ZnCuAl-LDH/Bi<sub>2</sub>MoO<sub>6</sub> Nanocomposites with Improved Visible Light-Driven Photocatalytic Degradation

Citation: Guiyun Yu, Fengxian Hu, Weiwei Cheng, Zitong Han, Chao Liu, Yong Dai. ZnCuAl-LDH/Bi₂MoO₆ Nanocomposites with Improved Visible Light-Driven Photocatalytic Degradation[J]. Acta Physico-Chimica Sinica, 2020, 36(7): 191101. doi: 10.3866/PKU.WHXB201911016 shu

ZnCuAl-LDH/Bi₂MoO₆纳米复合材料的构建及其可见光催化降解性能

郁桂云 ^1, ,
胡丰献 ^1, ,
程伟伟 ^1, ,
韩字童 ^2, ,
刘超 ^{2,
,} ,
戴勇 ^{1,
,}

1.
盐城工学院化学化工学院，江苏盐城 224051
2.
盐城工学院材料科学与工程学院，江苏盐城 224051

通讯作者: 刘超, cliu@ycit.edu.cn
戴勇, 123daiyong123@163.com

基金项目:
中国博士后科学基金 2018M632283

国家自然科学基金 51902282

国家自然科学基金(21603182, 51902282), 江苏省高等学校自然科学基金(16KJB150038)和中国博士后科学基金(2018M632283)资助项目

江苏省高等学校自然科学基金 16KJB150038

国家自然科学基金 21603182

摘要: 本工作采用稳态共沉淀法制备了ZnCuAl-LDH/Bi₂MoO₆ (LDH/Bi₂MoO₆)纳米复合材料，并研究了所得材料在可见光下降解污染物罗丹明B (RhB)的光催化性能。结果表明，所得LDH/Bi₂MoO₆纳米复合材料比单纯的ZnCuAl-LDH和Bi₂MoO₆具有显著提高的光催化活性和较好的稳定性。光催化性能的提高得益于异质结的形成以及高的比表面积，从而有利于光生电子-空穴对的有效分离和更多光催化活性位点的暴露。研究发现，在光降解过程中，所产生的•OH和O₂^•−是主要的反应性物种，而e⁻和h⁺的贡献较少。基于实验结果，提出了一种可能的光催化机制。本工作提供了一种制备基于LDH和(或)Bi₂MoO₆纳米复合材料的方法，所得LDH/Bi₂MoO₆纳米复合材料可望作为一种可见光光催化剂，在净化环境和缓解资源短缺方面有潜在应用。

关键词:

English

ZnCuAl-LDH/Bi₂MoO₆ Nanocomposites with Improved Visible Light-Driven Photocatalytic Degradation

Guiyun Yu ^1, ,
Fengxian Hu ^1, ,
Weiwei Cheng ^1, ,
Zitong Han ^2, ,
Chao Liu ^{2,
,} ,
Yong Dai ^{1,
,}

1.
School of Chemistry & Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051, Jiangsu Province, P. R. China
2.
School of Materials Science and Engineering, Yancheng Institute of Technology, Yancheng 224051, Jiangsu Province, P. R. China

Corresponding author: Chao Liu, cliu@ycit.edu.cn Yong Dai, 123daiyong123@163.com

Received Date: 07 November 2019
Revised Date: 20 December 2016
Available Online: 15 July 2020
Fund Project:

The project was supported by the National Natural Science Foundation of China (21603182, 51902282), the Natural Science Foundation of the Jiangsu Higher Education Institutions, China (16KJB150038), and the China Postdoctoral Science Foundation (2018M632283)

Abstract: In this study, pure Bi₂MoO₆ was synthesized via a solvothermal method. A ZnCuAl-layered double hydroxide (LDH)/Bi₂MoO₆ (denoted as LDH/Bi₂MoO₆) nanocomposite was synthesized via a steady-state co-precipitation route using Bi₂MoO₆ as the matric material. LDH was deposited on the surface of Bi₂MoO₆ with a close contact interface. The specific surface area of the resulting LDH/Bi₂MoO₆ composite increased up to 19.1 m²∙g⁻¹ owing to the stacking arrangement between LDH and the Bi₂MoO₆ nanosheets, resulting in the generation of a large number of reactive sites. In addition, the light absorption region of the LDH/Bi₂MoO₆ composite was larger than those of pure LDH and Bi₂MoO₆ because of the formation of a heterojunction structure and the possible quantum size effect. The photocatalytic performance of the as-prepared samples was evaluated by carrying out the degradation of rhodamine B (RhB) using them under visible light irradiation. Compared to pure LDH and Bi₂MoO₆, the LDH/Bi₂MoO₆ nanocomposite exhibited enhanced photocatalytic activity for the degradation of RhB. With an increase in the LDH content, the photocatalytic activity of the LDH/Bi₂MoO₆ composite first increased and then decreased. Although the addition of an optimum amount of LDH was beneficial for the generation of electron-hole pairs, excessive LDH on the surface of Bi₂MoO₆ decreased the visible light absorption ability of both the components, thus reducing photocatalytic activity of the composite. This indicates that an appropriate LDH:Bi₂MoO₆ molar ratio is necessary for obtaining LDH/Bi₂MoO₆ composites with excellent photocatalytic activity. Furthermore, the LDH/Bi₂MoO₆ composite showed high photocatalytic stability and reusability. The structure of the LDH/Bi₂MoO₆ composite remained almost unchanged even after four photodegradation cycles. The enhanced photocatalytic performance of the composite can be attributed to the combined effect of its heterojunction structure and high specific surface area, which are beneficial for effective separation of photogenerated charge carriers and the availability of a large number of active sites for photocatalysis. It was found that •OH and O₂^•− were the main reactive species, while e⁻ and h⁺ contributed little to the photodegradation process. The generation, transfer, and separation of photoinduced electrons and holes in the composites were investigated by transient photocurrent responses, electrochemical impedance spectroscopy Nyquist plots, and photoluminescence measurements. The results showed that the heterojunction structure of the composites played a key role in enhancing their photocatalytic activity. A possible photodegradation mechanism was proposed for the composite. This study will provide a facile approach for the preparation of LDH- and/or Bi₂MoO₆-based nanocomposites. The LDH/Bi₂MoO₆ nanocomposite prepared in this study showed huge potential to be used as a visible-light photocatalyst for degrading environmental pollutants.

Key words:

1. [1]
  葛明, 谭勉勉, 崔广华.物理化学学报, 2014, 30, 2107. doi: 10.3866/PKU.WHXB201409041Ge, M.; Tan, M. M.; Cui, G. H. Acta Phys. -Chim. Sin. 2014, 30, 2107. doi: 10.3866/PKU.WHXB201409041
2. [2]
  Liu, C.; Zhu, H.; Zhu, Y.; Dong, P.; Hou, H.; Xu, Q.; Chen, X.; Xi, X.; Hou, W. Appl. Catal. B: Environ. 2018, 228, 54. doi: 10.1016/j.apcatb.2018.01.074
3. [3]
  Ren, J.; Ouyang, S.; Chen, H.; Umezawa, N.; Lu, D.; Wang, D.; Xu, H.; Ye, J. Appl. Catal. B: Environ. 2015, 168, 243. doi: 10.1016/j.apcatb.2014.12.021
4. [4]
  Liu, C.; Gao, X.; Han, Z.; Sun, Y.; Feng, Y.; Yu, G.; Xi, X.; Zhang, Q.; Zou, Z. Nanomaters 2019, 9, 1503. doi: 10.3390/nano9101503
5. [5]
  Zhang, M.; Shao, C.; Zhang, P.; Su, C.; Zhang, X.; Liang, P.; Sun, Y.; Liu, Y. J. Hazard. Mater. 2012, 225, 155. doi: 10.1016/j.jhazmat.2012.05.006
6. [6]
  Reilly, L. M.; Sankar, G. S.; Catlow, C. R. A. J. Solid State Chem. 1999, 148, 178. doi: 10.1006/jssc.1999.8486
7. [7]
  Pirovano, C.; Saiful, I. M.; Vannier, R.; Nowogrocki, G.; Mairesse, G. Solid State Ion. 2001, 140, 115. doi: 10.1016/S0167-2738(01)00699-3
8. [8]
  Jin, S.; Hao, S.; Gan, Y.; Guo, W.; Li, H.; Hu, X.; Hou, H.; Zhang, G.; Yan, S.; Gao, W.; Liu, G. Mater. Chem. Phys. 2017, 199, 107. doi: 10.1016/j.matchemphys.2017.06.053
9. [9]
  Du, X.; Wan, J.; Jia, J.; Pan, C.; Hu, X.; Fan, J.; Liu, E. Mater. Design. 2017, 119, 113. doi: 10.1016/j.matdes.2017.01.070
10. [10]
  Seftel, E. M.; Puscasu, M. C.; Mertens, M.; Cool, P.; Garja, G. Appl. Catal. B: Environ. 2014, 150, 157. doi: 10.1016/j.apcatb.2013.12.019
11. [11]
  Yan, T.; Sun, M.; Liu, H.; Wu, T.; Liu, X.; Yan, Q.; Xu, W.; Du, B. J. Alloy. Compd. 2015, 634, 223. doi: 10.1016/j.jallcom.2015.02.064
12. [12]
  Xu, Y.; Zhang, W. Appl. Catal. B: Environ. 2013, 140, 306. doi: 10.1016/j.apcatb.2013.04.019
13. [13]
  Chen, Y.; Tian, G.; Shi, Y.; Xiao, Y. Appl. Catal. B: Environ. 2015, 164, 40. doi: 10.1016/j.apcatb.2014.08.036
14. [14]
  Debasmita, K.; Satybadi, M.; Arun, T.; Parida, K.M. ACS Omega 2017, 2, 9040. doi: 10.1021/acsomega.7b01250
15. [15]
  Prince, J.; Montoya, A.; Ferrat, G.; Valente, J. S. Chem. Mater. 2009, 21, 5826. doi: 10.1021/cm902741c doi: 10.1021/cm902741c
16. [16]
  Ma, R.; Liu, Z.; Takada, K.; Iya, N.; Bando, Y.; Sasaki, T. J. Am. Chem. Soc. 2007, 129, 5257. doi: 10.1021/ja0693035
17. [17]
  Wang, J.; Wei, Y.; Yu, J. Appl. Clay Sci. 2013, 72, 37. doi: 10.1016/j.clay.2013.01.006
18. [18]
  张晓晴, 徐艳, 杨春辉, 张燕平, 印永祥, 尚书勇.物理化学学报, 2015, 31, 948. doi: 10.3886/PKU.WHXB201503111Zhang, X. Q.; Xu, Y.; Yang, C. H.; Zhang, Y. P.; Ying, Y. X.; Shang, S. Y. Acta Phys. -Chim. Sin. 2015, 31, 948. doi: 10.3886/PKU.WHXB201503111
19. [19]
  Huang, G.; Sun, Y.; Zhao, C.; Zhao, Y.; Song, Z.; Chen, J.; Ma, S.; Du, J.; Yin, Z. J. Colloid Interface Sci. 2017, 494, 215. doi: 10.1016/ j.jcis.2017.01.079
20. [20]
  Zubair, M.; Daud, M.; McKay, G.; Shehzad, F.; Al-Harthi, M. A. Appl. Clay Sci. 2017, 143, 279. doi: 10.1016/j.jcis.2017.01.079
21. [21]
  Oh, J. M.; Choi, S. J.; Lee, G. E.; Han, S. H.; Choy, J. H. Adv. Funct. Mater. 2009, 19, 1617. doi: 10.1002/adfm.200801127
22. [22]
  Shao, M.; Ning, F.; Zhao, J.; Wei, M.; Evans, D. G.; Duan, X. J. Am. Chem. Soc. 2012, 134, 1071. doi: 10.1021/ja2086323
23. [23]
  He, J.; Yang, Z.; Zhang, L.; Li, Y.; Pan, L. Int. J. Hydrog. Energy 2017, 42, 9930. doi: 10.1016/j.ijhydene.2017.01.229
24. [24]
  Bernardo, M. P.; Moreira, F. K. V.; Ribeiro, C. Appl. Clay Sci. 2017, 137, 143. doi: 10.1016/j.clay.2016.12.022
25. [25]
  Mohapatra, L.; Parida, K. M. Sep. Purif. Technol. 2012, 91, 73. doi: 10.1016/j.seppur.2011.10.028
26. [26]
  Parida, K. M.; Mohapatra, L. Chem. Eng. J. 2012, 179, 131. doi: 10.1016/j.cej.2011.10.070
27. [27]
  Nayak, S.; Mohapatra, L.; Parida, K. J. Mater. Chem. A 2015, 3, 18622. doi: 10.1039/C5TA05002B
28. [28]
  Ma, J.; Ding, J.; Yu, L.; Li, L.; Kong, Y. Appl. Clay Sci. 2015, 109, 76. doi: 10.1016/j.clay.2015.02.009
29. [29]
  Mohapatra, L.; Parida, K. M. Phys. Chem. Chem. Phys. 2014, 16, 16985. doi: 10.1039/C4CP01665C
30. [30]
