光催化甲烷转化研究进展

引用本文: 许振民, 卞振锋. 光催化甲烷转化研究进展[J]. 物理化学学报, 2020, 36(3): 1907013-0. doi: 10.3866/PKU.WHXB201907013 shu

Citation: Xu henmin, Bian Zhenfeng. Photocatalytic Methane Conversion[J]. Acta Physico-Chimica Sinica, 2020, 36(3): 1907013-0. doi: 10.3866/PKU.WHXB201907013 shu

光催化甲烷转化研究进展

许振民 ,
卞振锋 ^,

上海师范大学，资源化学教育部重点实验室，上海 200234

作者简介:
卞振锋教授，博士生导师，2012年入选上海市“东方学者”特聘教授，2013年入选上海市曙光学者，2015年获得国家优秀青年科学基金。一直从事光催化净化环境研究，涉及光催化剂合成方法学、污染物降解机理和实际应用。至今以第一/通讯作者发表SCI论文30余篇，包括Environ. Sci. Technol.、Nature Commun.、J. Am. Chem. Soc.、Angew. Chem. Int. Ed.等，论文他引近5000次，8篇为ESI论文; 荣获2015年度上海市自然科学一等奖，排名第二; 获2013–2014年度太阳能光化学与光催化研究领域优秀青年奖;

通讯作者: 卞振锋, bianzhenfeng@shnu.edu.cn

基金项目:

国家自然科学基金(21876114, 21761142011, 51572174), 上海市科委国际合作项目(19160712900);资源化学国际合作联合实验室(IJLRC)与上海市东方学者人才计划资助项目

摘要: 甲烷催化转化为高附加值产物、实现甲烷高效利用，具有重要的研究意义及工业应用价值。长期以来，如何在较温和的条件下将甲烷转化为其它更有价值的有机衍生物，如醇、芳烃、长链烷烃和烯烃等，是催化、化学及化工领域的热点和难点课题之一。光催化反应由光能激发产生光生电子和空穴，参与到甲烷C―H键活化和自由基形成，这为低温甲烷转化提供新的途径，本文主要围绕甲烷氧化和偶联反应，总结了近年来光催化研究进展，并对如何进一步提高光催化性能提出展望。

关键词:

English

Photocatalytic Methane Conversion

Xu henmin ,
Bian Zhenfeng ^,

Laboratory of Resource Chemistry, Ministry of Education, Shanghai Normal University, Shanghai 200234, P. R. China

Corresponding author: Zhenfeng Bian, bianzhenfeng@shnu.edu.cn; Tel.: +86-21-64322272

Received Date: 01 July 2019
Accepted Date: 29 August 2019
Revised Date: 13 August 2019
Available Online: 15 March 2020
Fund Project:

The project was supported by the National Natural Science Foundation of China (21876114, 21761142011, 51572174), Shanghai Government, China (19160712900), International Joint Laboratory on Resource Chemistry, China (IJLRC), and the Program for Professor of Special Appointment (Eastern Scholar) at Shanghai Institutions of Higher Learning, China

Abstract: Methane is a promising energy source with vast reserves, and is considered one of the promising alternatives to nonrenewable petroleum resources because it can be converted into valuable hydrocarbon feedstocks and hydrogen through appropriate reactions. Recently, the conversion of CH₄ into other high-value-added products has received increasing attention because of their sustainability for energy and the environment. However, methane has a tetrahedral geometry with four equivalent C―H bonds due to the sp³ hybridization of the central carbon atom, with a C―H bond length of 0.1087 nm and an H-C―H bond angle of 109.5°. The absence of a dipole moment and the small polarizability (2.84 × 10⁻⁴⁰ C²·m²·J⁻¹) imply that methane requires a high local electric field for polarization and for nucleophilic or electrophilic attack. Nevertheless, it is believed that an effective method to activate CH₄ would be available, so that not only methanol, formaldehyde, and ethylene but also other industrially valuable raw materials can be obtained. On the other hand, the conversion of this combustible gas into the corresponding liquid fossil fuel proceeds via secondary chemical conversion, and it can greatly reduce transportation costs. From the economic viewpoint, this can still provide considerable benefits. Homogeneous catalysts have been reported to catalyze methane, but most of them operate at high pressures (2–7 MPa), or in strongly acidic media and at high temperatures (up to 500 K). Heterogeneous catalysts reported in the literature are also active only at high temperatures. Therefore, finding an efficient method to active methane has become a hot research topic. Photocatalysis technology is recognized as the optimal solution for the conversion of CH₄ since solar energy is by far the largest exploitable resource of energy. In the past years, much effort has been undertaken for the conversion of CH₄ under light at low temperature. In this regard, several photocatalysts, including silica-alumina-titania, silica-supported oxides, and ceria- and zeolite-based materials, have been developed. In photocatalytic methane conversion, the C―H bond can be selectively activated by adjusting the wavelength and intensity of the incident light and the oxidation capacity of the photocatalysts, thereby avoiding the formation of byproducts. This review summarizes a series of photocatalytic direct methane conversion systems developed in recent years, including methane oxidation and coupling processes. The effects of the catalyst composition and structure, oxidant, and electron transfer on the activation of the C―H bond of methane are detailed. Finally, future perspectives and challenges for the photocatalytic conversion of methane are discussed.

