Citation: WANG Lu, SUN Wei, LIU Chao. Homodinuclear Ferrous Group Metal Complexes and Their Application in Homogeneous Catalysis[J]. Acta Physico-Chimica Sinica, ;2019, 35(7): 697-708. doi: 10.3866/PKU.WHXB201807071 shu

Homodinuclear Ferrous Group Metal Complexes and Their Application in Homogeneous Catalysis

WANG Lu ¹ ,
SUN Wei ^1,2 ,
LIU Chao ^1,,

1.
State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, P. R. China
2.
University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Corresponding author: LIU Chao, chaoliu@licp.cas.cn
Received Date: 28 July 2018
Revised Date: 4 September 2018
Accepted Date: 4 September 2018
Available Online: 7 July 2018
Fund Project: the National Natural Science Foundation of China 21703265the National Natural Science Foundation of China 21603245the National Natural Science Foundation of China 91745110The project was supported by the National Natural Science Foundation of China (91745110, 21673261, 21603245, 21633013, 21703265), a Start-up Funding from Lanzhou Institute of Chemical Physics (LICP), the Young Elite Scientist Sponsorship Program by Chain Association for Science and Technology (CAST), the Youth Innovation Promotion Association Chinese Academy of Sciences (CAS) (2018458) and the 'Light of West China' Programthe National Natural Science Foundation of China 21633013a Start-up Funding from Lanzhou Institute of Chemical Physics (LICP) the National Natural Science Foundation of China 21673261the Youth Innovation Promotion Association Chinese Academy of Sciences (CAS) 2018458the 'Light of West China' Program the Young Elite Scientist Sponsorship Program by Chain Association for Science and Technology (CAST)

With the development of synthetic chemistry, more and more efficient catalysts are exploited to activate inert chemical bonds and organic molecules. In the synthetic chemistry, catalysts play an important role, scientists are paying more and more attention to the design and synthesis of catalysts. The majority of catalysts in homogeneous catalytic systems belong to mononuclear active species. In addition to the development of catalysis science, major research is also being conducted on the development of the coordination environment for metal centers to increase their catalytic ability and thereby create enhanced catalytic processes. The catalytic activity of dinuclear catalysts varies from those of mononuclear catalysts. Due to the synergistic effect between the two metal centers, the catalytic activity of dinuclear catalytic systems exhibits particular performance characteristics. The first row of elements in group Ⅷ of the periodic table, Fe, Co, and Ni, are also known as the ferrous group. These metals have drawn attention in recent years because of their relatively low price, stable structure, commercial availability, and ability to catalyze various type of reactions. Homodinuclear ferrous group metal complexes are applied in a wide variety of reactions, including hydroboration, hydrosilylation, cross-coupling reactions, asymmetric 1, 4-addition, asymmetric Mannich reactions, CO₂ activation, copolymerization, and alkyne cyclotrimerizations. Compared with mononuclear metal catalytic systems, there are currently relatively few types of homogenous catalytic systems that are catalyzed by bimetal catalysts. However, such catalytic systems possess significant advantages over mononuclear catalytic systems. For example, the catalytic activity and reaction selectivity of dinuclear metal catalytic systems are far superior, the reaction conditions milder, and the operations required simpler. However, research on the mechanisms of dinuclear metal catalytic systems is still insufficient. For example, the interaction between metals and substrates requires further investigation. This review focusses on the synthesis and characterization of homodinuclear bimetallic iron complexes. The application of homodinuclear iron, cobalt, and nickel complexes in homogeneous catalytic systems is introduced and summarized in detail. Finally, the challenges for the future development of homogeneous catalytic systems that utilize homodinuclear bimetallic iron complexes are outlined.
- Homodinuclear complex,
- Homogeneous catalysis,
- Iron catalyst,
- Co catalyst,
- Ni catalyst
1. [1]
  Yu, W. F.; Meng, X. G.; Liu, Y.; Li, X. H. Acta Phys. -Chim. Sin. 2013, 29, 2041. doi: 10.3866/PKU.WHXB201306282
2. [2]
  Luo, K. J.; Geng, H.; Zhang, C. Y.; Ni, H. L.; Li, Q. Chin. J. Inorg. Chem. 2017, 33, 405. doi: 10.11862/cjic.2017.026
3. [3]
  Huang, S. P.; Yuan, Z. Z. Acta Phys. -Chim. Sin. 2009, 25, 1599. doi: 10.3866/PKU.WHXB20090753
4. [4]
  Guo, L. Q.; Shi, X. L.; Ruan, W. J.; Zhang, X. H.; Zhu, Z. A. Acta Phys. -Chim. Sin. 2010, 26, 1195. doi: 10.3866/PKU.WHXB20100336
5. [5]
  Liu, H.; Zang, N.; Zhao, F. Y.; Liu, K.; Li, Y.; Ruan, W. J. Acta Phys. -Chim. Sin. 2014, 30, 1801. doi: 10.3866/PKU.WHXB201407171
6. [6]
  Liu, F. Q.; Zhao, J.; Zhang, D.; Duan, X. Q.; Wang, L.; Deng, Y. Y.; Li, W. H. Chin. J. Inorg. Chem. 2015, 31, 1402. doi: 10.11862/cjic.2015.166
7. [7]
  Behlen, M. J.; Zhou, Y. Y.; Steiman, T. J.; Pal, S.; Hartline, D. R.; Zeller, M.; Uyeda, C. Dalton Trans. 2017, 46, 5493. doi: 10.1039/c6dt04465d doi: 10.1039/c6dt04465d
8. [8]
  Gavrilova, A. L.; Bosnich, B. Chem. Rev. 2004, 104, 349. doi: 10.1021/cr020604g doi: 10.1021/cr020604g
9. [9]
  Do, L. H.; Xue, G.; Que, L., Jr.; Lippard, S. J. Inorg. Chem. 2012, 51, 2393. doi: 10.1021/ic202379b doi: 10.1021/ic202379b
10. [10]
  Ohki, Y.; Hatanaka, T.; Tatsumi, K. J. Am. Chem. Soc. 2008, 130, 17174. doi: 10.1021/ja8063028 doi: 10.1021/ja8063028
11. [11]
  Zhang, F.; Song, H.; Zhuang, X.; Tung, C. H.; Wang, W. J. Am. Chem. Soc. 2017, 139, 17775. doi: 10.1021/jacs.7b11416 doi: 10.1021/jacs.7b11416
12. [12]
  Obligacion, J. V.; Chirik, P. J. Org. Lett. 2013, 15, 2680. doi: 10.1021/ol400990u doi: 10.1021/ol400990u
13. [13]
  Iovan, D. A.; Betley, T. A. J. Am. Chem. Soc. 2016, 138, 1983. doi: 10.1021/jacs.5b12582 doi: 10.1021/jacs.5b12582
14. [14]
  Tong, P.; Yang, D.; Li, Y.; Wang, B.; Qu, J. Organometallics 2015, 34, 3571. doi: 10.1021/acs.organomet.5b00387 doi: 10.1021/acs.organomet.5b00387
15. [15]
  Wilkinson, E. C.; Dong, Y.; Que, L. J. Am. Chem. Soc. 1994, 116, 8394. doi: 10.1021/ja00097a068 doi: 10.1021/ja00097a068
16. [16]
  Mo, Z.; Zhang, Q.; Deng, L. Organometallics 2012, 31, 6518. doi: 10.1021/om300722g doi: 10.1021/om300722g
17. [17]
  Chen, Z.; Furutachi, M.; Kato, Y.; Matsunaga, S.; Shibasaki, M. Angew. Chem. Int. Ed. 2009, 48, 2218. doi: 10.1002/anie.200805967 doi: 10.1002/anie.200805967
18. [18]
  Gao, J.; Woolley, F. R.; Zingaro, R. A. Org. Biomol. Chem. 2005, 3, 2126. doi: 10.1039/b503971a doi: 10.1039/b503971a
19. [19]
  Kember, M. R.; White, A. J. P.; Williams, C. K. Macromolecules 2010, 43, 2291. doi: 10.1021/ma902582m doi: 10.1021/ma902582m
20. [20]
  Yu, C. Y.; Chuang, H. J.; Ko, B. T. Catal. Sci. Technol. 2016, 6, 1779. doi: 10.1039/c5cy01290b doi: 10.1039/c5cy01290b
21. [21]
  Lin, P. -M.; Chang, C. -H.; Chuang, H. -J.; Liu, C. -T.; Ko, B. -T.; Lin, C. -C. ChemCatChem 2016, 8, 984. doi: 10.1002/cctc.201501280 doi: 10.1002/cctc.201501280
22. [22]
  Chen, Z.; Morimoto, H.; Matsunaga, S.; Shibasaki, M. J. Am. Chem. Soc. 2008, 130, 2170. doi: 10.1021/ja710398q doi: 10.1021/ja710398q
23. [23]
  Chen, Z.; Yakura, K.; Matsunaga, S.; Shibasaki, M. Org. Lett. 2008, 10, 3239. doi: 10.1021/ol800965t doi: 10.1021/ol800965t
24. [24]
  Shepherd, N. E.; Tanabe, H.; Xu Y.; Matsunaga, S.; Shibasaki, M. J. Am. Chem. Soc. 2010, 132, 3666. doi: 10.1021/ja1002636 doi: 10.1021/ja1002636
25. [25]