  Dai, W. L.; Hu, X.; Wang, T.; Xiong, W.; Luo, X.; Zou, J. Appl. Surf. Sci. 2018, 434, 481. doi: 10.1016/j.apsusc.2017.10.207
31. [31]
  Liu, Y.; Zhu, G.; Gao, J.; Hojamberdiev, M.; Zhu, R.; Wei, X.; Guo, Q.; Liu, Q. Appl. Catal. B: Environ. 2017, 200, 72. doi: 10.1016/j.apcatb.2016.06.069
32. [32]
  Zhu, Y.; Laipan, M.; Zhu, R.; Xu, T.; Liu, J.; Zhu, J.; Xi, Y.; Zhu, G.; He, H. J. Mol. Catal. A: Chem. 2017, 427, 54. doi: 10.1016/j.molcata.2016.11.031
33. [33]
  Zhang, Y.; Liu, J.; Li, Y.; Yu, M.; Yin, X.; Li, S. J. Wuhan Univ. Technol. 2017, 32, 1199. doi: 10.1007/s11595-017-1731-6
34. [34]
  Nayak, S.; Parida, K. M. Int. J. Hydrog. Energy 2016, 41, 21166. doi: 10.1016/j.ijhydene.2016.08.062
35. [35]
  Iftekhar, S.; Srivastava, V.; Ramasamy, D. L.; Naseer, W. A.; Sillanpää, M. Chem. Eng. J. 2018, 347, 398. doi: 10.1016/j.cej.2018.04.126
36. [36]
  Li, H.; Liu, C.; Li, K.; Wang, H. J. Mater. Sci. 2008, 43, 7026. doi: 10.1007/s10853-008-3034-y
37. [37]
  Phuruangrat, A.; Ekthammathat, N.; Kuntalue, B.; Dumrongrojthanath, P.; Thongtem, S.; Thongtem, T. J. Nanomater. 2014, 934165. doi: 10.1155/2014/934165
38. [38]
  Tian, Y.; Cheng, F.; Zhang, X.; Yan, F.; Zhou, B.; Chen, Z.; Liu, J.; Xi, F.; Dong, X. Powder Technol. 2014, 267, 126. doi: 10.1016/j.powtec.2014.07.021
39. [39]
  Ezeh, C. I.; Tomatis, M.; Yang, X.; He, J.; Sun, C. Ultrason. Sonochem. 2018, 40, 341. doi: 10.1016/j.ultsonch.2017.07.013
40. [40]
  Martínez-de la Cruz, A.; Alfaro, S. O. J. Mol. Catal. A: Chem. 2010, 320, 85. doi: 10.1016/j.molcata.2010.01.008
41. [41]
  Li, Y.; Ouyang, S.; Xu, H.; Hou, W.; Zhao, M.; Chen, H.; Ye, J. Adv. Funct. Mater. 2019, 29, 1901024. doi: 10.1002/adfm.201901024.
42. [42]
  Guzmán-Vargas, A.; Lima, E.; Uriostegui-Ortega, G. A.; Oliver-Tolentino, M. A.; Rodríguez, E. E. Appl. Surf. Sci. 2016, 363, 372. doi: 10.1016/j.apsusc.2015.12.050
43. [43]
  Jiang, H.; Katsumata, K. I.; Hong, J.; Yamaguchi, A.; Nakata, K.; Terashima, C.; Matsushita, N.; Miyauchi, M.; Fujishima, A. Appl. Catal. B: Environ. 2018, 224, 783. doi: 10.1016/j.apcatb.2017.11.011
44. [44]
  Jin, L.; Zhu, G.; Hojamberdiev, M.; Luo, X.; Tan, C.; Peng, J.; Wei, X.; Li, J.; Liu, P. Ind. Eng. Chem. Res. 2014, 53, 13718. doi: 10.1021/ie502133x
45. [45]
  Lu, H.; Xu, L.; Wei, B.; Zhang, M.; Gao, H.; Sun, W. Appl. Surf. Sci. 2014, 303, 360. doi: 10.1016/j.apsusc.2014.03.006
46. [46]
  Hu, R.; Xiao, X.; Tu, S.; Zuo, X.; Nan, J. Appl. Catal. B: Environ. 2015, 163, 510. doi: 10.1016/j.apcatb.2014.08.025
47. [47]
  Chen, Z.; Lin, B.; Chen, Y.; Zhang, K.; Li, B.; Zhu, H. J. Phys. Chem. Solids 2010, 71, 841. doi: 10.1016/j.jpcs.2010.02.011
48. [48]
  Vázquez-Cuchillo, O.; Gómez, R.; Cruz-López, A.; Torres-Martínez, L. M.; Zanella, R.; Sandoval, F. J. A.; Ángel-Sánchez, K. D. J. Photochem. Photobiol. A 2013, 266, 6. doi: 10.1016/j.jphotochem.2013.05.007
49. [49]
  Zhang, L.; Li, F.; Evans, D. G.; Duan, X. Ind. Eng. Chem. Res. 2010, 49, 5959. doi: 10.1021/ie9019193
50. [50]
  Bi, J.; Wu, L.; Li, J.; Li, Z.; Wang, X.; Fu, X. Acta Mater. 2007, 55, 4699. doi: 10.1016/j.actamat.2007.04.034
51. [51]
  Liu, C.; Wu, Q.; Ji, M.; Zhu, H.; Hou, H.; Yang, Q.; Jiang, C.; Wang, J.; Tian, L.; Chen, J.; Hou, H. J. Alloy. Compd. 2017, 723, 1121. doi: 10.1016/j.jallcom.2017.07.003
52. [52]
  Vadivel, S.; Kamalakannan, V.P.; Balasubramanian, N. Ceram. Int. 2014, 40, 14051. doi: 10.1016/j.ceramint.2014.05.133
53. [53]
  Liu, C.; Xu, Q.; Zhang, Q.; Zhu, Y.; Ji, M.; Tong, Z.; Hou, W.; Zhang, Y.; Xu, J. J. Mater. Sci. 2019, 54, 2458. doi: 10.1007/s10853-018-2990-0
54. [54]
  Liu, C.; Sun, T.; Wu, L.; Liang, J.; Huang, Q.; Chen, T.; Hou, W. Appl. Catal. B: Environ. 2015, 170, 17. doi: 10.1016/j.apcatb.2015.01.026
55. [55]
  Wang, W.; Fang, J.; Shao, S.; Lai, M.; Lu, C. Appl. Catal. B: Environ. 2017, 217, 57. doi: 10.1016/j.apcatb.2017.05.037
56. [56]
  Huang, Y.; Fan, W.; Long, B.; Li, H.; Zhao, F.; Liu, Z.; Tong, Y.; Ji, H. Appl. Catal. B: Environ. 2016, 185, 68. doi: 10.1016/j.apcatb.2015.11.043
57. [57]
  Guo, C.; Xu, J.; Wang, S.; Li, L.; Zhang, Y.; Li, X. CrystEngComm 2012, 14, 3602. doi: 10.1039/c2ce06757a