Key words:

1. [1]
  Xiao, G.; Guan, F.; Gang, L.; Hao, M.; Hong, F.; Liang, Y.; Chao, M.; Xing, W.; De, D.; Ming, W.; et al. Science 2014, 334, 616. doi: 10.1126/science.1253150 doi: 10.1126/science.1253150
2. [2]
  Golisz, S. R.; Brent, G. T.; Goddard, W. A.; Groves, J. T.; Periana, R. A. Catal. Lett. 2010, 141, 213. doi: 10.1007/s10562-010-0499-5 doi: 10.1007/s10562-010-0499-5
3. [3]
  Patrick, G.; Michel, P. Appl. Catal. B: Environ. 2002, 39, 1. doi: 10.1016/S0926-3373(02)00076-0 doi: 10.1016/S0926-3373(02)00076-0
4. [4]
  Cullis, C. F.; Willatt, B. M. J. Cat. 1983, 83, 267. doi: 10.1016/0021-9517(83)90054-4 doi: 10.1016/0021-9517(83)90054-4
5. [5]
  Andrey, J. Z.; Jackie, Y. Y. Nature 2000, 43, 6765. doi: 10.1038/47450 doi: 10.1038/47450
6. [6]
  Tao, F. F.; Shan, J. J.; Nguyen, L.; Wang, Z.; Zhang, S.; Zhang, L.; Wu, Z.; Huang, W.; Zeng, S.; Hu, P. Nat. Commun. 2015, 6, 7798. doi: 10.1038/ncomms8798 doi: 10.1038/ncomms8798
7. [7]
  Wang, H.; Chen, C.; Zhang, Y.; Peng, L.; Ma, S.; Yang, T.; Guo, H.; Zhang, Z.; Su, D. S.; Zhang, J. Nat. Commun. 2015, 6, 7181. doi: 10.1038/ncomms8181 doi: 10.1038/ncomms8181
8. [8]
  Cargnello, M.; Delgado, J. J.; Hernandez, J. C. Bakhmutsky, K.; Montini, T.; Calvino, J. J.; Gorte, R. J.; Fornasiero, P. Science 2012, 337, 713. doi: 10.1126/science.1222887 doi: 10.1126/science.1222887
9. [9]
  Narsimhan, K.; Iyoki, K.; Dinh, K.; Roman, L. Y. ACS Cent. Sci. 2016, 2, 424. doi: 10.1021/acscentsci.6b00139 doi: 10.1021/acscentsci.6b00139
10. [10]
  Baek, J.; Rung, B.; Pei, X.; Park, M.; Fakra, S. C.; Liu, Y. S.; Matheu, R.; Alshmimri, S. A.; Alshehri, S; Trickett, C. A.; et al. J. Am. Chem. Soc. 2018, 140, 18208. doi: 10.1021/jacs.8b11525 doi: 10.1021/jacs.8b11525
11. [11]
  Chen, X.; Li, Y.; Pan, X.; Cortie, D.; Huang, X.; Yi, Z. Nat. Commun. 2016, 7, 12273. doi: 10.1038/ncomms12273 doi: 10.1038/ncomms12273
12. [12]
  Shan, J.; Li, M.; Allard, L. F.; Lee, S.; Flytzani, S. M. Nature 2017, 551, 605. doi: 10.1038/nature24640 doi: 10.1038/nature24640
13. [13]
  Sh, Q. W.; Xian, T.; Ju, C. H.; Wang, L.; Zhang, J. L. J. Am. Chem. Soc. 2019, 141, 6592. doi: 10.1021/jacs.8b13858 doi: 10.1021/jacs.8b13858
14. [14]
  Ji, X.; Jin, R.; Li, A.; Bi, Y.; Ruan, Q.; Deng, Y.; Zhang, Y.; Yao, S.; Sankar, G.; Ma, D.; Tang, J. Nat. Catal. 2018, 1, 889. doi: 10.1038/s41929-018-0170-x doi: 10.1038/s41929-018-0170-x
15. [15]
  Hansan, L.; Chao, S.; Lei, Z.; Jiu, Z.; Hai, W.; Wilkinson, D. P. J. Power Sources 2006, 155, 95. doi: 10.1016/j.jpowsour.2006.01.030 doi: 10.1016/j.jpowsour.2006.01.030
