.1016/j.joule.2018.02.012 doi: 10.1016/j.joule.2018.02.012
35. [35]
  Li, Z.; Wu, G.; Yang, Y.; Wan, Z.; Zeng, X.; Yan, L.; Wu, S.; Ling, M.; Liang, C.; Hui, K. N.; et al. Adv. Energy Mater. 2022, 12, 2201197. doi: 10.1002/aenm.202201197 doi: 10.1002/aenm.202201197
36. [36]
  Li, B.; Cao, P. F.; Saito, T.; Sokolov, A. P. Chem. Rev. 2023, 123, 701. doi: 10.1021/acs.chemrev.2c00575 doi: 10.1021/acs.chemrev.2c00575
37. [37]
  Wang, C.; Wu, H.; Chen, Z.; McDowell, M. T.; Cui, Y.; Bao, Z. Nat. Chem. 2013, 5, 1042. doi: 10.1038/nchem.1802 doi: 10.1038/nchem.1802
38. [38]
  Li, C. H.; Zuo, J. L. Adv. Mater. 2020, 32, 1903762. doi: 10.1002/adma.201903762 doi: 10.1002/adma.201903762
39. [39]
  Kim, J.; Park, K.; Cho, Y.; Shin, H.; Kim, S.; Char, K.; Choi, J. W. Adv. Sci. 2021, 8, 2004290. doi: 10.1002/advs.202004290 doi: 10.1002/advs.202004290
40. [40]
  Zhang, L.; Zhang, L.; Chai, L.; Xue, P.; Hao, W.; Zheng, H. J. Mater. Chem. A 2014, 2, 19036. doi: 10.1039/c4ta04320k doi: 10.1039/c4ta04320k
41. [41]
  Ying, H.; Zhang, Y.; Cheng, J. Nat. Commun. 2014, 5, 3218. doi: 10.1038/ncomms4218 doi: 10.1038/ncomms4218
42. [42]
  Chen, Z.; Wang, C.; Lopez, J.; Lu, Z.; Cui, Y.; Bao, Z. Adv. Energy Mater. 2015, 5, 1401826. doi: 10.1002/aenm.201401826 doi: 10.1002/aenm.201401826
43. [43]
  Jiao, X.; Yin, J.; Xu, X.; Wang, J.; Liu, Y.; Xiong, S.; Zhang, Q.; Song, J. Adv. Funct. Mater. 2020, 31, 2005699. doi: 10.1002/adfm.202005699 doi: 10.1002/adfm.202005699
44. [44]
  Kim, S. -M.; Kim, M. H.; Choi, S. Y.; Lee, J. G.; Jang, J.; Lee, J. B.; Ryu, J. H.; Hwang, S. S.; Park, J. -H.; Shin, K.; et al. Energy Environ. Sci. 2015, 8, 1538. doi: 10.1039/c5ee00472a doi: 10.1039/c5ee00472a
45. [45]
  Zhao, H.; Wei, Y.; Qiao, R.; Zhu, C.; Zheng, Z.; Ling, M.; Jia, Z.; Bai, Y.; Fu, Y.; Lei, J.; et al. Nano Lett. 2015, 15, 7927. doi: 10.1021/acs.nanolett.5b03003 doi: 10.1021/acs.nanolett.5b03003
46. [46]
  Liu, X.; Xu, Z.; Iqbal, A.; Chen, M.; Ali, N.; Low, C.; Qi, R.; Zai, J.; Qian, X. Nano-Micro Lett. 2021, 13, 54. doi: 10.1007/s40820-020-00564-5 doi: 10.1007/s40820-020-00564-5
47. [47]
  Chiang, C. K.; Fincher, C. R.; Park, Y. W.; Heeger, A. J.; Shirakawa, H.; Louis, E. J.; Gau, S. C.; MacDiarmid, A. G. Phys. Rev. Lett. 1977, 39, 1098. doi: 10.1103/PhysRevLett.39.1098 doi: 10.1103/PhysRevLett.39.1098
48. [48]
  Chen, S.; Song, Z.; Wang, L.; Chen, H.; Zhang, S.; Pan, F.; Yang, L. Accounts Chem. Res. 2022, 55, 2088. doi: 10.1021/acs.accounts.2c00259 doi: 10.1021/acs.accounts.2c00259
49. [49]
  Liu, G.; Xun, S.; Vukmirovic, N.; Song, X.; Olalde-Velasco, P.; Zheng, H.; Battaglia, V. S.; Wang, L.; Yang, W. Adv. Mater. 2011, 23, 4679. doi: 10.1002/adma.201102421 doi: 10.1002/adma.201102421
50. [50]
  Zhao, H.; Wang, Z.; Lu, P.; Jiang, M.; Shi, F.; Song, X.; Zheng, Z.; Zhou, X.; Fu, Y.; Abdelbast, G.; et al. Nano Lett. 2014, 14, 6704. doi: 10.1021/nl503490h doi: 10.1021/nl503490h
51. [51]
  Wu, M.; Xiao, X.; Vukmirovic, N.; Xun, S.; Das, P. K.; Song, X.; Olalde-Velasco, P.; Wang, D.; Weber, A. Z.; Wang, L. W.; et al. J. Am. Chem. Soc. 2013, 135, 12048. doi: 10.1021/ja4054465 doi: 10.1021/ja4054465
52. [52]
  Zhu, T.; Liu, G. J. Electrochem. Soc. 2021, 168, 050533. doi: 10.1149/1945-7111/abff01 doi: 10.1149/1945-7111/abff01
53. [53]
  Liu, D.; Zhao, Y.; Tan, R.; Tian, L. -L.; Liu, Y.; Chen, H.; Pan, F. Nano Energy 2017, 36, 206. doi: 10.1016/j.nanoen.2017.04.043 doi: 10.1016/j.nanoen.2017.04.043
54. [54]
  Higgins, T. M.; Park, S. H.; King, P. J.; Zhang, C. J.; McEvoy, N.; Berner, N. C.; Daly, D.; Shmeliov, A.; Khan, U.; Duesberg, G.; et al. ACS Nano 2016, 10, 3702. doi: 10.1021/acsnano.6b00218 doi: 10.1021/acsnano.6b00218