  Mouri, S.; Chen, Z.; Matsunaga, S.; Shibasaki, M. Chem. Commun. 2009, 5138. doi: 10.1039/b912380f doi: 10.1039/b912380f
26. [26]
  Shibasaki, M.; Matsunaga, S.; Kato, Y.; Chen, Z. Synlett 2009, 2009, 1635. doi: 10.1055/s-0029-1217192 doi: 10.1055/s-0029-1217192
27. [27]
  Mitsunuma, H.; Matsunaga, S. Chem. Commun. 2011, 47, 469. doi: 10.1039/c0cc02152k doi: 10.1039/c0cc02152k
28. [28]
  Xu, Y.; Matsunaga, S.; Shibasaki, M. Org. Lett. 2010, 12, 3246. doi: 10.1021/ol101185p doi: 10.1021/ol101185p
29. [29]
  Gopinath, P.; Watanabe, T.; Shibasaki, M. Org. Lett. 2012, 14, 1358. doi: 10.1021/ol3002078 doi: 10.1021/ol3002078
30. [30]
  Zhang, S.; Deng, P.; Zhou, J.; Liu, M.; Liang, G.; Xiong, Y.; Zhou, H. Chem. Commun. 2017, 53, 12914. doi: 10.1039/c7cc06468c doi: 10.1039/c7cc06468c
31. [31]
  Dible, B. R.; Sigman, M. S. J. Am. Chem. Soc. 2003, 125, 872. doi: 10.1021/ja0286876 doi: 10.1021/ja0286876
32. [32]
  Laskowski, C. A.; Hillhouse, G. L. Organometallics 2009, 28, 6114. doi: 10.1021/om900783u doi: 10.1021/om900783u
33. [33]
  Miyazaki, S.; Koga, Y.; Matsumoto, T.; Matsubara, K. Chem. Commun. 2010, 46, 1932. doi: 10.1039/b924716e doi: 10.1039/b924716e
34. [34]
  Matsubara, K.; Yamamoto, H.; Miyazaki, S.; Inatomi, T.; Nonaka, K.; Koga, Y.; Yamada, Y.; Veiros, L. F.; Kirchner, K. Organometallics 2016, 36, 255. doi: 10.1021/acs.organomet.6b00451 doi: 10.1021/acs.organomet.6b00451
35. [35]
  Nagao, S.; Matsumoto, T.; Koga, Y.; Matsubara, K. Chem. Lett. 2011, 40, 1036. doi: 10.1246/cl.2011.1036 doi: 10.1246/cl.2011.1036
36. [36]
  Wu, J.; Nova, A.; Balcells, D.; Brudvig, G. W.; Dai, W.; Guard, L. M.; Hazari, N.; Lin, P. H.; Pokhrel, R.; Takase, M. K. Chem. Eur. J. 2014, 20, 5327. doi: 10.1002/chem.201305021 doi: 10.1002/chem.201305021
37. [37]
  Durr, A. B.; Fisher, H. C.; Kalvet, I.; Truong, K. N.; Schoenebeck, F. Angew. Chem. Int. Ed. 2017, 56, 13431. doi: 10.1002/anie.201706423 doi: 10.1002/anie.201706423
38. [38]
  Yang, X.; Wang, Z. -X. Organometallics 2014, 33, 5863. doi: 10.1021/om500452c doi: 10.1021/om500452c
39. [39]
  Zhou, Y. Y.; Hartline, D. R.; Steiman, T. J.; Fanwick, P. E.; Uyeda, C. Inorg. Chem. 2014, 53, 11770. doi: 10.1021/ic5020785 doi: 10.1021/ic5020785
40. [40]
  Steiman, T. J.; Uyeda, C. J. Am. Chem. Soc. 2015, 137, 6104. doi: 10.1021/jacs.5b03092 doi: 10.1021/jacs.5b03092
41. [41]
  Pappas, I.; Treacy, S.; Chirik, P. J. ACS Catal. 2016, 6, 4105. doi: 10.1021/acscatal.6b01134 doi: 10.1021/acscatal.6b01134
42. [42]
  Léonard, N. G.; Chirik, P. J. ACS Catal. 2017, 8, 342. doi: 10.1021/acscatal.7b03909 doi: 10.1021/acscatal.7b03909
43. [43]
  Pal, S.; Uyeda, C. J. Am. Chem. Soc. 2015, 137, 8042. doi: 10.1021/jacs.5b04990 doi: 10.1021/jacs.5b04990
44. [44]
  Zhou, Y. -Y.; Uyeda, C. Angew. Chem. Int. Ed. 2016, 55, 3171. doi: 10.1002/anie.201511271 doi: 10.1002/anie.201511271
45. [45]
  Pal, S.; Zhou, Y. Y.; Uyeda, C. J. Am. Chem. Soc. 2017, 139, 11686. doi: 10.1021/jacs.7b05901 doi: 10.1021/jacs.7b05901
46. [46]
  Hartline, D. R.; Zeller, M.; Uyeda, C. J. Am. Chem. Soc. 2017, 139, 13672. doi: 10.1021/jacs.7b08691 doi: 10.1021/jacs.7b08691
47. [47]
  Rounds, H. R.; Zeller, M.; Uyeda, C. Organometallics 2018, 37, 545. doi: 10.1021/acs.organomet.7b00862 doi: 10.1021/acs.organomet.7b00862
48. [48]
  Powers, I. G.; Andjaba, J. M.; Luo, X.; Mei, J.; Uyeda, C. J. Am. Chem. Soc. 2018, 140, 4110. doi: 10.1021/jacs.8b00503 doi: 10.1021/jacs.8b00503
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