16. [16]
  Nishth, A.; Simon, J. F.; Rebecca, U. M.; Sultan, M. A.; Nikolaos, D.; Qian, H.; David, J. M.; Robert, L. J.; David, J. W.; Stuart, H. T.; et al. Science 2017, 358, 223. doi: 10.1126/science doi: 10.1126/science
17. [17]
  Newton, M. A.; Knorpp, A. J.; Pinar, A. B.; Sushkevich, V. L.; Palagin, D.; Bokhoven, J. A. J. Am. Chem. Soc. 2018, 140, 10090. doi: 10.1021/jacs.8b05139 doi: 10.1021/jacs.8b05139
18. [18]
  Vanelderen, P.; Snyder, B. E.; Tsai, M. L.; Hadt, R. G.; Van, J.; Coussens, O.; Schoonheydt, R. A.; Sels, B. F.; Solomon, E. I. J. Am. Chem. Soc. 2015, 137, 6383. doi: 10.1021/jacs.5b02817 doi: 10.1021/jacs.5b02817
19. [19]
  Snyder, B. E.; Vanelderen, P.; Bols, M. L.; Hallaert, S. D.; Bottger, L. H.; Ungur, L.; Pierloot, K.; Schoonheydt, R. A.; Sels, B. F.; Solomon, E. I. Nature 2016, 536, 317. doi: 10.1038/nature19059 doi: 10.1038/nature19059
20. [20]
  Michael, M.; Thomas, S.; Wolf, A. H. Angew. Chem. Int. Ed. 2002, 41, 1475. doi: 10.1002/1521-3773 doi: 10.1002/1521-3773
21. [21]
  Vitaly, L. S.; Dennis, P.; Marco, R.; Jeroen, A. B. Science 2017, 356, 523. doi: 10.1126/science.aam9035 doi: 10.1126/science.aam9035
22. [22]
  Huang, W.; Zhang, S.; Tang, Y.; Li, Y.; Nguyen, L.; Li, Y.; Shan, J.; Xiao, D.; Gagne, R.; Anatoly, I. F.; et al. Angew. Chem. Int. Ed. 2016, 55, 13441. doi: 10.1002/anie.201604708 doi: 10.1002/anie.201604708
23. [23]
  Zimmermann, T.; Soorholtz, M.; Bilke, M.; Schuth, F. J. Am. Chem. Soc. 2016, 138, 12395. doi: 10.1021/jacs.6b05167 doi: 10.1021/jacs.6b05167
24. [24]
  Rahim, M. H.; Armstrong, R. D.; Hammond, C.; Dimitratos, N.; Freakley, S. J.; Forde, M. M.; Morgan, D. J.; Lalev, G.; Jenkins, R. L.; Lopez, J. A.; et al. Catal. Sci. Technol. 2016, 6, 3410. doi: 10.1039/c5cy01586c doi: 10.1039/c5cy01586c
25. [25]
  Liu, C.; Mou, C. Y.; Yu, S. F.; Chan, S. I. Energy Environ. Sci. 2016, 9, 1361. doi: 10.1039/c5ee03372a doi: 10.1039/c5ee03372a
26. [26]
  Grundner, S.; Markovits, M. A.; Li, G.; Tromp, M.; Pidko, E. A.; Hensen, E. J.; Jentys, A.; Sanchez, M.; Lercher, J. A. Nat. Commun. 2015, 6, 7546. doi: 10.1038/ncomms8546 doi: 10.1038/ncomms8546
27. [27]
  Kaliaguine, S. L.; Shelomov. B. N.; Kazansky. V. B. J. Catal. 1978, 55, 384. doi: 10.1016/0021-9517(78)90225-7 doi: 10.1016/0021-9517(78)90225-7
28. [28]
  Heactor, H. L.; Agustõan, M. Catal. Lett. 2002, 83, 37. doi: 10.1023/A:1020649313699 doi: 10.1023/A:1020649313699