55. [55]
  Tsai, C. -Y.; Liu, Y. -L. Electrochim. Acta 2021, 379, 138180. doi: 10.1016/j.electacta.2021.138180 doi: 10.1016/j.electacta.2021.138180
56. [56]
  Munaoka, T.; Yan, X.; Lopez, J.; To, J. W. F.; Park, J.; Tok, J. B. H.; Cui, Y.; Bao, Z. Adv. Energy Mater. 2018, 8, 1703138. doi: 10.1002/aenm.201703138 doi: 10.1002/aenm.201703138
57. [57]
  Hu, Y.; Shao, D.; Chen, Y.; Peng, J.; Dai, S.; Huang, M.; Guo, Z. -H.; Luo, X.; Yue, K. ACS Appl. Energy Mater. 2021, 4, 10886. doi: 10.1021/acsaem.1c01849 doi: 10.1021/acsaem.1c01849
58. [58]
  Cai, Y.; Liu, C.; Yu, Z.; Ma, W.; Jin, Q.; Du, R.; Qian, B.; Jin, X.; Wu, H.; Zhang, Q.; et al. Adv. Sci. 2023, 10, 2205590. doi: 10.1002/advs.202205590 doi: 10.1002/advs.202205590
59. [59]
  Liu, H.; Wu, Q.; Guan, X.; Liu, M.; Wang, F.; Li, R.; Xu, J. ACS Appl. Energy Mater. 2022, 5, 4934. doi: 10.1021/acsaem.2c00329 doi: 10.1021/acsaem.2c00329
60. [60]
  Garsuch, R. R.; Le, D. -B.; Garsuch, A.; Li, J.; Wang, S.; Farooq, A.; Dahn, J. R. J. Electrochem. Soc. 2008, 155, A721. doi: 10.1149/1.2956964 doi: 10.1149/1.2956964
61. [61]
  Li, Z.; Zhang, Y.; Liu, T.; Gao, X.; Li, S.; Ling, M.; Liang, C.; Zheng, J.; Lin, Z. Adv. Energy Mater. 2020, 10, 1903110. doi: 10.1002/aenm.201903110 doi: 10.1002/aenm.201903110
62. [62]
  Liu, J.; Zhang, Q.; Zhang, T.; Li, J. -T.; Huang, L.; Sun, S. -G. Adv. Funct. Mater. 2015, 25, 3599. doi: 10.1002/adfm.201500589 doi: 10.1002/adfm.201500589
63. [63]
  Zeng, W.; Wang, L.; Peng, X.; Liu, T.; Jiang, Y.; Qin, F.; Hu, L.; Chu, P. K.; Huo, K.; Zhou, Y. Adv. Energy Mater. 2018, 8, 1702314. doi: 10.1002/aenm.201702314 doi: 10.1002/aenm.201702314
64. [64]
  Oh, D. Y.; Nam, Y. J.; Park, K. H.; Jung, S. H.; Kim, K. T.; Ha, A. R.; Jung, Y. S. Adv. Energy Mater. 2019, 9, 1802927. doi: 10.1002/aenm.201802927 doi: 10.1002/aenm.201802927
65. [65]
  Zhu, J.; Zhang, Z.; Zhao, S.; Westover, A. S.; Belharouak, I.; Cao, P. F. Adv. Energy Mater. 2021, 11, 2003836. doi: 10.1002/aenm.202003836 doi: 10.1002/aenm.202003836
66. [66]
  Nguyen, C. C.; Yoon, T.; Seo, D. M.; Guduru, P.; Lucht, B. L. ACS Appl. Mater. Inter. 2016, 8, 12211. doi: 10.1021/acsami.6b03357 doi: 10.1021/acsami.6b03357
67. [67]
  Parikh, P.; Sina, M.; Banerjee, A.; Wang, X.; D'Souza, M. S.; Doux, J. -M.; Wu, E. A.; Trieu, O. Y.; Gong, Y.; Zhou, Q.; et al. Chem. Mater. 2019, 31, 2535. doi: 10.1021/acs.chemmater.8b05020 doi: 10.1021/acs.chemmater.8b05020
68. [68]
  Browning, K. L.; Browning, J. F.; Doucet, M.; Yamada, N. L.; Liu, G.; Veith, G. M. Phys. Chem. Chem. Phys. 2019, 21, 17356. doi: 10.1039/c9cp02610j doi: 10.1039/c9cp02610j
69. [69]
  Browning, K. L.; Sacci, R. L.; Doucet, M.; Browning, J. F.; Kim, J. R.; Veith, G. M. ACS Appl. Mater. Inter. 2020, 12, 10018. doi: 10.1021/acsami.9b22382 doi: 10.1021/acsami.9b22382
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  Ying Li , Yushen Zhao , Kai Chen , Xu Liu , Tingfeng Yi , Li-Feng Chen . Rational Design of Cross-Linked N-Doped C-Sn Nanofibers as Free-Standing Electrodes towards High-Performance Li-Ion Battery Anodes. Acta Physico-Chimica Sinica, 2024, 40(3): 2305007-0. doi: 10.3866/PKU.WHXB202305007
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10. [10]
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11. [11]
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12. [12]
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15. [15]
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17. [17]
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18. [18]
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沈阳化工大学材料科学与工程学院沈阳 110142