基于立方烷结构的分子催化剂在光催化水氧化中的研究进展

引用本文: 孙万军, 林军奇, 梁向明, 杨峻懿, 马宝春, 丁勇. 基于立方烷结构的分子催化剂在光催化水氧化中的研究进展[J]. 物理化学学报, 2020, 36(3): 1905025-0. doi: 10.3866/PKU.WHXB201905025 shu

Citation: Sun Wanjun, Lin Junqi, Liang Xiangming, Yang Junyi, Ma Baochun, Ding Yong. Recent Advances in Catalysts Based on Molecular Cubanes for Visible Light-Driven Water Oxidation[J]. Acta Physico-Chimica Sinica, 2020, 36(3): 1905025-0. doi: 10.3866/PKU.WHXB201905025 shu

基于立方烷结构的分子催化剂在光催化水氧化中的研究进展

孙万军 ^1,3, ,
林军奇 ^1, ,
梁向明 ^1, ,
杨峻懿 ^1, ,
马宝春 ^1, ,
丁勇 ^{1,2,
,}

1.
兰州大学化学化工学院，兰州 730000
2.
中国科学院兰州化学物理研究所，羰基合成与选择氧化国家重点实验室，兰州 730000
3.
甘肃民族师范学院化学与生命科学系，甘肃合作 747000

作者简介:

丁勇，教授，博士生导师，甘肃省飞天学者特聘教授。主要从事光催化以及光电催化水的氧化和水的还原以及多酸催化化学。2004年12月于中国科学院兰州化学物理研究所获得博士学位，之后加盟兰州大学化学化工学院。2009年12月至2011年01月在美国埃默里大学化学系访学。现任Chinese Journal of Catalysis青年编委，中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室客座研究员。至今在SCI学术刊物上发表研究论文100余篇;

通讯作者: 丁勇, dingyong1@lzu.edu.cn

基金项目:

国家自然科学基金(21773096, 21572084), 兰州大学中央高校基本科研业务费(lzujbky-2018-k08), 甘肃省自然科学基金(17JR5RA186)和甘肃省高等学校科学研究(2018A-123)项目资助

摘要: 随着化石燃料大量使用带来的气候变化和环境污染问题日趋严重，寻找清洁高效的可再生能源用做传统化石燃料的替代品，已经成为当前的研究热点。光驱动的水分解反应被认为是太阳能制氢的可行途径。水的全分解包括两个半反应-水的氧化和质子还原。其中水的氧化反应是一个涉及四个电子和四个质子转移的复杂过程，需要很高的活化能，被认为是全分解水反应的瓶颈步骤。因此，开发高效、稳定、廉价丰产的水氧化催化剂是人工光合作用突破的关键因素。立方烷具有类似自然界光合作用酶光系统Ⅱ(PSⅡ)活性中心Mn₄CaO₅簇的结构，世界各国的科学家受自然界光合作用的启发，开发出了许多基于过渡金属的立方烷结构的催化剂，常见的有锰、钴和铜等立方烷催化剂。本文简要地综述了近年来立方烷分子催化剂在光催化水氧化中的研究进展。首先介绍了立方烷基光催化水氧化反应历程，继而详细介绍了基于有机配体的立方烷配合物和全无机的多金属氧酸盐立方烷水氧化催化剂，其次是半导体(BiVO₄或聚合的氮化碳(PCN))为捕光材料复合立方烷分子催化剂的水氧化体系最新研究进展。最后总结并展望了该领域所面临的挑战及其前景。

关键词:

English

Recent Advances in Catalysts Based on Molecular Cubanes for Visible Light-Driven Water Oxidation

1.
College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, P. R. China
2.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China
3.
Department of Chemistry and Life Science, Gansu Normal University for Nationalities, Hezuo 747000, Gansu Province, P. R. China

Corresponding author: Yong Ding, Email: dingyong1@lzu.edu.cn; Tel.: +86-931-8912585

Received Date: 06 May 2019
Accepted Date: 20 June 2019
Revised Date: 11 June 2019
Available Online: 15 March 2020
Fund Project:

The project was supported by the Natural Science Foundation of China (21773096, 21572084), Fundamental Research Funds for the Central Universities (lzujbky-2018-k08), Natural Science Foundation of Gansu (17JR5RA186) and Higher Education Institution Research Project of Gansu Province (2018A-123)