29. [29]
  Hu, Y.; Nagai, Y.; Rahmawaty, D.; Wei, C.; Anpo, M. Catal. Lett. 2008, 124, 80. doi: 10.1007/s10562-008-9491-8: doi: 10.1007/s10562-008-9491-8:
30. [30]
  Richard, P. N.; Charles, E. T.; Joseph, R. D. Catal. Today 1997, 33, 167. doi: 10.1016/S0920-5861(96)00155-1 doi: 10.1016/S0920-5861(96)00155-1
31. [31]
  Villa, K.; Murcia, L. S.; Remon, M. J.; Andreu, T. Appl. Catal. B: Environ. 2016, 187, 30. doi: 10.1016/j.apcatb.2016.01.032 doi: 10.1016/j.apcatb.2016.01.032
32. [32]
  Xuan, L.; Chen, G.; Liang, Y.; Zhen, J.; Jin, L. Adv. Funct. Mater. 2010, 20, 2815. doi: 10.1002/adfm.201000792 doi: 10.1002/adfm.201000792
33. [33]
  Chen, Y.; Zeng, D.; Zhang, K.; Lu, A.; Wang, L.; Peng, D. L. Nanoscale 2014, 6, 874. doi: 10.1039/c3nr04558g doi: 10.1039/c3nr04558g
34. [34]
  Li, G.; Tang, Z. Nanoscale 2014, 6, 3995. doi: 10.1039/c3nr06787d doi: 10.1039/c3nr06787d
35. [35]
  Reza, G. M.; Dinh, C. T.; Beland, F.; Do, T. O. Nanoscale 2015, 7, 8187. doi: 10.1039/c4nr07224c doi: 10.1039/c4nr07224c
36. [36]
  Amiri, O.; Salavati, N. M.; Mir, N.; Beshkar, F.; Saadat, M.; Ansari, F. Renewable Energy 2018, 125, 590. doi: 10.1016/j.renene.2018.03.003 doi: 10.1016/j.renene.2018.03.003
37. [37]
  Qing, Q.; Hong, Y.; Zheng, J.; Gong, L.; Ying, B. RSC Adv. 2014, 4, 59114. doi: 10.1039/c4ra09355k doi: 10.1039/c4ra09355k
38. [38]
  Na, T.; Zhi, Z.; Shi, S.; Yong, D.; Zhong, W. Science 2007, 316, 732. doi: 10.1126/science.1140484 doi: 10.1126/science.1140484
39. [39]
  Hameed, A.; Ismail, I. M.; Aslam, M.; Gondal, M. A. Appl. Catal. A: Gen. 2014, 470, 327. doi: 10.1016/j.apcata.2013.10.045 doi: 10.1016/j.apcata.2013.10.045
40. [40]
  Xiao, J. D.; Han, L.; Luo, J.; Yu, S. H.; Jiang, H. L. Angew. Chem. Int. Ed. 2018, 57, 1103. doi: 10.1002/anie.201711725 doi: 10.1002/anie.201711725
41. [41]
  Wang, Y.; Suzuki, H.; Xie, J.; Tomita, O.; Martin, D. J.; Higashi, M.; Kong, D.; Abe, R.; Tang, J. Chem. Rev. 2018, 118, 5201. doi: 10.1021/acs.chemrev.7b00286 doi: 10.1021/acs.chemrev.7b00286
42. [42]
  Guo, L.; Yang, Z.; Marcus, K.; Li, Z.; Luo, B.; Zhou, L.; Wang, X.; Du, Y.; Yang, Y. J. Am. Chem. Soc. 2018, 11, 106. doi: 10.1039/c7ee02464a: doi: 10.1039/c7ee02464a:
43. [43]
  Qian, C.; Long, C.; Juan, Q.; Ying, T.; Yi, L.; Chao, X.; Jin, N.; Wen, L. Chin. Chem. Lett. 2019, 06, 1214. doi: 10.1016/j.cclet.2019.03.002 doi: 10.1016/j.cclet.2019.03.002
44. [44]
  Murcia, L. S.; Bacariza, M. C.; Villa, K.; Lopes, J. M.; Morante, J. R.; Andreu, T. ACS Catal. 2017, 7, 2878. doi: 10.1021/acscatal.6b03535 doi: 10.1021/acscatal.6b03535
45. [45]
  Villa, K.; S, M. L.; Andreu, T.; Remon, M. J. Appl. Catal. B: Environ. 2015, 163, 150. doi: 10.1016/j.apcatb.2014.07.055 doi: 10.1016/j.apcatb.2014.07.055
46. [46]
  Xu, Z. M.; Zheng, Ru.; Chen, Y.; Zhu, J.; Bian Z. F. Chin. J. Catal. 2019, 40, 631. doi: S1872-2067(19)63309-7
47. [47]
  Shi, F.; Tse, M. K.; Pohl, M. M.; Bruckner, A.; Zhang, S.; Beller, M. Angew. Chem. Int. Ed. 2007, 46, 8866. doi: 10.1002/anie.200703418 doi: 10.1002/anie.200703418
48. [48]
  Wang, T.; Yang, G.; Liu, J.; Yang, B.; Ding, S.; Yan, Z.; Xiao, T. Appl. Surf. Sci. 2014, 311, 314. doi: 10.1016/j.apsusc.2014.05.060 doi: 10.1016/j.apsusc.2014.05.060
49. [49]
  Eunsung, K.; Scott, G. H. Environ. Sci. Technol. 2009, 43, 1493. doi: 10.1021/es802360f doi: 10.1021/es802360f
50. [50]
  Qian, X.; Ren, M.; Zhu, Y.; Yue, D.; Han, Y.; Jia, J.; Zhao, Y. Environ. Sci. Technol. 2017, 51, 3993. doi: 10.1021/acs.est.6b06429 doi: 10.1021/acs.est.6b06429
51. [51]
  Hems, R. F.; Hsieh, J. S.; Slodki, M. A.; Zhou, S.; Abbatt, J. P. Environ. Sci. Technol. Lett. 2017, 4, 439. doi: 10.1021/acs.estlett.7b00381 doi: 10.1021/acs.estlett.7b00381
52. [52]
  Jian, Z.; Jie, R.; Yuning, H.; Zhen, F. B.; He, L. J. Phys. Chem. C 2007, 111, 18965. doi: 10.1021/jp0751108 doi: 10.1021/jp0751108
53. [53]
  Yue, Z.; Yang, S.; Ying, W.; Ji, B.; Mcpherson, G. L.; John, V. T. RSC Adv. 2017, 7, 39049. doi: 10.1039/c7ra06621j doi: 10.1039/c7ra06621j
54. [54]
  Isaac, B.; Maxime, S. Angew. Chem. Int. Ed. 2016, 55, 12873. doi: 10.1002/anie.201607216 doi: 10.1002/anie.201607216
55. [55]
  Spannring, P.; Yazerski, V.; Bruijnincx, P. C. A.; Weckhuysen, B. M.; Klein, R. J. M. Chem. Eur. J. 2013, 19, 15012. doi: 10.1002/chem.201301371 doi: 10.1002/chem.201301371
56. [56]
  Eric, M. F. Science 2012, 6105, 340. doi: 10.1126/science.1226840 doi: 10.1126/science.1226840
57. [57]
  Vasant, R. C.; Anil, K. K.; Tushar, V. C. Science 1997, 275, 1286. doi: 10.1126/science.275.5304.1286 doi: 10.1126/science.275.5304.1286
58. [58]
  Shimura, K.; Yoshida, H. Catal. Surv. Asia 2014, 18, 24. doi: 10.1007/s10563-014-9165-z doi: 10.1007/s10563-014-9165-z
59. [59]
  Yuliati, L.; Itoh, H.; Yoshida, H. Chem. Phy. Lett. 2008, 452, 178. doi: 10.1016/j.cplett.2007.12.051 doi: 10.1016/j.cplett.2007.12.051
60. [60]
  Yuko, K.; Yoshida, H.; Tadashi, H. Chem. Commun. 1998, 21, 2389. doi: 10.1039/A806825I doi: 10.1039/A806825I
