“可控自组装体系及其功能化”重大研究计划取得系列重要研究成果

引用本文: 高飞雪, 陈拥军, 刘冬生, 刘鸣华, 田中群, 张希. “可控自组装体系及其功能化”重大研究计划取得系列重要研究成果[J]. 物理化学学报, 2020, 36(11): 2006060-0. doi: 10.3866/PKU.WHXB202006060 shu

Citation: Gao Feixue, Chen Yongjun, Liu Dongsheng, Liu Minghua, Tian Zhongqun, Zhang Xi. Review of Major Research Plan on "Controlled Self-assembly Systems and Functionalization"[J]. Acta Physico-Chimica Sinica, 2020, 36(11): 2006060-0. doi: 10.3866/PKU.WHXB202006060 shu

“可控自组装体系及其功能化”重大研究计划取得系列重要研究成果

高飞雪 ^{1,
,} ,
陈拥军 ^1, ,
刘冬生 ^2, ,
刘鸣华 ^3, ,
田中群 ^4, ,
张希 ^2,

1.
国家自然科学基金委员会，化学科学部，北京 100085
2.
清华大学化学系，北京 100084
3.
中国科学院化学研究所，北京 100190
4.
厦门大学化学化工学院，福建厦门 100190

通讯作者: 高飞雪, gaofx@nsfc.gov.cn

摘要: 2005年美国科学(Science)杂志在纪念该刊创办125周年之际，把“我们能推动化学自组装走多远？”列为未来最具挑战性的25个科学问题之一，受到世界各国科学家的广泛关注和重视。“十一五”期间，国家自然科学基金委员会组织多领域的科学家充分讨论和酝酿从而提出了“可控自组装体系及其功能化”重大研究计划。计划实施以来，我国科学家开拓和认识了多种新型弱相互作用力，发展了多种具有“中国标签”的新组装基元，建立了类似于有机“人名反应”的组装新方法，实现了多组分、多层次组装体的功能，构建了一批有重要科学意义和潜在实用价值的可控自组装体系，实现了从跟随到原创的跨越式发展，全面推动了我国化学可控自组装研究走向国际舞台的中心。本文介绍了“可控自组装体系及其功能化”重大研究计划的总体科学目标、总体布局和实施思路，以及该重大研究计划资助下取得的系列重要研究成果。

关键词:

English

Review of Major Research Plan on "Controlled Self-assembly Systems and Functionalization"

1.
Department of Chemical Sciences, National Natural Science Foundation of China, Beijing 100085, P. R. China
2.
Department of Chemistry, Tsinghua University, Beijing 100084, P. R. China
3.
Institute of Chemistry Chinese Academy of Sciences, Beijing 100190, P. R. China
4.
College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian Province, P. R. China

Corresponding author: Feixue Gao, Email: gaofx@nsfc.gov.cn; Tel.: +86-10-62327035

Received Date: 24 June 2020
Accepted Date: 24 June 2020
Revised Date: 24 June 2020
Available Online: 15 November 2020

Abstract: In 2005, the Science magazine, in commemorating the 125th anniversary of its founding, proposed 25 most challenging scientific issues in the future. One of the issues, "How far can we push chemical self-assembly?" has attracted the attention of scientists all over the world. During the 11th Five Year Plan period, NSFC convened scientists from various fields and proposed a major research project, "Controllable self-assembly system and its functionalization". Since the implementation of this project, Chinese scientists have developed and recognized a variety of noncovalent interactions, constructed numerous assembly building blocks with the "Chinese label", established a new assembly method similar to an organic "name reaction", realized the functions of multi-component and multi-level assemblies, and constructed a batch of controllable self-assembly systems having scientific importance and potential practical value. They have achieved great leap forward from following to original innovation, and brought the research of chemical self-assembly in China to move forward to the center of international stage. In this study, we examined the overall scientific goals, general layout of the plan, and ideas for implementation of the major research program "Controllable Self-Assembly System and its Functionalization", as well as an array of significant research accomplishments made possible through the funding received by the program.