扫一扫看文章

计量

PDF下载量: 33
文章访问数: 1405
HTML全文浏览量: 306

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

ZnCuAl-LDH/Bi₂MoO₆纳米复合材料的构建及其可见光催化降解性能

通讯作者: 刘超, cliu@ycit.edu.cn
戴勇, 123daiyong123@163.com

English

ZnCuAl-LDH/Bi₂MoO₆ Nanocomposites with Improved Visible Light-Driven Photocatalytic Degradation

Corresponding author: Chao Liu, cliu@ycit.edu.cn Yong Dai, 123daiyong123@163.com

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

ZnCuAl-LDH/Bi2MoO6纳米复合材料的构建及其可见光催化降解性能

通讯作者: 刘超, cliu@ycit.edu.cn 戴勇, 123daiyong123@163.com

English

ZnCuAl-LDH/Bi2MoO6 Nanocomposites with Improved Visible Light-Driven Photocatalytic Degradation

Corresponding author: Chao Liu, cliu@ycit.edu.cn Yong Dai, 123daiyong123@163.com

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

ZnCuAl-LDH/Bi₂MoO₆纳米复合材料的构建及其可见光催化降解性能

通讯作者: 刘超, cliu@ycit.edu.cn
戴勇, 123daiyong123@163.com

ZnCuAl-LDH/Bi₂MoO₆ Nanocomposites with Improved Visible Light-Driven Photocatalytic Degradation

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs