石墨烯作为硫载体在锂硫电池中的研究进展

引用本文: 张梦迪, 陈蓓, 吴明铂. 石墨烯作为硫载体在锂硫电池中的研究进展[J]. 物理化学学报, 2022, 38(2): 210100. doi: 10.3866/PKU.WHXB202101001 shu

Citation: Mengdi Zhang, Bei Chen, Mingbo Wu. Research Progress in Graphene as Sulfur Hosts in Lithium-Sulfur Batteries[J]. Acta Physico-Chimica Sinica, 2022, 38(2): 210100. doi: 10.3866/PKU.WHXB202101001 shu

石墨烯作为硫载体在锂硫电池中的研究进展

重质油国家重点实验室，中国石油大学(华东)新能源学院，化学工程学院，山东青岛 266580

作者简介:

吴明铂，1972年出生。2004年获大连理工大学博士学位，现为中国石油大学(华东)教授、博士生导师，新能源学院常务副院长。主要研究方向为新型及高性能碳素材料的制备及其在储能领域的应用;

通讯作者: 吴明铂, wumb@upc.edu.cn

基金项目:
国家自然科学基金 22005341

山东省自然科学基金 ZR2018ZC1458

山东省自然科学基金 ZR2020QB128

兖矿集团科技项目 YKKJ2019AJ08JG-R63

泰山学者计划 ts201712020

中组部万人计划科技创新领军人才 W03020508

摘要: 锂硫电池因其超高的理论能量密度以及硫资源丰富、成本低廉、无毒的优点，被认为是极具发展潜力与应用前景的新一代储能设备。然而，硫正极导电性差、体积膨胀以及穿梭效应严重等问题严重制约了其商业化应用。石墨烯具有高比表面积、高导电性和高柔韧性，并且易于进行表面化学修饰及组装，是一种理想的硫载体材料。本文主要综述了近年来三维石墨烯、表面化学修饰的石墨烯、石墨烯基复合材料以及石墨烯基柔性材料在锂硫电池正极中的研究现状，并展望了石墨烯作为硫载体在锂硫电池正极中的发展趋势。

关键词:

English

Research Progress in Graphene as Sulfur Hosts in Lithium-Sulfur Batteries

State Key Laboratory of Heavy Oil Processing, College of New Energy, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580, Shandong Province, China

Corresponding author: Mingbo Wu, Email: wumb@upc.edu.cn

Received Date: 04 January 2021
Accepted Date: 27 January 2021
Revised Date: 26 January 2021
Available Online: 15 February 2022
Fund Project:
the National Natural Science Foundation of China

the Shandong Provincial Natural Science Foundation

the Shandong Provincial Natural Science Foundation

the YanKuang Group Co., Ltd. Technology Project

the Taishan Scholar Project

the Technological Leading Scholar of 10000 Talent Project

Abstract: Lithium-sulfur batteries are considered to be one of the most promising new-generation energy storage devices, owing to their ultra-high theoretical energy density and the merits of sulfur cathodes, which include natural abundance, low cost, and no toxicity. However, the commercial application of lithium-sulfur batteries is still subject to various intractable challenges. First, the insulation of sulfur and its solid discharge products (Li₂S₂/Li₂S) leads to low utilization of the active materials. Second, the cathode suffers from an 80% volume expansion after the discharge process, which adversely affects its structural stability. Finally, intermediary lithium polysulfides can easily dissolve into the electrolyte, which can trigger the "shuttle effect." This results in the loss of active materials, fast capacity fading, and low Coulombic efficiency. Graphene has garnered significant interest as a host material to accommodate sulfur for high-performance lithium-sulfur battery. A graphene host featuring a high specific surface area, excellent conductivity, and excellent mechanical stability can ensure a good electrical contact between the sulfur species and the current collector and withstand the volumetric strain of the electrode during cycling. Unfortunately, lithium polysulfides are still prone to escape from cathodes owing to the open two-dimensional (2D) plane structure of graphene sheets. To address this issue, various graphene-based materials with unique structures and chemical compositions have been trialed as sulfur hosts. In this review, we summarize research progress regarding three-dimensional (3D) graphene, graphene with modified surface chemistry, graphene-based composites, and graphene-based flexible materials as sulfur hosts for lithium-sulfur batteries. Furthermore, we analyze the challenges of applying graphene host materials in high-performance lithium-sulfur batteries. This review is mainly divided into four parts: (1) 3D graphene materials as sulfur hosts: the interconnected 3D porous network structure assembled from 2D graphene sheets provides a half-enclosed cavity to accommodate sulfur and its discharge products, which can inhibit the diffusion of lithium polysulfides to a certain extent. (2) Graphene materials with modified surface chemistry as sulfur hosts: hydrophilic surface functional groups and doped non-metal or metal heteroatoms on graphene can chemically adsorb polar lithium polysulfides. (3) Graphene-based composites as sulfur hosts: in various graphene-based composites, graphene usually functions as a conductive and flexible substrate. Other components, such as other types of carbon or metal compounds, can play an important role in restricting lithium polysulfides and propelling their reaction kinetics. (4) Flexible graphene-sulfur electrodes: the excellent flexibility and conductivity of graphene endowed it and its composites with a broad range of prospective applications regarding flexible lithium-sulfur batteries.

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沈阳化工大学材料科学与工程学院沈阳 110142

石墨烯作为硫载体在锂硫电池中的研究进展

作者简介:

吴明铂，1972年出生。2004年获大连理工大学博士学位，现为中国石油大学(华东)教授、博士生导师，新能源学院常务副院长。主要研究方向为新型及高性能碳素材料的制备及其在储能领域的应用;

通讯作者: 吴明铂, wumb@upc.edu.cn

English

Research Progress in Graphene as Sulfur Hosts in Lithium-Sulfur Batteries

Corresponding author: Mingbo Wu, Email: wumb@upc.edu.cn

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中国化学会秘书处

石墨烯作为硫载体在锂硫电池中的研究进展

作者简介: 吴明铂，1972年出生。2004年获大连理工大学博士学位，现为中国石油大学(华东)教授、博士生导师，新能源学院常务副院长。主要研究方向为新型及高性能碳素材料的制备及其在储能领域的应用;

通讯作者: 吴明铂, wumb@upc.edu.cn

English

Research Progress in Graphene as Sulfur Hosts in Lithium-Sulfur Batteries

Corresponding author: Mingbo Wu, Email: wumb@upc.edu.cn

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作者简介:

吴明铂，1972年出生。2004年获大连理工大学博士学位，现为中国石油大学(华东)教授、博士生导师，新能源学院常务副院长。主要研究方向为新型及高性能碳素材料的制备及其在储能领域的应用;

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs