Citation: LI Hui, LIU Shuangyu, WANG Huiming, WANG Bo, SHENG Peng, XU Li, ZHAO Guangyao, BAI Huitao, CHEN Xin, CAO Yuliang, CHEN Zhongxue. Improved Sodium Storage Performance of Na_0.44MnO₂ Cathode at a High Temperature by Al₂O₃ Coating[J]. Acta Physico-Chimica Sinica, ;2019, 35(12): 1357-1364. doi: 10.3866/PKU.WHXB201902021 shu

Improved Sodium Storage Performance of Na_0.44MnO₂ Cathode at a High Temperature by Al₂O₃ Coating

LI Hui ¹ ,
LIU Shuangyu ¹ ,
WANG Huiming ² ,
WANG Bo ¹ ,
SHENG Peng ¹ ,
XU Li ¹ ,
ZHAO Guangyao ¹ ,
BAI Huitao ¹ ,
CHEN Xin ¹ ,
CAO Yuliang ³ ,
CHEN Zhongxue ^2,,

1.
State Key Laboratory of Advanced Transmission Technology, Global Energy Interconnection Research Institute Co. Ltd., Beijing 102211, P. R. China
2.
Key Laboratory of Hydraulic Machinery Transients, Ministry of Education, School of Power and Mechanical Engineering, Wuhan University, Wuhan 430072, P. R. China
3.
Hubei Key Laboratory of Electrochemical Power Sources, College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, P. R. China

Corresponding author: CHEN Zhongxue, zxchen_pmc@whu.edu.cn
Received Date: 25 February 2019
Revised Date: 2 April 2019
Accepted Date: 2 April 2019
Available Online: 10 December 2019
Fund Project: the National Natural Science Foundation of China 21673165the National Natural Science Foundation of China 21875171the Science and Technology Project of State Grid SGRIDGKJ[2017]841The project was supported by the Science and Technology Project of State Grid (SGRIDGKJ[2017]841), the National Basic Research Program of China (2016YFB0901500) and the National Natural Science Foundation of China (21875171, 21673165)the National Basic Research Program of China 2016YFB0901500

Renewable energy resources (such as wind and solar) are being increasingly utilized to overcome issues of energy shortage and environmental deterioration. However, the intrinsically fluctuant and intermittent character of renewable energy sources hinders their practical application; therefore, batteries have been developed to act as a link between renewable energy sources and consumers. Lithium-ion batteries have become the most advanced battery technology in the last three decades, and have successfully captured the electric vehicles market; however, many concerns have recently arisen about the vastly expanded demand for lithium resources, which contrasts with their limited reserves. In this context, sodium-ion batteries have emerged as a promising alternative because of their intercalation chemistry similar to that of lithium-ion batteries, and the abundance of Na resources in the Earth's crust. Like lithium-ion batteries, the performance and cost of sodium-ion batteries are determined primarily by their cathodes. Among the various cathode materials that have been reported for sodium-ion batteries, Na_0.44MnO₂ is regarded as one of the most promising because of its opened three-dimensional tunnel structure and good chemical stability; it has also been demonstrated in previous studies to have superior cycling stability at room temperature. In practical terms, commercial batteries are often used at high temperatures (above 40 ℃) in summer. Several Mn-based cathode materials for lithium-ion batteries, such as LiMn₂O₄ and LiNi_0.5Mn_1.5O₄, exhibit severe capacity decay at high temperatures. Therefore, the evaluation of the Na_0.44MnO₂ cathode in sodium-ion batteries at high temperatures is critical for its further commercialization. In this study, a Na_0.44MnO₂ cathode is prepared by a facile solid-state method and its electrochemical performance at a high temperature is measured. The electrochemical tests show that the Na_0.44MnO₂ cathode has a capacity retention of 66.5% over 100 cycles and a low reversible capacity of 12.3 mAh∙g^-1 at 10C (1C = 120 mAh∙g^-1). To improve its performance at a high temperature, Al₂O₃-coated Na_0.44MnO₂ is prepared via a liquid-phase method, and the coating effect is evaluated by electrochemical measurements as well as morphological, structural, and chemical composition analyses. The results show that the electrochemical performance of uncoated Na_0.44MnO₂ at 55 ℃ is significantly improved after coating with Al₂O₃; the capacity retention after 100 cycles increases to 79.2%, and the discharge capacity at 10C is increased to 63.6 mAh∙g^-1. The improved performance is clearly attributed to the Al₂O₃ coating, which effectively prevents direct contact of Na_0.44MnO₂ with the electrolyte and alleviates the dissolution of manganese at a high temperature, thus maintaining a stable electrode/electrolyte interface and reducing charge transfer resistance.
- Sodium-ion battery,
- Na_0.44MnO₂,
- Al₂O₃ coating,
- High temperature performance,
- Manganese dissolution
1. [1]
  Palomares, V.; Serras, P.; Villaluenga, I.; Hueso, K. B.; Carretero-González, J.; Rojo, T. Energy Environ. Sci. 2012, 5, 5884. doi: 10.1039/c2ee02781j doi: 10.1039/c2ee02781j
2. [2]
  Pan, H.; Hu, Y. S.; Chen, L. Energy Environ. Sci. 2013, 6, 2338. doi: 10.1039/c3ee40847g doi: 10.1039/c3ee40847g
3. [3]
  Slater, M. D.; Kim, D.; Lee, E.; Johnson, C. S. Adv. Funct. Mater. 2013, 23, 947. doi: 10.1002/adfm.201200691 doi: 10.1002/adfm.201200691
4. [4]
  Fang, Y.; Chen, Z.; Ai, X.; Yang, H.; Cao, Y. Acta Phys. -Chim. Sin. 2017, 33, 211. doi: 10.3866/PKU.WHXB201610111
5. [5]
  Nayak, P.K.; Yang, L.; Brehm, W.; Adelhelm, P. Angew. Chem. Int. Ed. 2018, 57, 102. doi: 10.1002/anie.201703772 doi: 10.1002/anie.201703772
6. [6]
  Delmas, C. Adv. Energy Mater. 2018, 8, 1703137. doi: 10.1002/aenm.201703137 doi: 10.1002/aenm.201703137
7. [7]
  Pu, X.; Wang, H.; Zhao, D.; Yang, H.; Ai, X.; Cao, S.; Chen, Z.; Cao, Y. Small 2019, 1805427. doi: 10.1002/smll.201805427 doi: 10.1002/smll.201805427
8. [8]
  Liu, S.; Shao, L.; Zhang, X.; Tao, Z.; Chen, J. Acta Phys. -Chim. Sin. 2018, 34, 581. doi: 10.3866/PKU.WHXB201711222
9. [9]
  Fang, Y.; Chen, Z.; Xiao, L.; Ai, X.; Cao, Y.; Yang, H. Small 2018, 14, 1703116. doi: 10.1002/smll.201703116 doi: 10.1002/smll.201703116
10. [10]
  Ni, Q.; Bai, Y.; Wu, F.; Wu, C. Adv. Sci. 2017, 4, 1600275. doi: 10.1002/advs.201600275 doi: 10.1002/advs.201600275
11. [11]
  Li, H.; Bai, Y.; Wu, F.; Ni, Q.; Wu, C. ACS Appl. Mater. Interfaces 2016, 8, 27779. doi: 10.1021/acsami.6b09898 doi: 10.1021/acsami.6b09898
12. [12]
  Kim, H.; Kim, D. J.; Seo, D. H.; Yeom, M. S.; Kang, K.; Kim, D. K.; Jung, Y. Chem. Mater. 2012, 24, 1205. doi: 10.1021/cm300065y doi: 10.1021/cm300065y
13. [13]
  He, X.; Wang, J.; Qiu, B.; Paillard, E.; Ma, C.; Cao, X.; Liu, H.; Stan, M. C.; Liu, H.; Gallash, T.; et al. Nano Energy 2016, 27, 602. doi: 10.1016/j.nanoen.2016.07.021 doi: 10.1016/j.nanoen.2016.07.021
14. [14]
  Zhou, X.; Guduru, R. K.; Mohanty, P. J. Mater. Chem. A 2013, 1, 2757. doi: 10.1039/c3ta01134h doi: 10.1039/c3ta01134h
15. [15]
  Ma, G.; Zhao, Y.; Huang, K.; Ju, Z.; Liu, C.; Hou, Y.; Xing, Z. Electrochim. Acta 2016, 222, 36. doi: 10.1016/j.electacta.2016.11.048 doi: 10.1016/j.electacta.2016.11.048
16. [16]
  Sauvage, F.; Laffont, L.; Tarascon, J. M.; Baudrin, E. lnorg. Chem. 2007, 46, 3289. doi: 10.1021/ic0700250 doi: 10.1021/ic0700250
17. [17]
  Thackeray, M. M. Prog. Solid State Chem. 1997, 25, 1. doi: 10.1016/S0079-6786(97)81003-5 doi: 10.1016/S0079-6786(97)81003-5
18. [18]
  Li, X.; Xu, Y.; Wang, C. J. Alloys Compd. 2009, 479, 310. doi: 10.1016/j.jallcom.2008.12.081 doi: 10.1016/j.jallcom.2008.12.081
19. [19]
  Yamada, A.; Tanaka, M.; Tanaka, K.; Sekai, K. J. Power Sources 1999, 81-82, 73. doi: 10.1016/S0378-7753(99)00106-8 doi: 10.1016/S0378-7753(99)00106-8
20. [20]
  Capitaine, F.; Gravereau, P.; Delmas, C. Solid State Ion. 1996, 89, 197. doi: 10.1016/0167-2738(96)00369-4 doi: 10.1016/0167-2738(96)00369-4
21. [21]
  Gummow, R. J.; Thackeray, M. J. Electrochem. Soc. 1994, 141, 1178. doi: 10.1149/1.2054893 doi: 10.1149/1.2054893
22. [22]
  Cao, Y.; Xiao, L.; Wang, W.; Choi, D.; Nie, Z.; Yu, J.; Saraf, L. V.; Yang, Z.; Liu, J. Adv. Mater. 2011, 23, 3155. doi: 10.1002/adma.201100904 doi: 10.1002/adma.201100904
23. [23]
  Jiang, X.; Liu, S.; Xu, H.; Chen, L.; Yang, J.; Qian, Y. Chem. Commun. 2015, 51, 8480. doi: 10.1039/c5cc02233a doi: 10.1039/c5cc02233a
24. [24]
  Chen, Z.; Yuan, T.; Pu, X.; Yang, H.; Ai, X.; Xia, Y.; Cao, Y. ACS Appl. Mater. Interfaces 2018, 10, 11689. doi: 10.1021/acsami.8b00478 doi: 10.1021/acsami.8b00478
25. [25]
  Yuan, T.; Zhang, J.; Pu, X.; Chen, Z.; Tang, C.; Zhang, X.; Ai, X.; Huang, Y.; Yang, H.; Cao, Y. ACS Appl. Mater. Interfaces 2018, 10, 34108. doi: 10.1021/acsami.8b08297 doi: 10.1021/acsami.8b08297
26. [26]
  Yuan, A.; Tian, L.; Xu, W.; Wang, Y. J. Power Sources 2010, 195, 5032. doi: 10.1016/j.jpowsour.2010.01.074 doi: 10.1016/j.jpowsour.2010.01.074
27. [27]
  Guan, D.; Jeevarajan, J.A.; Wang, Y. Nanoscale 2011, 3, 1465. doi: 10.1039/c0nr00939c doi: 10.1039/c0nr00939c
28. [28]
  Myung, S. T.; Izumi, K.; Komaba, S.; Sun, Y. K.; Yashiro, H.; Kumagai, N. Chem. Mater. 2005, 17, 3695. doi: 10.1021/cm050566s doi: 10.1021/cm050566s
29. [29]
  Zhou, X.; Xue, J.; Zhou, D.; Wang, Z.; Bai, Y.; Wu, X.; Liu, X.; Meng, J. ACS Appl. Mater. Interfaces 2010, 2, 2689. doi: 10.1021/am1004738 doi: 10.1021/am1004738
30. [30]
  Xiong, L.; Xu, Y.; Zhang, C.; Tao, T. Acta Phys. -Chim. Sin. 2012, 28, 1177. doi: 10.3866/PKU.WHXB201203092
31. [31]
  Chen, Z.; Qiu, S.; Cao, Y.; Ai, X.; Xie, K.; Hong, X.; Yang, H. J. Mater. Chem. 2012, 22, 17768, doi: 10.1039/c2jm33338d doi: 10.1039/c2jm33338d
32. [32]
  Song, J.; Xiao, B.; Lin, Y.; Xu, K.; Li, X. Adv. Energy Mater. 2018, 8, 1703082. doi: 10.1002/aenm.201703082 doi: 10.1002/aenm.201703082
33. [33]
  Tan, B. J.; Klabunde, K. J.; Sherwood, P. M. A. J. Am. Chem. Soc. 1991, 113, 855. doi: 10.1021/ja00003a019 doi: 10.1021/ja00003a019
34. [34]
  Liu, X.; Wang, J.; Zhang, J.; Yang, S. J. Mater. Sci.-Mater. El. 2006, 17, 865. doi: 10.1007/s10854-006-0041-0 doi: 10.1007/s10854-006-0041-0
35. [35]
  Li, J.; Xiong, S.; Liu, Y.; Ju, Z.; Qian, Y. Nano Energy 2013, 2, 1249. doi: 10.1016/j.nanoen.2013.06.003 doi: 10.1016/j.nanoen.2013.06.003
36. [36]
  Park, J. H.; Park, K.; Kim, R. H.; Yun, D. J.; Park, S. Y.; Han, D.; Lee, S. S.; Park, J. H. J. Mater. Chem. A 2015, 3, 10730. doi: 10.1039/c5ta00609k doi: 10.1039/c5ta00609k
1. [1]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5−xMn_0.5V_1.5−xZr_x (PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-0. doi: 10.3866/PKU.WHXB202407023
2. [2]
  Zilin Hu , Yaoshen Niu , Xiaohui Rong , Yongsheng Hu . Suppression of Voltage Decay through Ni³⁺ Barrier in Anionic-Redox Active Cathode for Na-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(6): 2306005-0. doi: 10.3866/PKU.WHXB202306005
3. [3]
  Xue Xiao , Jiachun Li , Xiangtong Meng , Jieshan Qiu . Sulfur-Doped Carbon-Coated Fe_0.95S_1.05 Nanospheres as Anodes for High-Performance Sodium Storage. Acta Physico-Chimica Sinica, 2024, 40(6): 2307006-0. doi: 10.3866/PKU.WHXB202307006
4. [4]
  Zhicheng JU , Wenxuan FU , Baoyan WANG , Ao LUO , Jiangmin JIANG , Yueli SHI , Yongli CUI . MOF-derived nickel-cobalt bimetallic sulfide microspheres coated by carbon: Preparation and long cycling performance for sodium storage. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 661-674. doi: 10.11862/CJIC.20240363
5. [5]
  Yuyao Wang , Zhitao Cao , Zeyu Du , Xinxin Cao , Shuquan Liang . Research Progress of Iron-based Polyanionic Cathode Materials for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(4): 2406014-0. doi: 10.3866/PKU.WHXB202406014
6. [6]
  Yu Guo , Zhiwei Huang , Yuqing Hu , Junzhe Li , Jie Xu . Recent Advances in Iron-based Heterostructure Anode Materials for Sodium Ion Batteries. Acta Physico-Chimica Sinica, 2025, 41(3): 2311015-0. doi: 10.3866/PKU.WHXB202311015
7. [7]
  Zhuo WANG , Xiaotong LI , Zhipeng HU , Junqiao PAN . Three-dimensional porous carbon decorated with nano bismuth particles: Preparation and sodium storage properties. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 267-274. doi: 10.11862/CJIC.20240223
8. [8]
  Qing Xue , Shengyi Li , Yanan Zhao , Peng Sheng , Li Xu , Zhengxi Li , Bo Zhang , Hui Li , Bo Wang , Libin Yang , Yuliang Cao , Zhongxue Chen . Novel Alkaline Sodium-Ion Battery Capacitor Based on Active Carbon||Na_0.44MnO₂ towards Low Cost, High-Rate Capability and Long-Term Lifespan. Acta Physico-Chimica Sinica, 2024, 40(2): 2303041-0. doi: 10.3866/PKU.WHXB202303041
9. [9]
  Hongyi LI , Aimin WU , Liuyang ZHAO , Xinpeng LIU , Fengqin CHEN , Aikui LI , Hao HUANG . Effect of Y(PO₃)₃ double-coating modification on the electrochemical properties of Li[Ni_0.8Co_0.15Al_0.05]O₂. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1320-1328. doi: 10.11862/CJIC.20230480
10. [10]
