NaTiSi<sub>2</sub>O<sub>6</sub>/C Composite as a Novel Anode Material for Lithium-Ion Batteries

Citation: Liu Kun, Liu Yao, Zhu Haifeng, Dong Xiaoli, Wang Yonggang, Wang Congxiao, Xia Yongyao. NaTiSi₂O₆/C Composite as a Novel Anode Material for Lithium-Ion Batteries[J]. Acta Physico-Chimica Sinica, 2020, 36(11): 1912030-0. doi: 10.3866/PKU.WHXB201912030 shu

NaTiSi₂O₆/C复合材料用于锂离子电池负极材料

.
复旦大学化学系，新能源研究院，上海市分子催化和功能材料重点实验室，上海 200433

通讯作者: 王丛笑, cxwang@fudan.edu.cn
夏永姚, yyxia@fudan.edu.cn

基金项目:
国家自然科学基金会 21875045

国家自然科学基金会(21875045)和国家重点研发项目(2016YFB0901500)资助

国家重点研发项目 2016YFB0901500

摘要: 在本文中，我们首次报道了一种新型的硅酸盐负极材料NaTiSi₂O₆，由溶胶-凝胶法和固相烧结法合成而得。这种材料属于单斜晶系，空间群为C2/c。通过葡萄糖的高温裂解和碳化，NaTiSi₂O₆/C复合物被成功制备出来，其表面积为132 m²·g^-1。在0.1 A·g^-1的电流密度下其首圈放电和充电的比容量分别为542.9 mAh·g^-1和266.6 mAh·g^-1，首圈库伦效率为49.1%。在经过100圈循环后，其充电比容量为224.1 mAh·g^-1，容量保持率为84.1%。原位X射线衍射测试表明，其充放电机理为嵌入反应。这使得NaTiSi₂O₆成为硅酸盐负极材料家族中新的一员。

关键词:

English

NaTiSi₂O₆/C Composite as a Novel Anode Material for Lithium-Ion Batteries

Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Institute of New Energy, Fudan University, Shanghai 200433, P. R. China

Corresponding author: Wang Congxiao, cxwang@fudan.edu.cn Xia Yongyao, yyxia@fudan.edu.cn

Received Date: 10 December 2019
Accepted Date: 07 January 2020
Revised Date: 07 January 2020
Available Online: 15 November 2020
Fund Project:
the National Natural Science Foundation of China 21875045

The project was supported by the National Natural Science Foundation of China (21875045) and the National Key Research and Development Program of China (2016YFB0901500)

the National Key Research and Development Program of China 2016YFB0901500

Abstract: The development of human society and the continuously emerging environmental problems call for cleaner energy resources. Lithium-ion batteries, since their commercialization in the early 1990s, have been an important power source of mobile phones, laptops as well as other portable electronic devices. Their advantages include environment-friendliness, light weight, and no memory effect compared with lead-acid or nickel-cadmium batteries. Electrode materials play an important role in the performance of lithium-ion batteries. The traditional commercial anode material, graphite, has a theoretical specific capacity of 372 mAh·g^-1 and working potential close to 0 V (vs Li⁺/Li), making it prone to the formation of lithium dendrite, which may cause short circuit especially when large current is applied. Another commercial anode material Li₄Ti₅O₁₂, which also undergoes an intercalation reaction during lithiation process, has a theoretical specific capacity of 175 mAh·g^-1 along with three lithium-ion intercalations per formula unit. This is relatively small, and it has a relatively high working potential of 1.55 V (vs Li⁺/Li), which reduces its output voltage and specific energy when assembled in full battery. To overcome the shortcomings mentioned above, it is essential to search for new anode materials that are low-cost, environment-friendly, and easy to synthesize. Silicate materials have gained widespread attention owing to their low cost and facile synthesis. Herein, we report for the first time a novel titanosilicate, NaTiSi₂O₆, synthesized by sol-gel and solid sintering. It is isostructural to pyroxene jadeite NaAlSi₂O₆, belonging to monoclinic crystal system with a space group of C2/c. By in situ pyrolysis and carbonization of glucose, nanosized NaTiSi₂O₆ mixed with carbon was successfully obtained with a specific surface area of 132 m²·g^-1, calculated according to the Brunauer–Emmett–Teller formula. The specific charge/discharge capacity in the first cycle at current density of 0.1 A·g^-1 is 266.6 mAh·g^-1 and 542.9 mAh·g^-1, respectively, with an initial coulombic efficiency of 49.1%. After 100 cycles, it retains a specific charge capacity of 224.1 mAh·g^-1, corresponding to a capacity retention rate of 84.1%. The average working potential of NaTiSi₂O₆ is 1.2–1.3 V (vs Li⁺/Li), slightly lower than that of Li₄Ti₅O₁₂. The reaction mechanism while charging and discharging was determined by in situ X-ray diffraction test as well as selected area electron diffraction. The results showed that NaTiSi₂O₆ undergoes an intercalation reaction during lithiation process, with two lithium-ion intercalations per formula unit. This makes NaTiSi₂O₆ a new member of the silicate anode material family, and may provide insights into the development of new silicate electrode materials in the future.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

NaTiSi₂O₆/C复合材料用于锂离子电池负极材料

通讯作者: 王丛笑, cxwang@fudan.edu.cn
夏永姚, yyxia@fudan.edu.cn

English

NaTiSi₂O₆/C Composite as a Novel Anode Material for Lithium-Ion Batteries

Corresponding author: Wang Congxiao, cxwang@fudan.edu.cn Xia Yongyao, yyxia@fudan.edu.cn

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CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

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NaTiSi2O6/C复合材料用于锂离子电池负极材料

通讯作者: 王丛笑, cxwang@fudan.edu.cn 夏永姚, yyxia@fudan.edu.cn

English

NaTiSi2O6/C Composite as a Novel Anode Material for Lithium-Ion Batteries

Corresponding author: Wang Congxiao, cxwang@fudan.edu.cn Xia Yongyao, yyxia@fudan.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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NaTiSi₂O₆/C复合材料用于锂离子电池负极材料

通讯作者: 王丛笑, cxwang@fudan.edu.cn
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