61. [61]
  Yuliati, L.; Tsubota, M.; Satsuma, A.; Itoh, H.; Yoshida H. J. Catal. 2006, 238, 214. doi: 10.1016/j.jcat.2005.12.002 doi: 10.1016/j.jcat.2005.12.002
62. [62]
  Yoshida, H.; Matsushita, N.; Kato, Y.; Hattori, T. J. Phys. Chem. B 2003, 107, 8355. doi: 10.1021/jp034458 doi: 10.1021/jp034458
63. [63]
  Yuko, K.; Hisao, Y.; Atsushi, S.; Tadashi, H. Microporous Mesoporous Mat. 2002, 51, 223. doi: 10.1016/s1387-1811(02)00268-8 doi: 10.1016/s1387-1811(02)00268-8
64. [64]
  Li, L.; Li, G. D.; Yan, C.; Mu, X. Y.; Pan, X. L.; Zou, X. X.; Wang, K. X.; Chen, J. S. Angew. Chem. Int. Ed. 2011, 50, 8299. doi: 10.1002/anie.201102320 doi: 10.1002/anie.201102320
65. [65]
  Li, L.; Cai, Y. Y.; Li, G. D.; Mu, X. Y.; Wang, K. X.; Chen, J. S. Angew. Chem. Int. Ed. 2012, 51, 4702. doi: 10.1002/anie.201200045 doi: 10.1002/anie.201200045
66. [66]
  Wei, H.; Shou, F.; Qun, L.; Yong, H. Science 1997, 277, 1287. doi: 10.1126/science.277.5330.1287 doi: 10.1126/science.277.5330.1287
67. [67]
  Schafer, S.; Wyrzgol, S. A.; Caterino, R.; Jentys, A.; Schoell, S. J.; Haver, M.; Knop, A.; Lercher, J. A.; Sharp, I. D.; Stut, M. J. Am. Chem. Soc. 2012, 134, 12528. doi: 10.1021/ja3020132 doi: 10.1021/ja3020132
68. [68]
  Li, L.; Fan, S.; Mu, X.; Mi, Z.; Li, C. J. Am. Chem. Soc. 2014, 136, 7793. doi: 10.1021/ja5004119 doi: 10.1021/ja5004119
69. [69]
  Yu, L.; Shao, Y.; Li, D. Appl. Catal. B: Environ. 2017, 204, 216. doi: 10.1016/j.apcatb.2016.11.039 doi: 10.1016/j.apcatb.2016.11.039
70. [70]
  Chen, Y.; Zhao, H.; Liu, B.; Yang, H. Appl. Catal. B: Environ. 2015, 163, 189. doi: 10.1016/j.apcatb.2014.07.044 doi: 10.1016/j.apcatb.2014.07.044
71. [71]
  Zhang, B.; Wang, Z.; Huang, B.; Zhang, X.; Qin, X.; Li, H.; Dai, Y.; Li, Y. Chem. Mater. 2016, 28, 6613. doi: 10.1021/acs.chemmater.6b02639 doi: 10.1021/acs.chemmater.6b02639
72. [72]
  Meng, L.; Chen, Z.; Ma, Z.; He, S.; Hou, Y.; Li, H.; Yuan, R.; Huang, X.; Wang, X.; Long, J. J. Am. Chem. Soc. 2018, 11, 294. doi: 10.1039/c7ee02951a doi: 10.1039/c7ee02951a
73. [73]
  Zhou, Y.; Zhang, L.; Wang, W. Nat. Commun. 2019, 10, 506. doi: 10.1038/s41467-019-08454-0 doi: 10.1038/s41467-019-08454-0

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沈阳化工大学材料科学与工程学院沈阳 110142

光催化甲烷转化研究进展

通讯作者: 卞振锋, bianzhenfeng@shnu.edu.cn

English

Photocatalytic Methane Conversion

Corresponding author: Zhenfeng Bian, bianzhenfeng@shnu.edu.cn; Tel.: +86-21-64322272

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