Abstract: Increasing climate change and environmental pollution caused by the excessive use of fossil fuels have prompted intensive research into clean and efficient renewable sources as a substitute for traditional fossil fuels. A very promising approach is to mimic the water splitting process that occurs in plants during photosynthesis, in order to convert solar energy into chemical energy. A successful water splitting reaction, which comprises two half reactions (water oxidation and the reduction of protons), can generate H₂ and O₂ from water. Hydrogen is a promising renewable energy carrier because of its clean combustion and high calorific value. Light-driven water splitting is considered to be a feasible way to transform water and solar energy into hydrogen energy. However, water oxidation is considered to be the bottleneck process of water splitting because it advances in a thermodynamically uphill manner with the involvement of 4e⁻ and 4H⁺. Inspired by the nature of Mn₄CaO₅ in photosystem Ⅱ (PS Ⅱ), the comprehensive understanding of its key features for use in active molecular water oxidation catalysts (WOCs) remains challenging. Extensive effort has been devoted to researching and manufacturing the structure and biomimicking the catalytic activity of Mn₄CaO₅ clusters that contain the Mn₃CaO₄ cubane structure, for the construction of low-cost and robust WOCs. WOCs can be divided into heterogeneous and homogeneous catalysts. Although heterogeneous WOCs are convenient for recycling and are easily prepared on a large scale, homogeneous WOCs, especially complexes based on organic ligands or polyoxometalates (POMs), have more advantages owing to their catalytic efficiency, structural modifications, and mechanistic understanding. Thus, recently, some molecules with an M₄O₄ (M = transition metals, mainly Mn, Co, Ni, and Cu) cubic structure have been reportedly used as photocatalytic WOCs. In this review, we present an overview of the most important and recent advances based on M₄O₄ cubic WOCs that contain first-row transition metal cubanes for visible light-driven water oxidation. Our main focus is on the structure of cubane catalysts, including metal complexes, POMs, and a system containing BiVO₄ or polymeric carbon nitride (PCN) as a photosensitizer, and cubic complexes as WOCs. Results have shown that the activity and stability of the catalyst can be tuned by the ligand stability, metal center, coordination environment, and other factors. This review will be helpful for designing new cubane catalysts for photocatalytic water oxidation that are highly efficient and stable.

Key words:

1. [1]
  Berardi, S.; Drouet, S.; Francàs, L.; Gimbert-Suriñach, C.; Guttentag, M.; Richmond, C.; Stoll, T.; Llobet, A. Chem. Soc. Rev. 2014, 43, 7501. doi: 10.1039/c3cs60405e doi: 10.1039/c3cs60405e
2. [2]
  Song, F.; Ding, Y.; Ma, B.; Wang, C.; Wang, Q.; Du, X.; Fu, S.; Song, J. Energy Environ. Sci. 2013, 6, 1170. doi: 10.1039/C3EE24433D doi: 10.1039/C3EE24433D
3. [3]
  Gong, J.; Li, C.; Wasielewski, M. R. Chem. Soc. Rev. 2019, 48, 1862. doi: 10.1039/c9cs90020al doi: 10.1039/c9cs90020al
4. [4]
  Wang, J. -W.; Zhong, D. -C.; Lu, T. -B. Coord. Chem. Rev. 2018, 377, 225. doi: 10.1016/j.ccr.2018.09.003 doi: 10.1016/j.ccr.2018.09.003
5. [5]
  肖岸, 卢辉, 赵阳, 骆耿耿.物理化学学报, 2016, 32 (12), 2968. doi: 10.3866/PKU.WHXB201609194Xiao, A.; Lu, H.; Zhao, Y.; Luo, G. G. Acta Phys. -Chim. Sin. 2016, 32 (12), 2968. doi: 10.3866/PKU.WHXB201609194
6. [6]
  Yu, L.; Ding, Y.; Zheng, M.; Chen, H.; Zhao, J. Chem. Commun. 2016, 52, 14494. doi: 10.1039/C6CC02728h doi: 10.1039/C6CC02728h
7. [7]
  Dismukes, G. C.; Brimblecombe, R.; Felton, G. A.; Pryadun, R. S.; Sheats, J. E.; Spiccia, L.; Swiegers, G. F. Acc. Chem. Res. 2009, 42, 1935. doi:10.1021/ar900249x doi: 10.1021/ar900249x
8. [8]
  Tian, T.; Gao, H.; Zhou, X.; Zheng, L.; Wu, J.; Li, K.; Ding, Y. ACS Energy Lett. 2018, 3, 2150. doi: 10.1021/acsenergylett.8b01206 doi: 10.1021/acsenergylett.8b01206
9. [9]
  Zhang, B.; Sun, L. Chem. Soc. Rev. 2019, 48, 2216. doi: 10.1039/c8cs00897c doi: 10.1039/c8cs00897c
10. [10]
  Gersten, S. W.; Samuels, G. J.; Meyer, T. J. J. Am. Chem. Soc. 1982, 104, 4029. doi: 10.1021/ja00378a053 doi: 10.1021/ja00378a053
11. [11]
  Umena, Y.; Kawakami, K.; Shen, J. -R.; Kamiya, N. Nature 2011, 473, 55. doi: 10.1038/nature09913 doi: 10.1038/nature09913
12. [12]
  Zhang, C. X.; Chen, C. H.; Dong, H. X.; Shen, J. R.; Dau, H.; Zhao, J. Q. Science 2015, 348, 690. doi: 10.1126/science.aaa6550 doi: 10.1126/science.aaa6550
13. [13]
  Kok, B.; Forbush, B.; McGloin, M. Photochem. Photobiol. 1970, 11, 457. doi: 10.1111/j.1751-1097.1970.tb06017.x doi: 10.1111/j.1751-1097.1970.tb06017.x
14. [14]
  Suga, M.; Akita, F.; Sugahara, M.; Kubo, M.; Nakajima, Y.; Nakane, T.; Yamashita, K.; Umena, Y.; Nakabayashi, M.; Yamane, T.; et al. Nature 2017, 543, 131. doi: 10.1038/nature21400 doi: 10.1038/nature21400
15. [15]
  Suga, M.; Akita, F.; Hirata, K.; Ueno, G.; Murakami, H.; Nakajima, Y.; Shimizu, T.; Yamashita, K.; Yamamoto, M.; Ago, H.; et al. Nature 2015, 517, 99. doi: 10.1038/nature13991 doi: 10.1038/nature13991
16. [16]
  Chen, C.; Chen, Y.; Yao, R.; Li, Y.; Zhang, C. Angew. Chem. Int. Ed. 2019, 58, 3939. doi: 10.1002/anie.201814440 doi: 10.1002/anie.201814440
17. [17]
  Lin, J.; Han, Q.; Ding, Y. Chem. Rec. 2018, 18, 1531. doi: 10.1002/tcr.201800029 doi: 10.1002/tcr.201800029
18. [18]
  Buriak, J. M.; Kamat, P. V.; Schanze, K. S. ACS Appl. Mater. Interfaces 2014, 6, 11815. doi: 10.1021/am504389z doi: 10.1021/am504389z
19. [19]
  Lin, J.; Meng, X.; Zheng, M.; Ma, B.; Ding, Y. Appl Catal B: Environ 2019, 241, 351. doi: 10.1016/j.apcatb.2018.09.052 doi: 10.1016/j.apcatb.2018.09.052