Key words:

1. [1]
  Lehn, J. Science 2002, 295 (5564), 2400. doi: 10.1126/science.1071063 doi: 10.1126/science.1071063
2. [2]
  Whitesides, G. M.; Grzybowski, B. Science 2002, 295 (5564), 2418. doi: 10.1126/science.1070821 doi: 10.1126/science.1070821
3. [3]
  Robert, F. Science 2005, 309, 95. doi: 10.1126/science.309.5731.95 doi: 10.1126/science.309.5731.95
4. [4]
  Wang, D.; Wang, M. J. Am. Chem. Soc. 2013, 135 (2), 892. doi: 10.1021/ja310834w doi: 10.1021/ja310834w
5. [5]
  Xi, J.; Xu, X. Phys. Chem. Chem. Phys. 2016, 18 (9), 6913. doi: 10.1039/C5CP08065G doi: 10.1039/C5CP08065G
6. [6]
  Zhang, I. Y.; Xu, X.; Jung, Y.; Goddard III, W. A. Proc. Natl. Acad. Sci. 2011, 108 (50), 19896. doi: 10.1073/pnas.1115123108 doi: 10.1073/pnas.1115123108
7. [7]
  Su, N. Q.; Xu, X. Annu. Rev. Phys. Chem. 2017, 68 (1), 155. doi: 10.1146/annurev-physchem052516-044835 doi: 10.1146/annurev-physchem052516-044835
8. [8]
  Su, N. Q.; Zhu, Z.; Xu, X. Proc. Natl. Acad. Sci. 2018, 115 (10), 2287. doi: 10.1073/pnas.1713047115 doi: 10.1073/pnas.1713047115
9. [9]
  Tian, J.; Zhou, T. Y.; Zhang, S. C.; Aloni, S.; Altoe, M. V.; Xie, S. H.; Wang, H.; Zhang, D. W.; Zhao, X.; Liu, Y.; et al. Nat. Commun. 2014, 5 (1), 5574. doi: 10.1038/ncomms6574 doi: 10.1038/ncomms6574
10. [10]
  Tian, J.; Xu, Z. Y.; Zhang, D. W.; Wang, H.; Xie, S. H.; Xu, D. W.; Ren, Y. H.; Wang, H.; Liu, Y.; Li, Z. T. Nat. Commun. 2016, 7 (1), 11580. doi: 10.1038/ncomms11580 doi: 10.1038/ncomms11580
11. [11]
  Qin, B.; Zhang, S.; Song, Q.; Hang, Z. H.; Xu, J. F.; Zhang, X. Angew. Chem. Int. Ed. 2017, 56 (26), 7639. doi: 10.1002/anie.201703572 doi: 10.1002/anie.201703572
12. [12]
  Yang, L. L.; Liu, X. G.; Tan, X. X.; Yang, H.; Wang, Z. Q.; Zhang, X. Polym. Chem. 2014, 5 (2), 323. doi: 10.1039/C3PY01161E doi: 10.1039/C3PY01161E
13. [13]
  Dong, Y. C.; Sun, Y. W.; Wang, L. Y.; Wang, D. W.; Zhou, T.; Yang, Z. Q.; Chen, Z.; Wang, Q. B.; Fan, Q. H.; Liu, D. S. Angew. Chem. Int. Ed. 2014, 53 (10), 2607. doi: 10.1002/anie.201310715 doi: 10.1002/anie.201310715
14. [14]
  Wang, Y.; Lin, H. X.; Chen, L.; Ding, S. Y.; Lei, Z. C.; Liu, D. Y.; Cao, X. Y.; Liang, H. J.; Jiang, Y. B.; Tian, Z. Q. Chem. Soc. Rev. 2014, 43 (1), 399. doi: 10.1039/C3CS60212E doi: 10.1039/C3CS60212E
15. [15]