  Liuyun Chen , Wenju Wang , Tairong Lu , Xuan Luo , Xinling Xie , Kelin Huang , Shanli Qin , Tongming Su , Zuzeng Qin , Hongbing Ji . Soft template-induced deep pore structure of Cu/Al₂O₃ for promoting plasma-catalyzed CO₂ hydrogenation to DME. Acta Physico-Chimica Sinica, 2025, 41(6): 100054-0. doi: 10.1016/j.actphy.2025.100054
11. [11]
  Xinpeng LIU , Liuyang ZHAO , Hongyi LI , Yatu CHEN , Aimin WU , Aikui LI , Hao HUANG . Ga₂O₃ coated modification and electrochemical performance of Li_1.2Mn_0.54Ni_0.13Co_0.13O₂ cathode material. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1105-1113. doi: 10.11862/CJIC.20230488
12. [12]
  Qinjin DAI , Shan FAN , Pengyang FAN , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Yong ZHANG . Performance of oxygen vacancy-rich V-doped MnO₂ for high-performance aqueous zinc ion battery. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 453-460. doi: 10.11862/CJIC.20240326
13. [13]
  Doudou Qin , Junyang Ding , Chu Liang , Qian Liu , Ligang Feng , Yang Luo , Guangzhi Hu , Jun Luo , Xijun Liu . Addressing Challenges and Enhancing Performance of Manganese-based Cathode Materials in Aqueous Zinc-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(10): 2310034-0. doi: 10.3866/PKU.WHXB202310034
14. [14]
  Fan Yang , Zheng Liu , Da Wang , KwunNam Hui , Yelong Zhang , Zhangquan Peng . Preparation and Properties of P-Bi₂Te₃/MXene Superstructure-based Anode for Potassium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2303006-0. doi: 10.3866/PKU.WHXB202303006
15. [15]
  Pengyang FAN , Shan FAN , Qinjin DAI , Xiaoying ZHENG , Wei DONG , Mengxue WANG , Xiaoxiao HUANG , Yong ZHANG . Preparation and performance of rich 1T-MoS₂ nanosheets for high-performance aqueous zinc ion battery cathode materials. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 675-682. doi: 10.11862/CJIC.20240339
16. [16]
  Yingchun ZHANG , Yiwei SHI , Ruijie YANG , Xin WANG , Zhiguo SONG , Min WANG . Dual ligands manganese complexes based on benzene sulfonic acid and 2, 2′-bipyridine: Structure and catalytic properties and mechanism in Mannich reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1501-1510. doi: 10.11862/CJIC.20240078
17. [17]
  Xintong Zhu , Bin Cao , Chong Yan , Cheng Tang , Aibing Chen , Qiang Zhang . Advances in coating strategies for graphite anodes in lithium-ion batteries. Acta Physico-Chimica Sinica, 2025, 41(9): 100096-0. doi: 10.1016/j.actphy.2025.100096
18. [18]
  Lina Guo , Ruizhe Li , Chuang Sun , Xiaoli Luo , Yiqiu Shi , Hong Yuan , Shuxin Ouyang , Tierui Zhang . Effect of Interlayer Anions in Layered Double Hydroxides on the Photothermocatalytic CO₂ Methanation of Derived Ni-Al₂O₃ Catalysts. Acta Physico-Chimica Sinica, 2025, 41(1): 100002-0. doi: 10.3866/PKU.WHXB202309002
19. [19]
  Xuechen Hu , Qiuying Xia , Fan Yue , Xinyi He , Zhenghao Mei , Jinshi Wang , Hui Xia , Xiaodong Huang . Electrochemical Characteristics of LiNbO₃ Anode Film and Its Applications in All-Solid-State Thin-Film Lithium-Ion Battery. Acta Physico-Chimica Sinica, 2024, 40(2): 2309046-0. doi: 10.3866/PKU.WHXB202309046
20. [20]
  Bo YANG , Gongxuan LÜ , Jiantai MA . Corrosion inhibition of nickel-cobalt-phosphide in water by coating TiO₂ layer. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 365-384. doi: 10.11862/CJIC.20240063

Get Citation

PDF

XML

Metrics

PDF Downloads(18)
Abstract views(921)
HTML views(50)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Improved Sodium Storage Performance of Na0.44MnO2 Cathode at a High Temperature by Al2O3 Coating

Metrics

通讯作者: 陈斌, bchen63@163.com

Improved Sodium Storage Performance of Na_0.44MnO₂ Cathode at a High Temperature by Al₂O₃ Coating