20. [20]
  Parent, A. R.; Crabtree, R. H.; Brudvig, G. W. Chem. Soc. Rev. 2013, 42, 2247. doi: 10.1039/C2CS35225G doi: 10.1039/C2CS35225G
21. [21]
  Yamada, Y.; Yano, K.; Hong, D.; Fukuzumi, S. Phys. Chem. Chem. Phys. 2012, 14, 5753. doi: 10.1039/c2cp00022a doi: 10.1039/c2cp00022a
22. [22]
  McCool, N. S.; Robinson, D. M.; Sheats, J. E.; Dismukes, G. C. J. Am. Chem. Soc. 2011, 133, 11446. doi: 10.1021/ja203877y doi: 10.1021/ja203877y
23. [23]
  Dismukes, G. C.; Brimblecombe, R.; Felton, G. A. N.; Pryadun, R. S.; Sheats, J. E.; Spiccia, L.; Swiegers, G. F. Acc. Chem. Res. 2009, 42, 1935. doi: 10.1021/ar900249x doi: 10.1021/ar900249x
24. [24]
  Smith, P. F.; Kaplan, C.; Sheats, J. E.; Robinson, D. M.; McCool, N. S.; Mezle, N.; Dismukes, G. C. Inorg. Chem. 2014, 53, 2113. doi: 10.1021/ic402720p doi: 10.1021/ic402720p
25. [25]
  Dimitrou, K.; Folting, K.; Streib, W. E.; Christou, G. J. Am. Chem. Soc. 1993, 115, 6432. doi: 10.1021/ja00067a077 doi: 10.1021/ja00067a077
26. [26]
  Sumner, E. C. Inorg. Chem. 1988, 27, 1320. doi: 10.1021/ic00281a004 doi: 10.1021/ic00281a004
27. [27]
  La Ganga, G.; Puntoriero, F.; Campagna, S.; Bazzan, I.; Berardi, S.; Bonchio, M.; Sartorel, A.; Natali, M.; Scandola, F. Faraday Discuss. 2012, 155, 177. doi: 10.1039/c1fd00093d doi: 10.1039/c1fd00093d
28. [28]
  Berardi, S.; La Ganga, G.; Natali, M.; Bazzan, I.; Puntoriero, F.; Sartorel, A.; Scandola, F.; Campagna, S.; Bonchio, M. J. Am. Chem. Soc. 2012, 134, 11104. doi: 10.1021/ja303951z doi: 10.1021/ja303951z
29. [29]
  Zhou, X.; Li, F.; Li, H.; Zhang, B.; Yu, F.; Sun, L. ChemSusChem 2014, 7, 2453. doi: 10.1002/cssc.201402195 doi: 10.1002/cssc.201402195
30. [30]
  Ullman, A. M.; Liu, Y.; Huynh, M.; Bediako, D. K.; Wang, H.; Anderson, B. L.; Powers, D. C.; Breen, J. J.; Abruña, H. D.; Nocera, D. G. J. Am. Chem. Soc. 2014, 136, 17681. doi: 10.1021/ja5110393 doi: 10.1021/ja5110393
31. [31]
  Nguyen, A. I.; Ziegler, M. S.; Oña-Burgos, P.; Sturzbecher-Hohne, M.; Kim, W.; Bellone, D. E.; Tilley, T. D. J. Am. Chem. Soc. 2015, 137, 12865. doi: 10.1021/jacs.5b08396 doi: 10.1021/jacs.5b08396
32. [32]
  Wang, H. -Y.; Mijangos, E.; Ott, S.; Thapper, A. Angew. Chem. Int. Ed. 2014, 53, 14499. doi: 10.1002/anie.201406540 doi: 10.1002/anie.201406540
33. [33]
  Wang, J. -W.; Sahoo, P.; Lu, T. -B. ACS Catal. 2016, 6, 5062. doi: 10.1021/acscatal.6b00798 doi: 10.1021/acscatal.6b00798
34. [34]
  Evangelisti, F.; More, R.; Hodel, F.; Luber, S.; Patzke, G. R. J. Am. Chem. Soc. 2015, 137, 11076. doi: 10.1021/jacs.5b05831 doi: 10.1021/jacs.5b05831
35. [35]
  Folkman, S. J.; Soriano-Lopez, J.; Galan-Mascaros, J. R.; Finke, R. G. J. Am. Chem. Soc. 2018, 140, 12040. doi: 10.1021/jacs.8b06303 doi: 10.1021/jacs.8b06303
36. [36]
  Evangelisti, F.; Guttinger, R.; More, R.; Luber, S.; Patzke, G. R. J. Am. Chem. Soc. 2013, 135, 18734. doi: 10.1021/ja4098302 doi: 10.1021/ja4098302
37. [37]