  Wang, Y.; Lin, H. X.; Ding, S. Y.; Ding, S. Y.; Liu, D.; Chen, D.; Lei, Z.; Fan, F.; Tian, Z. Sci. Sin. Chim. 2012, 42 (4), 525. doi: 10.1360/032011-828 doi: 10.1360/032011-828
16. [16]
  Liu, Y. Q.; Wang, T. Y.; Huan, Y.; Li, Z. B.; He, G. W.; Liu, M. H. Adv. Mater. 2013, 25 (41), 5875. doi: 10.1002/adma.201302345 doi: 10.1002/adma.201302345
17. [17]
  Liu, H. L.; Gong, Q. H.; Yue, Y. H.; Guo, L.; Wang, X. J. Am. Chem. Soc. 2017, 139 (25), 8579. doi: 10.1021/jacs.7b03175 doi: 10.1021/jacs.7b03175
18. [18]
  Li, X. B.; Gao, Y. J.; Wang, Y.; Zhang, F.; Zhang, X. Y.; Kong, Q. Y.; Zhao, N. J.; Guo, Q.; Wu, H. L.; Li, Z. J.; et al. J. Am. Chem. Soc. 2017, 139 (13), 4789. doi: 10.1021/jacs.6b12976 doi: 10.1021/jacs.6b12976
19. [19]
  Zhao, M. T.; Yuan, K.; Wang, Y.; Li, G. D.; Guo, J.; Gu, L.; Hu, W. P.; Zhao, H. J.; Tang, Z. Y. Nature 2016, 539 (7627), 76. doi: 10.1038/nature19763 doi: 10.1038/nature19763
20. [20]
  Liu, X. H.; Kang, F. Y.; Hu, C.; Wang, L.; Xu, Z.; Zheng, D. D.; Gong, W. M.; Lu, Y.; Ma, Y. H.; Wang, J. Y. Nat. Chem. 2018, 10 (12), 1201. doi: 10.1038/s41557-018-0150-4 doi: 10.1038/s41557-018-0150-4
21. [21]
  Li, S. P.; Jiang, Q.; Liu, S. L.; Zhang, Y. L.; Tian, Y. H.; Song, C., Wang, J.; Zou, Y. G.; Anderson, G. J.; Han, J. Y.; et al. Nat. Biotechnol. 2018, 36 (3), 258. doi: 10.1038/nbt.4071 doi: 10.1038/nbt.4071
22. [22]
  Huang, P.; Wang, D. L.; Su, Y.; Huang, W.; Zhou, Y. F.; Cui, D. X.; Zhu, X. Y.; Yan, D. Y. J. Am. Chem. Soc.2014, 136 (33), 11748. doi: 10.1021/ja505212y doi: 10.1021/ja505212y
23. [23]
  Zhou, L. Y.; Lv, F. T.; Liu, L. B.; Shen, G. Z.; Yan, X. H.; Bazan, G. C.; Wang, S. Adv. Mater. 2018, 30 (10), 1704888. doi: 10.1002/adma.201704888 doi: 10.1002/adma.201704888
24. [24]
  Chen, Y. Y.; Huang, Z. H.; Xu, J. F.; Sun, Z. W.; Zhang, X. ACS Appl. Mater. Interfaces 2016, 8 (35), 22780. doi: 10.1021/acsami.6b08295 doi: 10.1021/acsami.6b08295

扫一扫看文章

计量

PDF下载量: 0
文章访问数: 78
HTML全文浏览量: 4

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

“可控自组装体系及其功能化”重大研究计划取得系列重要研究成果

通讯作者: 高飞雪, gaofx@nsfc.gov.cn

English

Review of Major Research Plan on "Controlled Self-assembly Systems and Functionalization"

Corresponding author: Feixue Gao, Email: gaofx@nsfc.gov.cn; Tel.: +86-10-62327035

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处