  Song, F.; Moré, R.; Schilling, M.; Smolentsev, G.; Azzaroli, N.; Fox, T.; Luber, S.; Patzke, G. R. J. Am. Chem. Soc. 2017, 139, 14198. doi: 10.1021/jacs.7b07361 doi: 10.1021/jacs.7b07361
38. [38]
  Xie, W. -F.; Guo, L. -Y.; Xu, J. -H.; Jagodič, M.; Jagličić, Z.; Wang, W. -G.; Zhuang, G. -L.; Wang, Z.; Tung, C. -H.; Sun, D. Eur. J. Inorg. Chem. 2016, 2016, 3253. doi.10.1002/ejic.201600510
39. [39]
  Xu, J. -H.; Guo, L. -Y.; Su, H.-F.; Gao, X.; Wu, X. -F.; Wang, W. -G.; Tung, C. -H.; Sun, D. Inorg. Chem. 2017, 56, 1591. doi: 10.1021/acs.inorgchem.6b02698
40. [40]
  Zhao, Y.; Lin, J.; Liu, Y.; Ma, B.; Ding, Y.; Chen, M. Chem. Commun. 2015, 51, 17309. doi:10.1039/C5CC07448g doi: 10.1039/C5CC07448g
41. [41]
  Jiang, X.; Li, J.; Yang, B.; Wei, X. Z.; Dong, B. W.; Kao, Y.; Huang, M.; Tung, C.; Wu, L. Angew. Chem. Int. Ed. 2018, 57, 7850. doi: 10.1002/anie.201803944 doi: 10.1002/anie.201803944
42. [42]
  Lin, J.; Liang, X.; Cao, X.; Wei, N.; Ding, Y. Chem. Commun. 2018, 54, 12515. doi: 10.1039/c8cc06362a doi: 10.1039/c8cc06362a
43. [43]
  宋芳源, 丁勇, 赵崇超.化学学报, 2014, 72, 133. doi: 10.6023/a13101052Song, F.; Ding, Y.; Zhao, C. Acta Chim Sinica 2014, 72, 133. doi: 10.6023/a13101052
44. [44]
  Lv, H.; Geletii, Y. V.; Zhao, C.; Vickers, J. W.; Zhu, G.; Luo, Z.; Song, J.; Lian, T.; Musaev, D. G.; Hill, C. L. Chem. Soc. Rev. 2012, 41, 7572. doi: 10.1039/C2CS35292C doi: 10.1039/C2CS35292C
45. [45]
  Du, X.; Zhao, J.; Mi, J.; Ding, Y.; Zhou, P.; Ma, B.; Zhao, J.; Song, J. Nano Energy 2015, 16, 247. doi: 10.1016/j.nanoen.2015.06.025 doi: 10.1016/j.nanoen.2015.06.025
46. [46]
  Yu, L.; Ding, Y.; Zheng, M. Appl. Catal. B: Environ. 2017, 209, 45. doi: 10.1016/j.apcatb.2017.02.061 doi: 10.1016/j.apcatb.2017.02.061
47. [47]
  Yu, L.; Lin, J.; Zheng, M.; Chen, M.; Ding, Y. Chem. Commun. 2018, 54, 354. doi: 10.1039/C7CC08301G doi: 10.1039/C7CC08301G
48. [48]
  Du, X.; Ding, Y.; Song, F.; Ma, B.; Zhao, J.; Song, J. Chem. Commun. 2015, 51, 13925. doi: 10.1039/c5cc04551g doi: 10.1039/c5cc04551g
49. [49]
  Yin, Q.; Tan, J. M.; Besson, C.; Geletii, Y. V.; Musaev, D. G.; Kuznetsov, A. E.; Luo, Z.; Hardcastle, K. I.; Hill, C. L. Science 2010, 328, 342. doi: 10.1126/science.1185372 doi: 10.1126/science.1185372
50. [50]
  Han, Z.; Bond, A. M.; Zhao, C. Sci. China Chem. 2011, 54, 1877. doi: 10.1007/s11426-011-4442-4 doi: 10.1007/s11426-011-4442-4
51. [51]
  Sartorel, A.; Carraro, M.; Scorrano, G.; Zorzi, R. D.; Geremia, S.; McDaniel, N. D.; Bernhard, S.; Bonchio, M. J. Am. Chem. Soc. 2008, 130, 5006. doi: 10.1021/ja077837f doi: 10.1021/ja077837f
52. [52]
  Geletii, Y. V.; Botar, B.; Kögerler, P.; Hillesheim, D. A.; Musaev, D. G.; Hill, C. L. Angew. Chem. Int. Ed. 2008, 47, 3896. doi: 10.1002/anie.200705652 doi: 10.1002/anie.200705652
53. [53]
  Geletii, Y. V.; Huang, Z.; Hou, Y.; Musaev, D. G.; Lian, T.; Hill, C. L. J. Am. Chem. Soc. 2009, 131, 7522. doi: 10.1021/ja901373m doi: 10.1021/ja901373m
54. [54]
  Han, X. -B.; Zhang, Z. -M.; Zhang, T.; Li, Y. -G.; Lin, W.; You, W.; Su, Z. -M.; Wang, E.-B. J. Am. Chem. Soc. 2014, 136, 5359. doi: 10.1021/ja412886e
55. [55]
  Du, P.; Kokhan, O.; Chapman, K. W.; Chupas, P. J.; Tiede, D. M. J. Am. Chem. Soc. 2012, 134, 11096. doi: 10.1021/ja303826a doi: 10.1021/ja303826a
56. [56]
  Wei, J.; Feng, Y.; Zhou, P.; Liu, Y.; Xu, J.; Xiang, R.; Ding, Y.; Zhao, C.; Fan, L.; Hu, C. ChemSusChem 2015, 8, 2630. doi: 10.1002/cssc.201500490 doi: 10.1002/cssc.201500490
57. [57]
  Chen, W. C.; Wang, X. L.; Qin, C.; Shao, K. Z.; Su, Z. M.; Wang, E. B. Chem. Commun. 2016, 52, 9514. doi: 10.1039/c6cc03763a doi: 10.1039/c6cc03763a
58. [58]
  Al-Oweini, R.; Sartorel, A.; Bassil, B. S.; Natali, M.; Berardi, S.; Scandola, F.; Kortz, U.; Bonchio, M. Angew. Chem. Int. Ed. 2014, 53, 11182. doi: 10.1002/anie.201404664 doi: 10.1002/anie.201404664
59. [59]
  Schwarz, B.; Forster, J.; Goetz, M. K.; Yücel, D.; Berger, C.; Jacob, T.; Streb, C. Angew. Chem. Int. Ed. 2016, 55, 6329. doi: 10.1002/anie.201601799 doi: 10.1002/anie.201601799
60. [60]
  Han, X. -B.; Li, Y. -G.; Zhang, Z. -M.; Tan, H. -Q.; Lu, Y.; Wang, E. -B. J. Am. Chem. Soc. 2015, 137, 5486. doi: 10.1021/jacs.5b01329
61. [61]
  Stewart, A. C.; Bendall, D. S. Biochem. J. 1980, 188. 351. doi: 10.1042/bj1880351 doi: 10.1042/bj1880351
62. [62]
  Xiang, R.; Ding, Y.; Zhao, J. Chem. Asian J. 2014, 9, 3228. doi: 10.1002/asia.201402483 doi: 10.1002/asia.201402483
63. [63]
  Probs, B.; Kolano, C.; Hamm, P.; Alberto, R. Inorg. Chem. 2009, 48, 1836. doi: 10.1021/ic8013255 doi: 10.1021/ic8013255
64. [64]
  Liang, X.; Lin, J.; Cao, X.; Sun, W.; Yang, J.; Ma, B.; Ding, Y. Chem. Commun. 2019, 55, 2529. doi: 10.1039/c8cc09807g doi: 10.1039/c8cc09807g
65. [65]
  Ye, C.; Wang, X. -Z.; Li, J. -X.; Li, Z. -J.; Li, X. -B.; Zhang, L. -P.; Chen, B.; Tung, C. -H.; Wu, L. -Z. ACS Catal. 2016, 6, 8336. doi: 10.1021/acscatal.6b02664
66. [66]
  Li, Y.; Kong, T.; Shen, S. Small 2019, 1900772. doi: 10.1002/smll.201900772 doi: 10.1002/smll.201900772
67. [67]
  常晓侠, 巩金龙.物理化学学报, 2016, 32 (1), 2. doi: 10.3866/PKU.WHXB201510192Chang, X. X.; Gong, J. L. Acta Phys. -Chim. Sin. 2016, 32 (1), 2. doi: 10.3866/PKU.WHXB201510192
68. [68]
  Wang, Y.; Li, F.; Li, H.; Bai, L.; Sun, L. Chem. Commun. 2016, 52, 3050. doi: 10.1039/c5cc09588c doi: 10.1039/c5cc09588c
69. [69]
  Ye, S.; Chen, R.; Xu, Y.; Fan, F.; Du, P.; Zhang, F.; Zong, X.; Chen, T.; Qi, Y.; Chen, P.; et al. J. Catal. 2016, 338, 168. doi: 10.1016/j.jcat.2016.02.024 doi: 10.1016/j.jcat.2016.02.024
70. [70]
  Luo, Z. S.; Zhou, M.; Wang, X. C. Appl. Catal. B: Environ. 2018, 238, 664. doi: 10.1016/j.apcatb.2018.07.056 doi: 10.1016/j.apcatb.2018.07.056

扫一扫看文章

计量

PDF下载量: 1
文章访问数: 143
HTML全文浏览量: 13

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于立方烷结构的分子催化剂在光催化水氧化中的研究进展

通讯作者: 丁勇, dingyong1@lzu.edu.cn

English

Recent Advances in Catalysts Based on Molecular Cubanes for Visible Light-Driven Water Oxidation

Corresponding author: Yong Ding, Email: dingyong1@lzu.edu.cn; Tel.: +86-931-8912585

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处